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公开(公告)号：US4011252A
公开(公告)日：1977-03-08
申请号：US606280
申请日：1975-08-20
CPC分类号： C07C51/27
摘要： A process for producing fatty acids from C.sub.20 to C.sub.30 normal alkanes by air oxidizing the alkanes, followed by hydrogenating the product of the air oxidation and then oxidizing the hydrogenated product by nitric acid oxidation. The crude fatty acid product may be purified by a second hydrogenation to convert nitrogen impurities to amines and removal of the amines.
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公开(公告)号：US3947563A
公开(公告)日：1976-03-30
申请号：US512598
申请日：1974-10-07
申请人： Edward F. Dougherty
发明人： Edward F. Dougherty
IPC分类号： C07C29/149 , C01B13/14 , C01D1/00 , C07C29/00
CPC分类号： C07C29/149 , C12C11/02
摘要： Process for hydrogenolysis of an alkali metal or an alkaline earth metal salt of formic acid so as to produce methanol and a metal hydroxide corresponding to the formic acid salt wherein a catalyst of cobalt, rhenium, ruthenium, palladium, platinum or mixtures thereof is used.
摘要翻译： 用于氢解甲酸的碱金属或碱土金属盐以制备对应于甲酸盐的甲醇和金属氢氧化物的方法，其中使用钴，铼，钌，钯，铂或其混合物的催化剂。
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公开(公告)号：US3933930A
公开(公告)日：1976-01-20
申请号：US555920
申请日：1975-03-06
IPC分类号： C07C29/136 , C07B61/00 , C07C27/00 , C07C29/149 , C07C35/14 , C07C51/31 , C07C51/487 , C07C67/00 , C07C67/08 , C07C29/00
CPC分类号： C07C51/487 , C07C29/149 , C07C51/313 , C07C67/08 , Y02P20/582
摘要： In the production of 1,6-hexanediol by oxidation of cyclohexane to produce an acidic oxidation product comprising adipic acid, followed by esterification of the acidic oxidation product and a subsequent hydrogenolysis of the ester, the improvement which comprises a prehydrogenation of the acidic oxidation product prior to esterification thereof.
摘要翻译： 在通过环己烷氧化生产1,6-己二醇以产生包含己二酸的酸性氧化产物，随后酸化氧化产物的酯化和酯的随后氢解，其改进包括酸性氧化产物的预氢化 在其酯化之前。
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公开(公告)号：US4981662A
公开(公告)日：1991-01-01
申请号：US531619
申请日：1990-06-01
申请人： Edward F. Dougherty
发明人： Edward F. Dougherty
IPC分类号： C01B15/037 , C09K15/30
CPC分类号： C01B15/037
摘要： A stable hydrogen peroxide composition is provided of from 1% to 52% by weight hydrogen peroxide and 1,10-phenanthroline. The composition may contain other conventional additives suitable for stabilizing hydrogen peroxide.
摘要翻译： 提供了1％至52％重量的过氧化氢和1,10-菲咯啉的稳定的过氧化氢组合物。 组合物可以含有适用于稳定过氧化氢的其它常规添加剂。
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公开(公告)号：US3985814A
公开(公告)日：1976-10-12
申请号：US554251
申请日：1975-02-28
申请人： Edward F. Dougherty
发明人： Edward F. Dougherty
IPC分类号： C07C29/149 , C07C29/00
CPC分类号： C07C29/149
摘要： A process for the conversion of carboxyl groups to methylol groups by hydrogenolysis utilizing a platinum catalyst.
摘要翻译： 通过使用铂催化剂的氢解将羧基转化成羟甲基的方法。
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6.发明授权公开(公告)号：US06207859B1
公开(公告)日：2001-03-27
申请号：US09404415
申请日：1999-09-23
申请人： Leon B. Levy , Edward F. Dougherty , Charles C. Hobbs, Jr. , Jerome F. Perez , Mark O. Scates , Madan Singh
发明人： Leon B. Levy , Edward F. Dougherty , Charles C. Hobbs, Jr. , Jerome F. Perez , Mark O. Scates , Madan Singh
IPC分类号： C07C5702
摘要： A process for inhibiting free-radical polymerization of an alpha,beta-unsaturated (&agr;,&bgr;-unsaturated) carboxylic acid, and for providing desired grade &agr;,&bgr;-unsaturated carboxylic acid for use following storage and transport is described herein. In particular, bulk storage and shipment such as with overseas transport is described. The process comprises combining the &agr;,&bgr;-unsaturated carboxylic acid with a phenolic inhibitor and a coinhibitor to form an inhibited mixture, storing the inhibited mixture, transporting the inhibited mixture, and removing the coinhibitor to provide the desired grade &agr;,&bgr;-unsaturated carboxylic acid for use. In preferred embodiments, the &agr;,&bgr;-unsaturated carboxylic acid is acrylic acid, the phenolic inhibitor is p-methoxyphenol, the coinhibitor is manganese cation, and removal of the coinhibitor is carried out using an ion exchange resin.
