公开(公告)号：US20240359980A1

公开(公告)日：2024-10-31

申请号：US18291800

申请日：2022-08-02

申请人： ZEG Power AS

发明人： Arnstein NORHEIM ,  Margrethe STENRØD WEST ,  Vidar GRAFF

IPC分类号： C01B3/56 ,  B01D53/34 ,  B01D53/62 ,  B01D53/83 ,  B01D53/96 ,  C01B3/40 ,  C01B3/44

CPC分类号： C01B3/56 ,  B01D53/346 ,  B01D53/62 ,  B01D53/83 ,  B01D53/96 ,  C01B3/40 ,  C01B3/44 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2256/16 ,  B01D2257/504 ,  B01D2258/02 ,  C01B2203/0233 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/1058 ,  C01B2203/1241 ,  C01B2203/148 ,  C01B2203/1685

摘要： A system and method for producing hydrogen gas. The system comprises at least one reformer reactor, at least one separator, at least one separator transport line, at least one regenerator reactor, at least one regenerator transport line and at least one recycling line. The reformer reactor is for containing a CO2 capturing sorbent A forming a used sorbent A*, wherein the reformer reactor is configured to allow reform of a feed material B and a steam C to produce a reformate gas mixture comprising H2 and CO2. The reformer reactor comprising a reformer inlet for feeding at least one of B and C into the reformer reactor and a reformer outlet for ejecting A* and H2. A separator configured to separate A* from H2. The separator comprising a separator inlet for feeding H2 and A* into the separator and a separator outlet for ejecting the separated A *. A separator transport line for transporting A* and H2 from the reformer outlet to the separator inlet. The regenerator reactor comprising a regenerator inlet for receiving at least a portion of A* separated in the separator. A regenerator power source configured to provide sufficient energy to the received A* for allowing release of CO2, thereby regenerating the sorbent. A regenerator outlet for ejecting the regenerated sorbent. A regenerator transport line for transporting the flow of A* from the separator outlet to the regenerator inlet. A recycling line arranged to transport at least a portion of the regenerated sorbent from the regenerator outlet into the reformer reactor. The regenerator transport line comprises a flow regulating device arranged to adjust the flow rate of A* being transported into the regenerator inlet.

公开(公告)号：US20240351873A1

公开(公告)日：2024-10-24

申请号：US18523557

申请日：2023-11-29

申请人： HYUNDAI MOTOR COMPANY ,  KIA CORPORATION ,  RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITY

发明人： Haeun Jeong ,  Young Gul Hur ,  Pyung Soon Kim ,  Kyung Soo Park ,  Jiyong Kim

IPC分类号： C01B3/38 ,  B01D53/00 ,  B01D53/047 ,  C01B3/50 ,  C01B3/56 ,  C01B32/40

CPC分类号： C01B3/38 ,  B01D53/002 ,  B01D53/047 ,  C01B3/506 ,  C01B3/56 ,  C01B32/40 ,  B01D2256/22 ,  B01D2256/245 ,  B01D2257/108 ,  B01D2257/502 ,  C01B2203/0238 ,  C01B2203/0425 ,  C01B2203/046 ,  C01B2203/065 ,  C01B2203/0811 ,  C01B2203/1241 ,  C01B2203/1258

摘要： A hydrogen production system includes a desulfurization unit configured to remove a sulfur component from hydrocarbon gas. The system has a pre-reforming unit configured to convert hydrocarbons having two or more carbon atoms into methane (CH4) by reacting the hydrocarbon gas with water (H2O) vapor. The system has a mixed reforming unit configured to produce hydrogen (H2) and carbon monoxide (CO) by performing a mixed reforming reaction between the reaction product of the pre-reforming unit and carbon dioxide (CO2). The system has a separation unit for separating hydrogen (H2) and CO from the reaction product of the mixed reforming unit. The system has a first heat exchange unit configured to generate water vapor supplied to the pre-reforming unit using the heat of the reaction product of the mixed reforming unit.

