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公开(公告)号：US07951860B2
公开(公告)日：2011-05-31
申请号：US11632791
申请日：2005-07-22
IPC分类号： C08K5/5317
CPC分类号： C08K5/0091 , C08K3/22 , C08K5/5317 , C08K2201/008
摘要： Polymer composite materials having improved gas barrier properties are generally disclosed, along with process of making the same. The polymer composite materials can include phosphonate particles, oxide particles, and combinations thereof. For example, the particles can be metal phosphonate particles, synthetic oxide particles, or combinations thereof.
摘要翻译： 通常公开了具有改进的阻气性的聚合物复合材料及其制备方法。 聚合物复合材料可以包括膦酸盐颗粒，氧化物颗粒及其组合。 例如，颗粒可以是金属膦酸盐颗粒，合成氧化物颗粒或其组合。
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2.发明申请Process for Creating Composite Materials to Produce Polymer Nanocomposite Films that Exhibit Improved Light Fastness Properties 审中-公开制造复合材料生产聚合物纳米复合材料膜的方法，展示改善的耐光性能公开(公告)号：US20090089941A1
公开(公告)日：2009-04-09
申请号：US11911037
申请日：2006-04-10
CPC分类号： C08K5/5317
摘要： The present invention relates to new methods of producing polymer composite materials. More specifically, the invention involves a process in which layered materials including clays and other inorganic materials are dispersed into polymer systems to create polymer nanocomposite films. The resulting films exhibit improved resistance to fading when compared to polymer films that lack the additional layered materials.
摘要翻译： 本发明涉及生产聚合物复合材料的新方法。 更具体地，本发明涉及一种方法，其中包括粘土和其它无机材料的分层材料分散在聚合物体系中以产生聚合物纳米复合膜。 当与缺乏附加层状材料的聚合物膜相比时，所得膜具有改善的抗褪色性。
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公开(公告)号：US07438889B2
公开(公告)日：2008-10-21
申请号：US11165720
申请日：2005-06-24
IPC分类号： C01B3/26
CPC分类号： C01B3/38 , C01B3/56 , C01B2203/0244 , C01B2203/0425 , C01B2203/0475
摘要： A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.
摘要翻译： 一种生产氢的方法，包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下，在足以形成氢的复合金属氧化物的反应条件下，在制备步骤中使至少一种烃和蒸汽反应，其中复合金属 氧化物由公式<？in-line-formula description =“In-line Formulas”end =“lead”？>（A'
Ca x' x“x”x“”“”“”“Y”“”“”“” ＆lt;＆lt;＆lt;＆lt; /＆gt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt; 来自由Sr，Ba，第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu，Ni，Co，Cr和V中的至少一种元素; 0 <= x <= 1，0 <= x'<= 1，0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1，0 <= y'<= 1，0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。 -
公开(公告)号：US20060292066A1
公开(公告)日：2006-12-28
申请号：US11165720
申请日：2005-06-24
申请人： Guido Pez , Baolong Zhang , Hans-Conrad zur Loye
发明人： Guido Pez , Baolong Zhang , Hans-Conrad zur Loye
CPC分类号： C01B3/38 , C01B3/56 , C01B2203/0244 , C01B2203/0425 , C01B2203/0475
摘要： A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.
摘要翻译： 一种生产氢的方法，包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下，在足以形成氢的复合金属氧化物的反应条件下，在制备步骤中使至少一种烃和蒸汽反应，其中复合金属 氧化物由公式<？in-line-formula description =“In-line Formulas”end =“lead”？>（A'
Ca x' x“x”x“”“”“”“Y”“”“”“” ＆lt;＆lt;＆lt;＆lt; /＆gt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt; 来自由Sr，Ba，第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu，Ni，Co，Cr和V中的至少一种元素; 0 <= x <= 1，0 <= x'<= 1，0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1，0 <= y'<= 1，0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。 -
5.发明申请Layered Mixed-Metal Phosphonates for High Dielectric Strength polymer Nanocomposites 有权层状混合金属磷酸盐用于高介电强度聚合物纳米复合材料公开(公告)号：US20100216924A1
公开(公告)日：2010-08-26
申请号：US12705761
申请日：2010-02-15
IPC分类号： C08K5/5317 , C07F9/28 , C07F9/02
CPC分类号： C08K5/5317 , C07F9/3834
摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.
摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3 +或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。
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6.发明授权Methods of making layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites 有权制备用于高介电强度聚合物纳米复合材料的层状混合金属膦酸盐的方法公开(公告)号：US08247586B2
公开(公告)日：2012-08-21
申请号：US13329731
申请日：2011-12-19
IPC分类号： C07F9/02
CPC分类号： C08K5/5317 , C07F9/3834
摘要： Multi-metal phosphonates are generally provided. The multi-metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The multi-metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the multi-metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.
摘要翻译： 通常提供多金属膦酸盐。 多金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3-或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 多金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备多金属膦酸盐的方法。
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7.发明申请Methods of Making Layered Mixed-Metal Phosphonates for High Dielectric Strength Polymer Nanocomposites 有权制备层状混合金属磷酸盐用于高介电强度聚合物纳米复合材料的方法公开(公告)号：US20120095142A1
公开(公告)日：2012-04-19
申请号：US13329731
申请日：2011-12-19
IPC分类号： C08K5/5317 , C08L25/06 , C07F19/00
CPC分类号： C08K5/5317 , C07F9/3834
摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3−, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.
摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+或其组合; B是Ti4 +，Zr4 +，Al3-或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。
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8.发明授权Layered mixed-metal phosphonates for high dielectric strength polymer nanocomposites 有权用于高介电强度聚合物纳米复合材料的分层混合金属膦酸盐公开(公告)号：US08080600B2
公开(公告)日：2011-12-20
申请号：US12705761
申请日：2010-02-15
IPC分类号： C08K5/5333
CPC分类号： C08K5/5317 , C07F9/3834
摘要： Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, Co2+, Mn2+, Fe2+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.
摘要翻译： 通常提供混合金属膦酸盐。 混合金属膦酸盐通常可以具有：AB（RPO 3）3，其中A是Mg 2+，Ca 2+，Sr 2+，Ba 2+，Pb 2+，La 3+，Co 2+，Mn 2+，Fe 2+，或其组合; B是Ti4 +，Zr4 +，Al3 +或它们的组合; R为有机基团（例如，芳基，烷基，烯基等）。 混合金属膦酸盐可以与聚合物材料组合以形成聚合物膜。 还提供了通过使金属氧化物和有机膦酸组合和反应制备混合金属膦酸盐的方法。
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