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公开(公告)号：US4154825A
公开(公告)日：1979-05-15
申请号：US745900
申请日：1976-11-29
申请人： Harold E. Aller , Horst O. Bayer , Janet Ollinger
发明人： Harold E. Aller , Horst O. Bayer , Janet Ollinger
IPC分类号： C07F9/24 , C07F9/553 , C07F9/6509 , C07F9/655 , A01N9/36
CPC分类号： C07F9/65515 , C07F9/2454 , C07F9/5532 , C07F9/650958
摘要： This invention relates to novel phosphoramidates of the formula: ##STR1## wherein A is an optionally substituted (C.sub.6 -C.sub.10) aryl group;R is a hydrogen atom, a (C.sub.1 -C.sub.6) alkyl group, a di(C.sub.1 -C.sub.4) alkylamino group, a (C.sub.4 -C.sub.6) cycloamino group, a (C.sub.1 -C.sub.6) alkoxy group, a (C.sub.1 -C.sub.6) alkylthio group or a cyano group;R.sup.1 is (a) an optionally substituted (C.sub.1 -C.sub.6) alkyl group;(b) an optionally substituted (C.sub.3 -C.sub.8) cycloalkyl group;(c) an optionally substituted (C.sub.3 -C.sub.6) alkenyl group;(d) an optionally substituted (C.sub.5 -C.sub.8) cycloalkenyl group;(e) a (C.sub.3 -C.sub.6) alkynyl group; or(f) an optionally substituted aralkyl group of up to 11 carbon atoms;R.sup.2 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.3 is a (C.sub.1 -C.sub.6) alkyl group; andX is an oxygen or sulfur atom;To compositions containing them and to methods of using them to control certain harmful pests.
摘要翻译： 本发明涉及下式的新型氨基磷酸酯：其中A是任选取代的（C 6 -C 10）芳基; R是氢原子，（C1-C6）烷基，二（C1-C4）烷基氨基，（C4-C6）环氨基，（C1-C6）烷氧基，（C1-C6）烷硫基 基团或氰基; R 1是（a）任选取代的（C 1 -C 6）烷基; （B）选择性取代的（C 3 -C 8）环烷基; （C）选择性取代的（C 3 -C 6）烯基; （D）选择性取代的（C5-C8）环烯基; （E）A（C 3 -C 6）炔基; 或（F）最多11个碳原子的可选择的阿拉基尔集团; R2是（C1-C6）烷基; R3是（C1-C6）烷基; X为氧或硫原子; 包含它们的组合物以及使用它们控制某些有害物质的方法。
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公开(公告)号：US4263288A
公开(公告)日：1981-04-21
申请号：US964214
申请日：1978-11-27
申请人： Janet Ollinger , Horst O. Bayer
发明人： Janet Ollinger , Horst O. Bayer
CPC分类号： A01N57/30 , C07F9/2458
摘要： This invention relates to novel phosphoramidothioates of the formula: ##STR1## wherein A is optionally substituted (C.sub.6 -C.sub.10) aryl;R is hydrogen or (C.sub.1 -C.sub.6) alkyl;R.sup.1 is(a) optionally substituted (C.sub.1 -C.sub.6) alkyl,(b) (C.sub.3 -C.sub.8) cycloalkyl,(c) optionally substituted (C.sub.3 -C.sub.6) alkenyl,(d) (C.sub.3 -C.sub.6) alkynyl, or(e) optionally substituted (C.sub.7 -C.sub.11) aralkyl;R.sup.2 is(a) (C.sub.1 -C.sub.6) alkylthio,(b) (C.sub.6 -C.sub.10) aryloxy, or(c) NZ'Z"; whereinZ' is hydrogen or (C.sub.1 -C.sub.6) alkyl; andZ" is hydrogen, (C.sub.1 -C.sub.6) alkyl, (C.sub.3 -C.sub.6) alkenyl, di(C.sub.1 -C.sub.3) alkylamino, 2-ethylthioethyl, 2-methoxyethyl or (C.sub.1 -C.sub.4) alkoxycarbonylalkyl (C.sub.1 -C.sub.4);R.sup.3 is unsubstituted (C.sub.1 -C.sub.6) alkyl; andX is oxygen or sulfur;to compositions containing them and to methods of using them to control certain harmful pests.
