摘要:
The present invention relates to an amidothiophosphate derivative represented by the formula II: ##STR1## in which R.sub.1 is a methyl group or an ethyl group; R.sub.2 is a n-propyl group or a sec-butyl group; R.sub.3 is a C.sub.1 -C.sub.4 alkoxy group, a C.sub.1 -C.sub.4 alkylthio group, phenyl group or a phenoxy group; and n represents 1 or 2, and an insecticide, a nematocide and an acaricide containing the same as an active ingredient.
摘要:
A compound of Formula (I):(I) R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y=X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 where R.sup.5 is alkyl or aryl, and a is 1 or 2(B) --S(R.sup.6)(O).sub.bwhere R.sup.6 is alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)--wherein the subtituents are independently selected as in Formula (I) above.
摘要翻译:式(I)化合物:(I)R1(CA = CA1)xC(= X)NR2R3其中R1是任选被选自烷氧基,烯基,炔基,烯氧基,炔氧基,芳基,芳氧基,芳基烷氧基和芳氧基的基团取代的烷基, 稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢,烷基或卤代烷基; R2是烷基,烯基或环烷基,其中任何一个可以被卤素,烯基,烷基,环烷基,炔基,二氧戊环基烷基或烷氧基取代; (A)-Y = X1-(R4)a其中X1为O或S,Y为磷或碳,R4为氢,烷基,烷氧基,酰基或CO2R5 其中R 5是烷基或芳基,且a是1或2(B)-S(R 6)(O)b,其中R 6是烷基,芳基,芳氧基,烷氧基,硫代烷氧基,硫代芳基,链炔基,烷硫基或芳硫基,b是0, 1或2(C)-S(O)cNR 7 R 8,其中c是0,1或2,R 7是-COR 9或-CO 2 R 9,其中R 9是氢,烷基或氟原子,定义的基团(A)或(B) 或者被酰基,烷氧羰基或氰基取代的烷基,R8是烷基(D)R1-(CA = CA1)nC(= X)N(R2) - ,其中取代基如上式(I)所示独立选择。
摘要:
The soil life of herbicidally active thiolcarbamates is extended by employing in combination therewith certain organophosphorus compounds having the formula 3 ##STR1## in which R.sup.4 is selected from the group consisting of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 alkoxy; R.sup.5 is selected from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.2 -C.sub.4 alkenylthio and C.sub.2 -C.sub.4 alkynylthio; R.sup.6 is selected from the group consisting of hydrogen , C.sub.1 -C.sub.10 alkyl, C.sub.5 -C.sub.7 cycloalkyl and phenyl; and R.sup.7 is selected from the group consisting of C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.10 alkoxy, C.sub.1 -C.sub.10 alkylthio, C.sub.2 -C.sub.6 alkynoxy, C.sub.2 -C.sub.5 carbalkoxy, phenyl, phenoxy, (C.sub.1 -C.sub.3 alkoxy)phenyl, benzyl and benzyloxy, all optionally substituted with up to two halogen atoms.
摘要:
Phosphoramidates and salts and salt complexes useful as anthelmintics are disclosed. The products are prepared by treating an aminobenzene with an appropriately substituted isothiocyanatoate.
摘要:
The invention includes phosphonylureidobenzene compounds of the general formula ##STR1## or pharmaceutically acceptable salts in whichR.sup.1 and R.sup.2 are identical or different and represent an alkyl group, orR.sup.1 and R.sup.2 together represent a dimethylene group, a trimethylene group or a tetramethylene group,X and Y are identical or different and represent an oxygen atom or a sulphur atom andR.sup.3 and R.sup.4 are identical or different and represent an alkyl group, orR.sup.3 and R.sup.4 together represent a trimethylene group or a tetramethylene group, orR.sup.3 and R.sup.4, together with the carbon atom and nitrogen atom between them, form a thiazolidine ring system, which are used medicinally as parasiticides.The compounds are particularly effective in combatting helminths in carnivores.Also included in the invention are pharmaceutical compositions containing said phosphonylureidobenzene compounds and methods for the treatment of warm-blooded animals by administering said compounds or compositions.
摘要:
There is provided a method for controlling the larvae of heel flies which parasitize ruminants and other warm-blooded animals by administering to said animals an effective amount of an unsubstituted or substituted phenylene bis[imino(thio)carbonyl]diphosphor(thio)amidic acid ester.
摘要:
O-(2-Carbisopropoxyphenyl)-thiono-phosphoric(phosphonic) acid ester-amides and ester-imides of the formula ##SPC1##In whichR is lower alkyl or alkoxy,R' is hydrogen, andR" is a formyl or acetyl radical, orR' and R" conjointly form an aminomethylene, monoalkylaminomethylene or dialkylaminomethylene radical with 1 to 6 carbon atoms in each alkyl chain, or a phenylaminomethylene or heterocyclic aminomethylene radical, or a lower alkoxymethylene radical,Which possess insecticidal and acaricidal properties.
摘要:
S-ammonium (or metal) salts of N-acyl-Ohydrocarbylphosphoroamidothioates horoamidothioates are prepared by reacting an N-acyl-O,O-dihydrocarbylphosphoroamidothioate with an ammonium (or metal) sulfide or polysulfide. The S-ammonium (or metal) salts can be alkylated to produce an O-hydrocarbyl-Shydrocarbyl-N-acylphosphoroamidothioate.
摘要:
S-ALKALI METAL S-AMMONIUM SALTS OF N-ACYL-O-HYDROCARBYLPHOSPHOROAMIDOTHIOATES ARE PREPARED BY REACTING AN N-ACYL-O,O-DIHYDROCARBYLPHOSPHOROAMIDOTHIOATE WITH AN ALKALI METAL MERCAPTIDE OR AMMONIUM MERCAPTIDE.