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公开(公告)号：US4020102A
公开(公告)日：1977-04-26
申请号：US616684
申请日：1975-09-25
IPC分类号： C07D311/78 , C07C51/15 , C07C51/48 , C07C69/76
摘要： 2-Hydroxynaphthalene-3-carboxylic acid is prepared by the reaction of sodium-.beta.-naphtholate with carbon dioxide, extraction of the reaction mixture in the presence of water with benzene or a benzene derivative in a specific ratio and separation of the end product from the extracted mixture. The product is a starting material for the production of dyes and a coupling component in the manufacture of azo dyes.
摘要翻译： 2-羟基萘-3-羧酸通过β-萘酚钠与二氧化碳的反应制备，在特定比例下用苯或苯衍生物在水存在下萃取反应混合物，并将最终产物与 提取的混合物。 该产品是用于生产染料的起始材料和偶氮染料制造中的偶联组分。
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公开(公告)号：US4032568A
公开(公告)日：1977-06-28
申请号：US616446
申请日：1975-09-24
IPC分类号： C07C51/15
CPC分类号： C07C51/15
摘要： 2-HYDROXYNAPHTHALENE-3-CARBOXYLIC ACID IS PRODUCED BY HEATING A MIXTURE OF POTASSIUM .beta.-NAPHTHOLATE AND SODIUM .beta.-NAPHTHOLATE TO A TEMPERATURE OF AT LEAST 180.degree. C, reacting it with carbon dioxide and treating the salt formed with an acid. The product is a dye intermediate, a coupling component of surface coating dyes and chrome dyes, and a developer for diazo dyes.
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公开(公告)号：US4002675A
公开(公告)日：1977-01-11
申请号：US547641
申请日：1975-02-06
IPC分类号： C07D311/78 , B01J27/00 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/15 , C07C65/11 , C07C67/00
CPC分类号： C07C51/15
摘要： A process for the manufacture of 2-hydroxy-naphthalene-3-carboxylic acid by heating sodium .beta.-naphtholate or a mixture of potassium .beta.-naphtholate and sodium .beta.-naphtholate with nitrogen compounds and/or polyphosphates containing at least 3 phosphorus atoms per molecule to a temperature of at least 180.degree. C, reaction with carbon dioxide and subsequent reaction of the resulting salt with acid. The 2-hydroxy-naphthalene-3-carboxylic acid obtainable by the process of the invention is a starting material for the manufacture of dyes, a coupling component for dye lakes and for chrome dyes, and a developer for diazotizable dyes.
摘要翻译： 通过加热β-萘酚钠或β-萘酚钠和β-萘酚钠的混合物与每个分子含有至少3个磷原子的氮化合物和/或多磷酸盐的混合物来制备2-羟基 - 萘-3-羧酸的方法 至至少180℃的温度，与二氧化碳反应，随后将所得盐与酸反应。 通过本发明方法可获得的2-羟基 - 萘-3-羧酸是用于制造染料的原料，用于染料湖和铬染料的偶联组分，以及用于重氮化染料的显色剂。
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公开(公告)号：US4002664A
公开(公告)日：1977-01-11
申请号：US476394
申请日：1974-06-05
IPC分类号： C07B61/00 , B01J23/00 , B01J31/04 , C07C20060101 , C07C67/00 , C07C227/00 , C07C227/04 , C07C229/54 , C07C99/00
CPC分类号： Y02P20/52
摘要： Dimethylaminobenzenecarboxylic acid esters are produced by reaction of nitrobenzenecarboxylic acid esters with formaldehyde and hydrogen under pressure in the presence of a hydrogenation catalyst containing metals of atomic numbers 24 to 29 and of a weak acid, at temperatures from 35.degree. to 150.degree. C. The products are starting materials for the synthesis of dyes, especially of crystal violets, and of reactive dyes and pesticides.
