公开(公告)号：US10351494B1

公开(公告)日：2019-07-16

申请号：US15864730

申请日：2018-01-08

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Terris Yang ,  Daniel C. Merkel ,  Haluk Kopkalli ,  Gustavo Cerri ,  Yuon Chiu ,  Richard D. Horwath

IPC: B01D3/00 ,  B01D3/36 ,  C07C17/25 ,  C07C21/18 ,  C07C17/386 ,  C07C17/395

Abstract: The present disclosure provides various manufacturing processes for the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf or 1234yf). Such methods may allow for the improved yields, more economical processes, and waste reduction in the production of 1234yf and subsequent processes.

公开(公告)号：US09926244B2

公开(公告)日：2018-03-27

申请号：US15368027

申请日：2016-12-02

Applicant: Honeywell International Inc.

Inventor： Yuon Chiu ,  Stephen A. Cottrell ,  Hang T. Pham ,  Gustavo Cerri

IPC: C07C17/38 ,  C07C17/383 ,  C07C17/389 ,  C07C21/18

CPC classification number: C07C17/383 ,  C07C17/38 ,  C07C17/389 ,  C07C21/18

Abstract: The present disclosure provides separation processes that use azeotropic or azeotropic-like compositions of 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) that allow for improved recovery rates of 1-chloro-3,3,3-trifluoropropene during or after manufacturing processes. Such recovery or separation processes can utilize the unique properties of azeotropic or azeotropic-like composition with various combinations of separation techniques (e.g., distillation and decanting) that yield highly pure compositions of 1-chloro-3,3,3-trifluoropropene and simultaneously offer high yields of 1-chloro-3,3,3-trifluoropropene. Such highly pure compositions of 1-chloro-3,3,3-trifluoropropene may find useful applications in polymer technology as monomers or comonomers.

公开(公告)号：US20160332935A1

公开(公告)日：2016-11-17

申请号：US15088709

申请日：2016-04-01

Applicant: Honeywell International Inc.

Inventor： Stephen A. Cottrell ,  Gustavo Cerri ,  Yuon Chiu ,  Jennifer W. Mcclaine

IPC: C07C17/20

CPC classification number: C07C17/206 ,  Y02P20/125 ,  C07C19/08

Abstract: A process is described wherein otherwise unusable by-products from a process for the manufacture of trans HCFO-1233zd(E) are converted to a valuable product by introducing them into a process for the production of HFC-245fa. The process includes the catalytic hydrofluorination of a reaction mixture comprising the HCFO-1233zd production by-products.

Abstract translation: 描述了一种方法，其中来自用于制造反HCFO-1233zd（E）的方法的不可用的副产物通过将其引入用于生产HFC-245fa的方法而转化为有价值的产物。 该方法包括包含HCFO-1233zd生产副产物的反应混合物的催化氢氟化。

公开(公告)号：US20240425436A1

公开(公告)日：2024-12-26

申请号：US18825939

申请日：2024-09-05

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Gustavo Cerri ,  Mitchel Cohn ,  Selma Bektesevic

IPC: C07C21/18 ,  C07C17/25 ,  C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C07C17/395

Abstract: The present disclosure provides high purity E-1,3,3,3-tetrafluoropropene (HFO-1234ze). More specifically, the present disclosure provides E-1,3,3,3-tetrafluoropropene (HFO-234ze) in at least 99.99% purity, containing less than 3 ppm 1,1,3,3,3-pentafluoropropene (HFO-1225zc). The present disclosure further provides a method of making high purity E-1,3,3,3-tetrafluoropropene (HFO-1234ze).

公开(公告)号：US20240034705A1

公开(公告)日：2024-02-01

申请号：US18243657

申请日：2023-09-07

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Gustavo Cerri ,  Jinhua Yao ,  Jennifer W. McClaine

IPC: C07C17/23 ,  C07C17/383 ,  B01J27/132

CPC classification number: C07C17/23 ,  C07C17/383 ,  B01J27/132

Abstract: The present disclosure provides a method for conversion of a mixture of high-boiling fluorinated components comprising 1,1,3,3-tetrachloro-1-fluoropropane (HCFC-241fa), 1,3,3-trichloro-1,1-difluoropropane (HCFC-242fa), 1,1,3-trichloro-1,3-difluoropropane (HCFC-242fb), 3,3-dichloro-1,1,1-trifluoropropane (HCFC-243fa), 1,3-dichloro-1,1,3-trifluoropropane (HCFC-243fb), 3-chloro-1,1,1,3-tetrafluoropropane (HCFC-244fa), their isomers, and combinations thereof, to 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd). Heavy impurities, such as oligomers and other high boiling impurities, that are present may be purged during the process to prevent yield loss and reduction of catalyst efficacy.

公开(公告)号：US20240425435A1

公开(公告)日：2024-12-26

申请号：US18570415

申请日：2022-07-11

Applicant: Honeywell International Inc.

