Use of complex metal oxides in the autothermal generation of hydrogen
    1.
    发明授权
    Use of complex metal oxides in the autothermal generation of hydrogen 有权
    在自发生成氢气中使用复合金属氧化物

    公开(公告)号:US07438889B2

    公开(公告)日:2008-10-21

    申请号:US11165720

    申请日:2005-06-24

    IPC分类号: C01B3/26

    摘要: A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.

    摘要翻译: 一种生产氢的方法,包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下,在足以形成氢的复合金属氧化物的反应条件下,在制备步骤中使至少一种烃和蒸汽反应,其中复合金属 氧化物由公式<?in-line-formula description =“In-line Formulas”end =“lead”?>(A' Ca x' x“x”x“”“”“”“Y”“”“”“” &lt;&lt;&lt;&lt; /&gt;&lt;&lt;&lt;&lt;&lt;&lt; 来自由Sr,Ba,第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu,Ni,Co,Cr和V中的至少一种元素; 0 <= x <= 1,0 <= x'<= 1,0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1,0 <= y'<= 1,0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。

    Use of complex metal oxides in the autothermal generation of hydrogen
    3.
    发明申请
    Use of complex metal oxides in the autothermal generation of hydrogen 有权
    在自发生成氢气中使用复合金属氧化物

    公开(公告)号:US20060292066A1

    公开(公告)日:2006-12-28

    申请号:US11165720

    申请日:2005-06-24

    IPC分类号: C01B3/02 C01B3/26

    摘要: A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.

    摘要翻译: 一种生产氢的方法,包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下,在足以形成氢的复合金属氧化物的反应条件下,在制备步骤中使至少一种烃和蒸汽反应,其中复合金属 氧化物由公式<?in-line-formula description =“In-line Formulas”end =“lead”?>(A' Ca x' x“x”x“”“”“”“Y”“”“”“” &lt;&lt;&lt;&lt; /&gt;&lt;&lt;&lt;&lt;&lt;&lt; 来自由Sr,Ba,第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu,Ni,Co,Cr和V中的至少一种元素; 0 <= x <= 1,0 <= x'<= 1,0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1,0 <= y'<= 1,0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。

    Layered Mixed-Metal Phosphonates for High Dielectric Strength polymer Nanocomposites
    4.
    发明申请
    Layered Mixed-Metal Phosphonates for High Dielectric Strength polymer Nanocomposites 有权
    层状混合金属磷酸盐用于高介电强度聚合物纳米复合材料

    公开(公告)号:US20100216924A1

    公开(公告)日:2010-08-26

    申请号:US12705761

    申请日:2010-02-15

    IPC分类号: C08K5/5317 C07F9/28 C07F9/02

    CPC分类号: C08K5/5317 C07F9/3834

    摘要: Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

    摘要翻译: 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有:AB(RPO 3)3,其中A是Mg 2+,Ca 2+,Sr 2+,Ba 2+,Pb 2+,La 3+或其组合; B是Ti4 +,Zr4 +,Al3 +或它们的组合; R为有机基团(例如,芳基,烷基,烯基等)。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。

    Methods of making layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites
    5.
    发明授权
    Methods of making layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites 有权
    制备用于高介电强度聚合物纳米复合材料的层状混合金属膦酸盐的方法

    公开(公告)号:US08247586B2

    公开(公告)日:2012-08-21

    申请号:US13329731

    申请日:2011-12-19

    IPC分类号: C07F9/02

    CPC分类号: C08K5/5317 C07F9/3834

    摘要: Multi-metal phosphonates are generally provided. The multi-metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The multi-metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the multi-metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

    摘要翻译: 通常提供多金属膦酸盐。 多金属膦酸盐通常可以具有:AB(RPO 3)3,其中A是Mg 2+,Ca 2+,Sr 2+,Ba 2+,Pb 2+,La 3+或其组合; B是Ti4 +,Zr4 +,Al3-或它们的组合; R为有机基团(例如,芳基,烷基,烯基等)。 多金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备多金属膦酸盐的方法。

    Methods of Making Layered Mixed-Metal Phosphonates for High Dielectric Strength Polymer Nanocomposites
    6.
    发明申请
    Methods of Making Layered Mixed-Metal Phosphonates for High Dielectric Strength Polymer Nanocomposites 有权
    制备层状混合金属磷酸盐用于高介电强度聚合物纳米复合材料的方法

    公开(公告)号:US20120095142A1

    公开(公告)日:2012-04-19

    申请号:US13329731

    申请日:2011-12-19

    CPC分类号: C08K5/5317 C07F9/3834

    摘要: Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

    摘要翻译: 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有:AB(RPO 3)3,其中A是Mg 2+,Ca 2+,Sr 2+,Ba 2+,Pb 2+,La 3+或其组合; B是Ti4 +,Zr4 +,Al3-或它们的组合; R为有机基团(例如,芳基,烷基,烯基等)。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。

    Layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites
    7.
    发明授权
    Layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites 有权
    用于高介电强度聚合物纳米复合材料的分层混合金属膦酸盐

    公开(公告)号:US08080600B2

    公开(公告)日:2011-12-20

    申请号:US12705761

    申请日:2010-02-15

    IPC分类号: C08K5/5333

    CPC分类号: C08K5/5317 C07F9/3834

    摘要: Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, Co2+, Mn2+, Fe2+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.

    摘要翻译: 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有:AB(RPO 3)3,其中A是Mg 2+,Ca 2+,Sr 2+,Ba 2+,Pb 2+,La 3+,Co 2+,Mn 2+,Fe 2+,或其组合; B是Ti4 +,Zr4 +,Al3 +或它们的组合; R为有机基团(例如,芳基,烷基,烯基等)。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。