摘要翻译： 二甲基氨基苯甲酸酯是在含氢原子数为24〜29的氢化催化剂和弱酸的氢化催化剂的存在下，在35〜150℃的温度下，通过硝基苯甲酸酯与甲醛和氢气在压力下反应制得的。 是用于合成染料，特别是结晶紫罗兰和活性染料和农药的起始原料。
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公开(公告)号：US4038309A
公开(公告)日：1977-07-26
申请号：US643524
申请日：1975-12-22
IPC分类号： C07C51/15
CPC分类号： C07C51/15
摘要： The production of 2-hydroxynaphthalene-3-carboxylic acid by heating sodium .beta.-naphtholate in the presence of an araliphatic compound containing two aromatic radicals and/or in the presence of an aromatic ether having at least one aromatic radical etherified with an aliphatic, cycloaliphatic or araliphatic radical at a temperature of at least 200.degree. C, reaction with carbon dioxide and reaction of the salt formed with acid. The resultant 2-hydroxy-naphthalene-3-carboxylic acid is a starting material for the production of dyes, a coupling component of surface coating colors and chrome dyes and also a developer for diazotizable dyes.
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公开(公告)号：US4323510A
公开(公告)日：1982-04-06
申请号：US155189
申请日：1980-06-02
申请人： Helmut Hoch , Heinrich Hiller
发明人： Helmut Hoch , Heinrich Hiller
摘要： A vat dye obtained by heating a condensation product, which itself has been prepared by heating 3,9-di-(1-anthraquinonylamino)-benz[d,e]anthrone in an aluminum chloride/picoline or aluminum chloride/quinoline melt in the presence of sulfuryl chloride or thionyl chloride, in a melt of an alkali metal hydroxide in an alcohol or glycol or aqueous glycol.The dye gives deep clear brown dyeings having good fastness characteristics.
摘要翻译： 通过加热本身通过在氯化铝/甲基吡啶或氯化铝/喹啉熔体中加热3,9-（1-蒽醌基） - 苯并[d，e]蒽酮制得的冷凝产物， 在醇或二醇或水性二醇中的碱金属氢氧化物的熔体中存在磺酰氯或亚硫酰氯。 该染料产生深棕色染色，具有良好的牢度特性。
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7.发明授权Preparation of brilliant, transparent pigmentary bromo-isoviolanthrone of high tinctorial strength 失效具有高着色强度的辉煌透明色素溴 - 异戊醇的制备
公开(公告)号：US4298534A
公开(公告)日：1981-11-03
申请号：US127148
申请日：1980-03-04
申请人： Helmut Hoch , Erwin Hahn , Heinrich Hiller
发明人： Helmut Hoch , Erwin Hahn , Heinrich Hiller
CPC分类号： C09B67/0001 , C09B3/22
摘要： A process for the preparation of pigmentary forms of bromoisoviolanthrone, wherein the leuco compound is oxidized in an aqueous alkaline medium, in the presence of a surfactant, at from 10.degree. to 100.degree. C., with exposure to shearing forces.The pigment obtained gives full-shade colorations which are very transparent and very brilliant, while in white reductions very deep colorations are obtained.
摘要翻译： 一种用于制备颜料形式的溴异戊烷的方法，其中在表面活性剂存在下，在暴露于剪切力的情况下，在碱性介质中，无色化合物在10-100℃下被氧化。 获得的颜料得到非常透明和非常亮的全色调色，而在白色减少中获得非常深的着色。
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8.发明授权Preparation of triazinyl-bis-anthraquinone dyes by reacting aryldihalotriazine with amino anthraquinone 失效通过与氨基蒽醌反应ARYLDIHALOTRIAZINE来制备三亚氨基二硫代吗啉
公开(公告)号：US5210190A
公开(公告)日：1993-05-11
申请号：US768943
申请日：1991-10-22
申请人： Reinhard Helwig , Helmut Hoch , Gerhard Epple
发明人： Reinhard Helwig , Helmut Hoch , Gerhard Epple
CPC分类号： C09B1/467
摘要： Anthraquinone dyes I ##STR1## (Ar = aryl, A = anthraquinonyl) are prepared by reacting a aryldihalotriazine II ##STR2## (Hal = chlorine or bromine) with an aminoanthraquinone IIIA--NH.sub.2in an N--C.sub.1 --C.sub.4 -alkylpyrrolid-2-one or -piperid-2-one, N-di-C.sub.1 -C.sub.4 -alkylacetamide or -propionamide or urea derivatives of the formula IV ##STR3## (R = identical or different alkyl groups of from 1 to 4 carbon atoms which can also be linked together to form a 5- or 6-membered ring containing the urea group) as solvent.