Inventor： Haluk Kopkalli ,  Haiyou Wang ,  Gustavo Cerri ,  Selma Bektesevic ,  Yuon Chiu ,  Christian Jungong ,  Richard D. Horwath ,  Daniel C. Merkel ,  Jennifer W. McClaine ,  Terris Yang ,  Richard Wilcox ,  Joshua Close ,  Rajendar Mallepally

IPC: C07C17/363 ,  B01J27/224

Abstract: The present disclosure provides an integrated process for producing trifluoroiodomethane (CF3I), in three steps: a) reacting a first reactant stream comprising hydrogen (H2) and iodine (I2) in the presence of a first catalyst to produce a first product stream comprising hydrogen iodide (HI); (b) reacting the first product stream with a second reactant stream comprising trifluoroacetyl chloride (TFAC) in the presence of a second catalyst to produce an intermediate product stream comprising trifluoroacetyl iodide (TFAI); and (c) reacting the intermediate product stream to produce a final product stream comprising trifluoroiodomethane. (CF3I).

公开(公告)号：US12122733B2

公开(公告)日：2024-10-22

申请号：US18243657

申请日：2023-09-07

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Gustavo Cerri ,  Jinhua Yao ,  Jennifer W. McClaine

IPC: C07C17/23 ,  B01J27/132 ,  C07C17/383

CPC classification number: C07C17/23 ,  B01J27/132 ,  C07C17/383

Abstract: The present disclosure provides a method for conversion of a mixture of high-boiling fluorinated components comprising 1,1,3,3-tetrachloro-1-fluoropropane (HCFC-241fa), 1,3,3-trichloro-1,1-difluoropropane (HCFC-242fa), 1,1,3-trichloro-1,3-difluoropropane (HCFC-242fb), 3,3-dichloro-1,1,1-trifluoropropane (HCFC-243fa), 1,3-dichloro-1,1,3-trifluoropropane (HCFC-243fb), 3-chloro-1,1,1,3-tetrafluoropropane (HCFC-244fa), their isomers, and combinations thereof, to 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd). Heavy impurities, such as oligomers and other high boiling impurities, that are present may be purged during the process to prevent yield loss and reduction of catalyst efficacy.

公开(公告)号：US11795125B2

公开(公告)日：2023-10-24

申请号：US18083238

申请日：2022-12-16

Applicant: Honeywell International Inc.

Inventor： Haiyou Wang ,  Gustavo Cerri ,  Jinhua Yao ,  Jennifer W. McClaine

IPC: C07C17/23 ,  C07C17/383 ,  B01J27/132

CPC classification number: C07C17/23 ,  B01J27/132 ,  C07C17/383

Abstract: The present disclosure provides a method for conversion of a mixture of high-boiling fluorinated components comprising 1,1,3,3-tetrachloro-1-fluoropropane (HCFC-241fa), 1,3,3-trichloro-1, 1-difluoropropane (HCFC-242fa), 1,1,3-trichloro-1,3-difluoropropane (HCFC-242fb), 3,3-dichloro-1,1,1-trifluoropropane (HCFC-243fa), 1,3-dichloro-1,1,3-trifluoropropane (HCFC-243fb), 3-chloro-1,1,1,3-tetrafluoropropane (HCFC-244fa), their isomers, and combinations thereof, to 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd). Heavy impurities, such as oligomers and other high boiling impurities, that are present may be purged during the process to prevent yield loss and reduction of catalyst efficacy.

公开(公告)号：US20230234901A1

公开(公告)日：2023-07-27

申请号：US18083237

申请日：2022-12-16

Applicant: Honeywell International Inc.

Inventor： Gustavo Cerri ,  Jinhua Yao

IPC: C07C17/20 ,  C09K5/04

CPC classification number: C07C17/204 ,  C09K5/045

Abstract: High boiling fluorinated by-products obtained from a manufacturing process of 1-chloro-3,3,3-trifluoropropene (HFO-1233zd) not only include components that can be used as a starting material or feedstock in the production of 1,1,1,3,3-pentafluoropropane (HFC-245fa), but also contain impurities that can be detrimental in the HFC-245fa process. A method of providing an improved composition from the high boiling by-products obtained from an HFO-1233zd manufacturing process reduces these impurities. The improved composition can be used as a starting material or feedstock for the production of HFC-245fa.

公开(公告)号：US20150005536A1

公开(公告)日：2015-01-01

申请号：US14377727

申请日：2013-02-08

Applicant: Honeywell International, Inc.

Inventor： Haiyou Wang ,  Hsueh S. Tung ,  Haluk Kopkalli ,  Yuon Chiu ,  Gustavo Cerri ,  Jeffrey Ball ,  Philip L. Da Prato ,  Xuehui Sun ,  Mario Joseph Nappa

IPC: C07C17/395 ,  C07C17/23

CPC classification number: C07C17/395 ,  B01J27/08 ,  C07C17/06 ,  C07C17/087 ,  C07C17/23 ,  C07C17/25 ,  C07C17/386 ,  C07C17/389 ,  Y02P20/582 ,  C07C19/10 ,  C07C21/18

Abstract: A method for forming 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising providing a dehydrochlorination starting material having relatively low concentrations of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), especially and preferable less than about 8.0% when the dehydrochlorination reaction utilizes no substantial amount of catalyst or catalyst comprising austenitic nickel-based materials.

Abstract translation: 一种形成2,3,3,3-四氟丙烯（HFO-1234yf）的方法，包括提供具有较低浓度的2-氯-3,3,3-三氟丙烯（HCFO-1233xf）的脱氯化氢原料，特别优选较少 当脱氯化氢反应不使用显着量的包含奥氏体镍基材料的催化剂或催化剂时，约为8.0％。