Abstract:
3,4-DIHYDRO-1,2,3-OXATHIAZINONES ARE OBTAINED WHEN REACTING KETONES WITH ARYLOXYSULFONYL ISOCYANATES. THE COMPOUNDS HAVING LOW-MOLECULAR SUBSTITUENTS ARE ARTIFICIAL SWEETENING AGENTS AND THE DERIVATIVES HAVING HYDROPHOBIC SUBSTITUENTS ARE INTERFACIAL ACTIVE AGENTS. ALL OF THE NEW COMPOUNDS ARE ORGANIC INTERMEDIATES HAVING A PLURALITY OF REACTIVE GROUPS.
Abstract:
New 1-hydroxy-2-pyridones of the general formula IN WHICH R1 is alkyl of 1 to 17 carbon atoms, cycloalkyl of 5 to 8 carbon atoms, cyclohexylalkyl or phenalkyl both having 1 to 3 carbon atoms in the alkylene chain or Alpha -furyl, all of which may be substituted by halogen and R2 to R4 are hydrogen or lower alkyl or 2 adjacent substituents together form a trimethylene or tetramethylene chain, and in which R1 to R4 together contain at least 2 carbon atoms, are prepared by contacting unsaturated delta -keto esters or mixtures thereof with hydroxylamine and subjecting the products to cyclization. The compounds exhibit antimycotic properties.
Abstract:
POLY-B-AMIDES ARE PREPARED IN A TWO-PAHSE DISPERSION BY POLYMERIZING B-LACTAMS WHICH ARE UNSUBSTITUTED AT THE NITROGEN ATOM. ONE OF THE PAHSES CONSISTS OF AN ALIPHATIC OR A CYCLOALIPHATIC HYDROCARBON AND THE OTHER OF A SOLUTION OF THE LACTAM IN A HIGHLY POLAR SOLVENT. THE PREPARATION IS CARRIED OUT IN THE PRESENCE OF CATALYSTS, PROMOTERS AND EMULSIFIERS, THE POLY-B-AMIDES PRODUCED ARE SUITABLE FOR THE MANUFACTURE OF MOLDED ARTICLES, FILMS AND FILAMENTS.
IN WHICH ONE OF THE RADICALS R1 to R4 is substituted by an acryloyl or methacryloyl group are obtained from the corresponding 2-pyrone derivatives and acrylic or methacrylic acid or a derivative thereof. The compounds can be polymerized forming light-sensitive polymers which are cross-linked by the action of light and may be used in light-sensitive copying layers.