摘要翻译： 本发明涉及下式的新型氨基硫代磷酸酯：其中A是任选取代的（C 6 -C 10）芳基; R是氢或（C 1 -C 6）烷基; 或（c）任选取代的（C 3 -C 6）烯基，（d）（C 3 -C 6） 任选取代的（C 7 -C 11）芳烷基; R2是（a）（C1-C6）烷硫基，（b）（C6-C10）芳氧基或（c）NZ'Z“ 其中Z'为氢或（C1-C6）烷基; （C 1 -C 4）烷基，（C 3 -C 6）烯基，二（C 1 -C 3）烷基氨基，2-乙硫基乙基，2-甲氧基乙基或（C 1 -C 4）烷氧基羰基烷基（C 1 -C 4） R3是未取代的（C1-C6）烷基; X为氧或硫; 含有它们的组合物以及使用它们来控制某些有害害虫的方法。
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公开(公告)号：US4315870A
公开(公告)日：1982-02-16
申请号：US102471
申请日：1979-12-11
申请人： Janet Ollinger
发明人： Janet Ollinger
CPC分类号： C07F9/2487 , A01N57/28 , A01N57/30 , A01N57/36 , C07F9/2408 , C07F9/2462 , C07F9/2479
摘要： Disclosed are compounds of the formula: ##STR1## wherein R.sup.1 isa hydrogen atom;an unsubstituted or substituted alkyl group;an alkynyl group;an alkenyl group;an alkyldienyl;a cycloalkyl group;an alkoxycarbonyl group;an unsubstituted or substituted phenyl group;an unsubstituted or substituted phenylalkyl group;R.sup.2 is an unsubstituted alkyl group;R.sup.3 is a hydrogen atom, an alkyl group, or an alkenyl group;R.sup.4 is a hydrogen atom, an alkyl group or additionally when R.sup.3 and R.sup.5 are not taken together to form a heterocycle, an alkenyl group;R.sup.5 isa hydrogen atom;an unsubstituted or substituted alkyl group;an alkynyl group;an alkenyl group;a cycloalkyl group;an unsubstituted or substituted phenyl group;an unsubstituted or substituted phenyl (C.sub.1 -C.sub.5) alkyl group, orR.sup.3 and R.sup.5 can be taken together to form a heterocyclic ring of the formula ##STR2## wherein Z is a --CH.sub.2 CH.sub.2 -- group, a --CH.sub.2 CH.sub.2 CH.sub.2 -- group, or a --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 -- group; andX and X.sup.1 are independently an oxygen atom or a sulfur atom;as well as compositions containing them, and to methods of using them to control certain harmful pests.
摘要翻译： 公开了下式的化合物：其中R 1是氢原子; 未取代或取代的烷基; 炔基; 烯基; 烷基二烯基; 环烷基; 烷氧基羰基; 未取代或取代的苯基; 未取代或取代的苯基烷基; R2是未取代的烷基; R3是氢原子，烷基或烯基; R4是氢原子，烷基或另外当R3和R5不在一起形成杂环时，烯基; R5是氢原子; 未取代或取代的烷基; 炔基; 烯基; 环烷基; 未取代或取代的苯基; 未取代或取代的苯基（C 1 -C 5）烷基或R 3和R 5可以一起形成下式的杂环其中Z是-CH 2 CH 2 - 基，-CH 2 CH 2 CH 2 - 基或 - CH2CH2CH2CH2- X和X 1独立地为氧原子或硫原子; 以及含有它们的组合物，以及使用它们控制某些有害害虫的方法。
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公开(公告)号：US4614734A
公开(公告)日：1986-09-30
申请号：US624310
申请日：1984-06-25
CPC分类号： C07F9/65318 , A01N57/26 , C07F9/2408 , C07F9/2487
摘要： This invention relates to phosphoroamidothioate and phosphoroamidodithioate compounds, to compositions thereof which are useful as pesticides, for example, as athropodicides (that is, insecticides and acaricides), nematocides, and fungicides, and to a method of controlling pests, such as insects, acarids, nematodes, and fungi. The compounds of the invention are effective against soil insects, especially the corn rootworm, when applied by soil application techniques and are also effective when applied to agricultural plants and other plants by foliar application techniques.
摘要翻译： 本发明涉及磷酰氨基硫代磷酸酯和氨基二硫代磷酸酯化合物及其组合物，它们可用作农药，例如作为杀草剂（即杀虫剂和杀螨剂），杀线虫剂和杀真菌剂，以及控制害虫如昆虫，螨类的方法 ，线虫和真菌。 当通过土壤施用技术施用时，本发明的化合物对于土壤昆虫，特别是玉米根虫有效，并且在通过叶面施用技术应用于农业植物和其它植物时也是有效的。
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公开(公告)号：US4468388A
公开(公告)日：1984-08-28
申请号：US380577
申请日：1982-05-21
申请人： Janet Ollinger
发明人： Janet Ollinger
CPC分类号： A01N57/26
摘要： There are disclosed N-acyl and N-thioacyl phosphorodiamido(di)thioates having pesticidal activity when applied to pests or to loci to be freed from the pests by foliar or systemic application techniques.