摘要翻译： PCT No.PCT / EP90 / 01030 Sec。 371日期1991年10月22日 102（e）日期1991年10月22日PCT Filed 1990年6月27日PCT公布。 出版物WO91 / 00317 日本1991年1月10日。通过芳基二卤代三嗪II（Hal =氯或溴）与氨基蒽醌III A-NH 2的反应制备蒽醌染料I（Ar =芳基，A =蒽醌基） N-C 1 -C 4 - 烷基吡咯烷-2-酮或哌啶-2-酮，N-二-C 1 -C 4 - 烷基乙酰胺或 - 丙酰胺或式IV的脲衍生物（R =相同或不同的烷基 1至4个碳原子，其也可以连接在一起形成含有脲基团的5-或6-元环）作为溶剂。
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9.发明授权Preparation of 1-amino-4-hydroxy-2-(6'-hydroxyhexoxy)-anthraquinone 失效1-氨基-4-羟基-2-（6'-羟基己氧基） - 蒽醌的制备
公开(公告)号：US4916244A
公开(公告)日：1990-04-10
申请号：US230451
申请日：1988-08-10
申请人： Helmut Hoch
发明人： Helmut Hoch
CPC分类号： C09B1/503
摘要： 1-Amino-2-(6'-hydroxyhexoxy)-4-hydroxyanthraquinone (I) is prepared from the corresponding 2-phenoxy- or 2-halo-anthraquinone compound and 1,6-hexanediol with or without a phenol in the presence of an alkaline agent at elevated temperatures by reacting, per mole of the anthraquinone compound, from 2 to 6 moles of 1,6-hexanediol in the presence of ethylene oxide adducts on phenols or alkanols and/or polyethylene glycols at from 125.degree. to 135.degree. C. and then heating the resulting reaction mixture at from 140.degree. to 150.degree. C., in the course of which the stage 1 byproducts, namely the 1',6'-bis(1-amino-4-hydroxyanthraquinonyloxy)hexane diether is cleaved into (I), leaving a diether level of .ltoreq.2% by weight in (I).
摘要翻译： 由相应的2-苯氧基 - 或2-卤代蒽醌化合物和1,6-己二醇在有或没有苯酚存在下制备1-氨基-2-（6'-羟基己氧基）-4-羟基蒽醌（I） 在125〜135℃下，在环氧乙烷加成物存在下，在酚类或链烷醇和/或聚乙二醇的存在下，通过使每摩尔蒽醌化合物2〜6摩尔的1,6-己二醇反应， 然后在140℃至150℃下加热所得反应混合物，其中阶段1副产物即1'，6'-双（1-氨基-4-羟基蒽醌氧基）己烷二醚为 切割成（I），在（I）中留下重量百分比的二醚水平。
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10.发明授权Preparation of transparent pigmentary forms of 4,4',7,7'-tetrachlorothioindigo 失效制备4,4'，7,7'-四氯硫靛素的透明色素形式
公开(公告)号：US4332955A
公开(公告)日：1982-06-01
申请号：US137955
申请日：1980-04-07
申请人： Helmut Hoch , Erwin Hahn , Heinrich Hiller
发明人： Helmut Hoch , Erwin Hahn , Heinrich Hiller
IPC分类号： C09B7/10 , C09B67/28 , C07D333/64
CPC分类号： C09B7/10 , C09B67/0077
摘要： A transparent pigmentary form of 4,4',7,7'-tetrachlorothioindigo is prepared by oxidizing the leuco compound of tetrachlorothioindigo in aqueous alkaline suspension, in the presence of a dithionite, at from 20.degree. to 100.degree. C., with simultaneous exposure to shearing forces. Preferably, the oxidation is carried out in the presence of a surfactant.The pigment obtained gives brilliant, transparent full-shade colorations, while white reductions have a deep pure reddish hue.
摘要翻译： 通过在20℃至100℃下在连二亚硫酸盐存在下，将水性碱性悬浮液中的四氯硫靛素的无色化合物氧化，同时曝光制备4,4'，7,7'-四氯硫靛素的透明颜料形式 剪力。 优选地，氧化在表面活性剂的存在下进行。 获得的颜料产生了辉煌，透明的全色调，而白色减少具有深的纯红色色调。
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