公开(公告)号：US11918993B2

公开(公告)日：2024-03-05

申请号：US17248230

申请日：2021-01-14

申请人： PURE SUSTAINABLE TECHNOLOGIES, LLC

发明人： Michael Evan Siditsky ,  Kenneth Patrick Kelley

IPC分类号： B01J8/26 ,  B01J8/02 ,  B01J8/18 ,  B01J19/12 ,  C01B3/44 ,  C01B3/56 ,  C10L3/10

CPC分类号： B01J8/26 ,  B01J8/0278 ,  B01J8/1827 ,  B01J19/12 ,  C01B3/44 ,  C01B3/56 ,  C10L3/103 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2219/0875 ,  B01J2219/0892 ,  C01B2203/0233 ,  C01B2203/0425 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/1241 ,  C01B2203/1258 ,  C10L2290/542

摘要： Zero emission nested-loop (ZEN) reforming provides a scalable, eco-friendly process to produce high quality hydrogen at a relatively low operating cost. In one embodiment, a ZEN system comprises a reactor, a regenerator, and a photocatalytic reformer. During operation, the reactor receives a gas mixture and outputs hydrogen and catalyst adsorbed with carbon dioxide. The gas mixture is methane, steam, or hydrogen. Next, the regenerator receives the catalyst adsorbed with carbon dioxide and outputs carbon dioxide and desorbed catalyst. Next, the photocatalytic reformer receives carbon dioxide output by the regenerator and outputs methane and oxygen. The reactor receives at least some of the methane output by the photocatalytic reformer. By recycling methane in this way, the need for additional methane to fuel the system is reduced. The ZEN reforming system provides a novel technique to convert greenhouse gas emissions and carbon dioxide into oxygen and reusable methane gas.

公开(公告)号：US11738996B2

公开(公告)日：2023-08-29

申请号：US17397512

申请日：2021-08-09

申请人： GAS TECHNOLOGY INSTITUTE

发明人： Ganesan Subbaraman ,  Jeffrey A. Mays ,  Ronald J. Stanis

IPC分类号： C01B3/38 ,  F02C7/22 ,  F01K23/10 ,  B01D53/62 ,  B01D53/96 ,  B01D53/82 ,  B01D53/48 ,  F02C3/20 ,  B01D53/83 ,  C01B3/44

CPC分类号： C01B3/38 ,  B01D53/48 ,  B01D53/62 ,  B01D53/82 ,  B01D53/83 ,  B01D53/96 ,  C01B3/44 ,  F01K23/10 ,  F01K23/106 ,  F02C3/205 ,  F02C7/22 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2256/16 ,  B01D2257/504 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/84 ,  Y02C20/40 ,  Y02E20/18

摘要： Systems and methods for generating power using hydrogen fuel, such as derived from natural gas, are provided. Feed materials are introduced into a compact hydrogen generator to produce carbon dioxide, hydrogen gas and steam. Sorbent material within the compact hydrogen generator acts to absorb carbon dioxide, forming a used sorbent. Hydrogen gas and steam are separated from the used sorbent and passed to a power generator such as a hydrogen turbine to produce power. The used sorbent is introduced into a calciner and heated to desorb carbon dioxide and form a regenerated sorbent which can be recycled to the compact hydrogen generator.

公开(公告)号：US11673804B2

公开(公告)日：2023-06-13

申请号：US17212864

申请日：2021-03-25

申请人： L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude

发明人： Jean-Philippe Tadiello ,  Yue Chen

IPC分类号： C01B3/38 ,  B01D53/047

CPC分类号： C01B3/382 ,  B01D53/047 ,  C01B2203/0233 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/0495

摘要： Proposed is a process and a plant for production of pure carbon monoxide and hydrogen by steam reforming of hydrocarbons, preferably methane or naphtha, to afford a raw synthesis gas and subsequent, multistage workup, purification and fractionation of the raw synthesis gas to afford the target products, wherein the material streams obtained as by-products of the process chain are also to be advantageously utilized. This is achieved according to the invention by providing the recirculating compressor provided for recycling of the by-product material streams with a plurality of parallel, independently operable compressor stages.

公开(公告)号：US20170301938A1

公开(公告)日：2017-10-19

申请号：US15637253

申请日：2017-06-29

申请人： Thermochem Recovery International, Inc.