摘要翻译： 公开了当应用于害虫时具有杀虫活性的N-酰基和N-硫代酰基硫代氨基（二）硫代酸酯，或通过叶面或全身施用技术从害虫中除去的位点。
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6.发明授权N-(Substituted)aminocarbonyl O,S-dialkyl phosphoramido(di)thioates and method of controlling arthropods 失效N-（取代）氨基羰基O，S-二烷基磷酰氨基（二）硫酸酯和控制节肢动物的方法
公开(公告)号：US4059697A
公开(公告)日：1977-11-22
申请号：US662746
申请日：1976-03-01
申请人： Janet Ollinger
发明人： Janet Ollinger
CPC分类号： C07F9/2487 , A01N57/28 , A01N57/30 , C07F9/2458
摘要： This invention relates to novel phosphoramido(di)thioates of the formula: ##STR1## wherein A isA. a halogen atom,B. a cyano group,C. a (C.sub.1 -C.sub.6) alkoxy group,D. a (C.sub.1 -C.sub.6) alkylthio group,E. a (C.sub.1 -C.sub.6) alkylcarbonyloxy group,F. a phenoxy group, orG. a phenylthio group;R.sup.1 isA. a (C.sub.1 -C.sub.12) alkyl group,B. a (C.sub.3 -C.sub.8) cycloalkyl group,C. an optionally substituted aralkyl group of up to 11 carbon atoms, orD. an optionally substituted (C.sub.6 -C.sub.10) aryl group;R.sup.2 is a hydrogen atom or a (C.sub.1 -C.sub.4) alkyl group when A is a halogen atom, and a hydrogen atom when A is other than a halogen atom;R.sup.3 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.4 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.5 and R.sup.6 are independently hydrogen atoms or (C.sub.1 -C.sub.4) alkyl groups; andY is an oxygen or sulfur atom;To compositions containing them, to processes for preparing them, and to methods of utilizing them as arthropodicides.
摘要翻译： 本发明涉及下式的新型亚氨基酰氨基（二）硫酸酯：其中A为A。卤素原子，B.氰基，C.A（C 1 -C 6）烷氧基，D.A（C 1 -C 6 ）烷硫基，E.A（C 1 -C 6）烷基羰氧基，F.A苯氧基，或G.苯基硫基; R1是A（C1-C12）烷基，B.A（C3-C8）环烷基，C.一种可选择性取代的至多11个碳原子的芳烷基，或D.可选地取代的（C6-C10）芳基 组; 当A为卤素原子时，R2为氢原子或（C1-C4）烷基，当A为卤原子时，为氢原子; R3是（C1-C6）烷基; R4是（C1-C6）烷基; R5和R6独立地为氢原子或（C1-C4）烷基; Y是氧或硫原子; 包含它们的组合物，制备它们的方法以及使用它们作为抗坏血酸的方法。
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公开(公告)号：US4544553A
公开(公告)日：1985-10-01
申请号：US391072
申请日：1982-06-22
CPC分类号： C07F9/65318 , A01N57/26 , C07F9/2408 , C07F9/2487
摘要： This invention relates to phosphoroamidothioate and phosphorcamidodithioate compounds, to compositions thereof which are useful as pesticides. For example, as arthropodicides (that is, insecticides and acaricides), nematocides, and fungicides, and to a method of controlling pests, such as insects, acarids, nematodes, and fungi. The compounds of the invention are effective against soil insects, especially the corn rootworm, when applied by soil application techniques and are also effective when applied to agricultural plants and other plants by foliar application techniques.
摘要翻译： 本发明涉及磷酰氨基硫代磷酸酯和氨基二硫代磷酸酯化合物，其用作农药的组合物。 例如，作为杀虫剂（即杀虫剂和杀螨剂），杀线虫剂和杀真菌剂，以及防治害虫如昆虫，螨虫，线虫和真菌的方法。 当通过土壤施用技术施用时，本发明的化合物对于土壤昆虫，特别是玉米根虫有效，并且在通过叶面施用技术应用于农业植物和其它植物时也是有效的。
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公开(公告)号：US4468389A
公开(公告)日：1984-08-28
申请号：US380576
申请日：1982-05-21
申请人： Janet Ollinger
发明人： Janet Ollinger
CPC分类号： C07F9/2483 , A01N57/28 , A01N57/30
摘要： There are disclosed N-sulfonyl phosphorodiamido(di)thioates having pesticidal activity, especially miticidal activity against mites possessing resistance to organophosphorous compounds, when applied to pests or to loci to be freed from the pests by foliar or systematic application techniques.
摘要翻译： 已经公开了具有杀虫活性的N-磺酰基磷酰二氨基（二）硫酸盐，特别是当应用于害虫或通过叶面或系统施用技术从害虫中除去的位点时，具有抗有机磷化合物抗性的螨虫的杀螨活性。
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公开(公告)号：US4468387A
公开(公告)日：1984-08-28
申请号：US380575
申请日：1982-05-21
申请人： Janet Ollinger
发明人： Janet Ollinger
CPC分类号： A01N57/28 , A01N57/30 , C07F9/2487
摘要： There are disclosed N-sulfonyl N'-oxalate phosphorodiamido(di)thioates having pesticidal activity, especially miticidal activity against mites possessing resistance to organo-phosphorous compounds, when applied to pests or to loci to be freed from the pests by foliar or systemic application techniques.
摘要翻译： 公开了具有杀虫活性的N-磺酰基N'-草酸二亚氨基（二）硫代磷酸酯，特别是对具有抗有机磷化合物的抗螨剂的杀螨活性，当应用于害虫或通过叶面或系统应用从害虫中除去的位点时 技术
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