发明人： RAVI CHANDRAN

IPC分类号： H01M8/0612 ,  C01B3/02 ,  C01B3/12 ,  C01B3/44 ,  C10J3/46 ,  B01J21/04 ,  C01B3/50 ,  F02C3/28 ,  H01M8/124 ,  C10K1/02

CPC分类号： H01M8/0631 ,  B01J21/04 ,  C01B3/02 ,  C01B3/12 ,  C01B3/36 ,  C01B3/44 ,  C01B3/50 ,  C01B2203/0205 ,  C01B2203/0233 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0425 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/062 ,  C01B2203/066 ,  C01B2203/067 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1041 ,  C01B2203/1205 ,  C10J3/463 ,  C10J3/466 ,  C10J3/482 ,  C10J3/62 ,  C10J3/726 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/094 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/0976 ,  C10J2300/1215 ,  C10J2300/123 ,  C10J2300/1246 ,  C10J2300/1276 ,  C10J2300/1606 ,  C10J2300/1612 ,  C10J2300/1646 ,  C10J2300/1653 ,  C10K1/02 ,  F02C3/28 ,  F05D2220/32 ,  F05D2220/72 ,  H01M8/0618 ,  H01M8/0643 ,  H01M2008/1293 ,  Y02E20/16 ,  Y02E20/18 ,  Y02E20/185 ,  Y02E50/12 ,  Y02E60/50 ,  Y02E60/525 ,  Y02P20/52 ,  Y02T50/672

摘要： A direct carbonaceous material to power generation system integrates one or more solid oxide fuel cells (SOFC) into a fluidized bed gasifier. The fuel cell anode is in direct contact with bed material so that the H2 and CO generated in the bed are oxidized to H2O and CO2 to create a push-pull or source-sink reaction environment. The SOFC is exothermic and supplies heat within a reaction chamber of the gasifier where the fluidized bed conducts an endothermic reaction. The products from the anode are the reactants for the reformer and vice versa. A lower bed in the reaction chamber may comprise engineered multi-function material which may incorporate one or more catalysts and reactant adsorbent sites to facilitate excellent heat and mass transfer and fluidization dynamics in fluidized beds. The catalyst is capable of cracking tars and reforming hydrocarbons.

公开(公告)号：US09260302B2

公开(公告)日：2016-02-16

申请号：US14379039

申请日：2013-02-15

申请人： Stichting Energieonderzoek Centrum Nederland

发明人： Hendricus Adrianus Johannes Van Dijk ,  Paul Dean Cobden ,  Stéphane Walspurger ,  Jan Wilco Dijkstra

IPC分类号： C01B3/16 ,  C01B3/12 ,  C01B3/56

CPC分类号： C01B3/16 ,  C01B3/12 ,  C01B3/56 ,  C01B2203/0283 ,  C01B2203/0425 ,  C01B2203/043 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/063 ,  C01B2203/1205 ,  C01B2203/1258 ,  C01B2203/1264

摘要： High-pressure steam supply in hydrogen production process is made more efficient by water gas shift process which comprises, in alternating sequence: (a) a reaction stage wherein a feed gas comprising CO and H2O is fed into a water gas shift reactor containing a sorbent material capable of adsorbing H2O and CO2 and wherein a product gas issuing from the reactor is collected, (b) a regeneration stage wherein CO2 is removed from the reactor, (c) a loading stage, wherein H2O is fed into the reactor; wherein said feed gas mixture has a molar ratio of H2O to CO below 1.2, and the loading stage is performed at a lower pressure than the pressure of the reaction stage.

摘要翻译： 氢气生产过程中的高压蒸汽供应通过水煤气变换过程更为有效，其中水交换过程包括：（a）反应阶段，其中将包含CO和H 2 O的进料气体进料到含有吸附剂的水煤气变换反应器 能够吸收H 2 O和CO 2并且其中收集从反应器排出的产物气体的物质，（b）从反应器中除去CO 2的再生阶段，（c）加料阶段，其中将H 2 O进料到反应器中; 其中所述进料气体混合物的H 2 O与CO的摩尔比低于1.2，并且在比反应级的压力低的压力下进行加料阶段。

公开(公告)号：US20150322357A1

公开(公告)日：2015-11-12

申请号：US14803462

申请日：2015-07-20

申请人： Calix Limited

发明人： Mark Geoffrey Sceats ,  Julian Westley Dinsdale

IPC分类号： C10K1/00 ,  C10L3/10 ,  C10K1/32 ,  C10K3/00 ,  C10K1/26

CPC分类号： C10K1/005 ,  B01D53/62 ,  B01D2251/402 ,  B01D2251/404 ,  B01D2251/602 ,  B01D2253/1124 ,  B01D2253/304 ,  B01D2257/504 ,  B01J20/041 ,  B01J20/28004 ,  B01J20/3204 ,  B01J20/3433 ,  B01J20/3483 ,  B01J2220/42 ,  C01B3/16 ,  C01B3/384 ,  C01B32/50 ,  C01B2203/0233 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1241 ,  C01B2203/84 ,  C01B2203/86 ,  C10K1/26 ,  C10K1/32 ,  C10K1/34 ,  C10K3/00 ,  C10K3/04 ,  C10L3/08 ,  C10L3/104 ,  C10L2290/12 ,  C10L2290/542 ,  Y02C10/04 ,  Y02C10/08 ,  Y02P20/128 ,  Y02P20/152 ,  Y02P30/30

摘要： A method and system for processing an input fuel gas and steam to produce separate CO2 and output fuel gas streams. The method comprises the steps of using a decarboniser segment for reacting at least a solid sorbent reacts with the fuel gas and steam to remove carbon from the input fuel gas and to produce the output fuel gas stream in an exhaust gas from the decarboniser; using a calciner segment for reacting the solid sorbent from the decarboniser segment therein to release the CO2 into the CO2 gas stream; wherein CO2 partial pressures and temperatures in the decarboniser and calciner segments respectively are controlled such that the temperature in the decarboniser segment is higher than the temperature in the calciner.

摘要翻译： 一种用于处理输入燃料气体和蒸汽以产生单独的CO 2并输出燃料气流的方法和系统。 所述方法包括以下步骤：使用脱碳段进行反应，使至少一种固体吸附剂与燃料气体和蒸汽反应，以从输入燃料气体中除去碳，并产生来自脱碳装置的排气中的输出燃料气流; 使用煅烧段将来自其中的脱碳碳段的固体吸附剂反应以将CO 2释放到CO 2气流中; 其中控制脱碳装置和煅烧炉段中的CO 2分压和温度，使得脱碳分段中的温度高于煅烧炉中的温度。

公开(公告)号：US09168511B2

公开(公告)日：2015-10-27

申请号：US13885636

申请日：2011-11-15

申请人： Johannis Alouisius Zacharias Pieterse

发明人： Johannis Alouisius Zacharias Pieterse

IPC分类号： B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/745 ,  B01J37/00 ,  B01J37/08 ,  B01J37/16 ,  C01B3/26 ,  B01J23/89 ,  B01J23/00 ,  B01J23/755 ,  B01J37/03 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  C01B3/40 ,  C01B3/50

CPC分类号： B01J23/8946 ,  B01J21/02 ,  B01J21/10 ,  B01J23/005 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J37/033 ,  B01J37/036 ,  B01J37/084 ,  C01B3/40 ,  C01B3/50 ,  C01B3/501 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/041 ,  C01B2203/0425 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1217 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1619 ,  Y02P20/52

摘要： The invention provides a catalyst for the production of hydrogen by steam reforming. The catalyst is a porous catalyst which is based on at least aluminum oxide and preferably magnesium oxide, and further comprises boron and nickel. The porous catalyst comprises pores having an average pore size in the range of 0.1-50 nm. The activity of the catalyst may be further enhanced by addition of a noble metal such as Rh, Ru, Pd, Ir or Pt. The catalyst can be broadly used in hydrogen production processes, and is especially suitable for reforming using a membrane which is selective for a predetermined reaction product. Such process can be operated at relatively low temperatures of about 450-700° C.

摘要翻译： 本发明提供一种用于通过蒸汽重整生产氢的催化剂。 催化剂是基于至少氧化铝，优选氧化镁的多孔催化剂，并且还包含硼和镍。 多孔催化剂包含平均孔径在0.1-50nm范围内的孔。 通过添加诸如Rh，Ru，Pd，Ir或Pt的贵金属可以进一步提高催化剂的活性。 该催化剂可广泛用于制氢过程中，特别适用于使用对预定反应产物具有选择性的膜的重整。 这种方法可以在约450-700℃的较低温度下操作

公开(公告)号：US20150274524A1

公开(公告)日：2015-10-01

申请号：US14669583

申请日：2015-03-26

申请人： Georgia Tech Research Corporation

发明人： Andrei G. Fedorov ,  David M. Anderson

IPC分类号： C01B3/38 ,  B01J19/24

CPC分类号： C01B3/38 ,  C01B2203/0233 ,  C01B2203/0261 ,  C01B2203/041 ,  C01B2203/0425 ,  C01B2203/0475 ,  C01B2203/085 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1223 ,  C01B2203/1235 ,  C01B2203/1241

摘要： The present disclosure provides compositions including method of producing H2, variable volume reactors, methods of using variable volume reactors, and the like.

摘要翻译： 本公开提供了包括生产H 2的方法，可变体积反应器，使用可变体积反应器的方法等的组合物。