摘要翻译： 本文描述了一种用于抑制α，β-不饱和（α，β-不饱和）羧酸的自由基聚合以及用于在储存和运输之后用于提供所需的等级α，β-不饱和羧酸的方法。 具体来说，大量存储和运输如海运。 该方法包括将α，β-不饱和羧酸与酚类抑制剂和联合抑制剂组合以形成抑制的混合物，储存被抑制的混合物，运输被抑制的混合物，以及除去联合抑制剂以提供所需的等级α，β-不饱和羧酸 酸使用。 在优选的实施方案中，α，β-不饱和羧酸是丙烯酸，酚类抑制剂是对甲氧基苯酚，联合抑制剂是锰阳离子，并且使用离子交换树脂进行去除联合抑制剂。
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公开(公告)号：US06180804B2
公开(公告)日：2001-01-30
申请号：US09151145
申请日：1998-09-10
申请人： Edward F. Dougherty
发明人： Edward F. Dougherty
IPC分类号： C07C4600
CPC分类号： C07C49/747 , C01B15/023 , C07C46/00 , C07C49/683 , C07C50/18
摘要： A working solution for producing hydrogen peroxide, containing an alkylanthraguinone working compound dissolved in a solvent, is regenerated by contacting the working solution with a catalyst containing from 5% to 100% boehmite at a temperature of 25° C. to 150° C. At least a portion of the tetrahydro-alkylanthraquinone epoxide present in the working solution is converted to working compound to maintain the composition of the working solution within specified limits.
摘要翻译： 通过使工作溶液与含有5％至100％勃姆石的催化剂在25℃至150℃的温度下接触，再生生成含有溶解在溶剂中的烷基桂环酮工作化合物的过氧化氢的工作溶液。 存在于工作溶液中的四氢 - 烷基蒽醌环氧化物的至少一部分转化为工作化合物，以将工作溶液的组成保持在规定的限度内。
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8.发明授权
公开(公告)号：US6046357A
公开(公告)日：2000-04-04
申请号：US165674
申请日：1998-10-02
申请人： Leon B. Levy , Edward F. Dougherty
发明人： Leon B. Levy , Edward F. Dougherty
IPC分类号： C07C51/47 , C07C51/50 , C07C57/075 , C07C57/02
摘要： A process for inhibiting free-radical polymerization of an alpha,beta-unsaturated (.alpha.,.beta.-unsaturated) carboxylic acid, and for providing desired grade .alpha.,.beta.-unsaturated carboxylic acid for use following storage and transport is described herein. In particular, bulk storage and shipment such as with overseas transport is described. The process comprises combining the .alpha.,.beta.-unsaturated carboxylic acid with a phenolic inhibitor and a coinhibitor to form an inhibited mixture, storing the inhibited mixture, transporting the inhibited mixture, and removing the coinhibitor to provide the desired grade .alpha.,.beta.-unsaturated carboxylic acid for use. In preferred embodiments, the .alpha.,.beta.-unsaturated carboxylic acid is acrylic acid, the phenolic inhibitor is .rho.-methoxyphenol, the coinhibitor is manganese cation, and removal of the coinhibitor is carried out using an ion exchange resin.
摘要翻译： 本文描述了用于抑制α，β-不饱和（α，β-不饱和）羧酸的自由基聚合以及用于提供用于储存和运输之后的所需等级α，β-不饱和羧酸的方法。 具体来说，大量存储和运输如海运。 该方法包括将α，β-不饱和羧酸与酚类抑制剂和联合抑制剂组合以形成抑制的混合物，储存受抑制的混合物，运输被抑制的混合物，并除去共抑制剂以提供所需的等级α，β-不饱和羧酸 酸使用。 在优选的实施方案中，α，β-不饱和羧酸是丙烯酸，酚类抑制剂是对甲氧基苯酚，联合抑制剂是锰阳离子，并且使用离子交换树脂进行去除联合抑制剂。
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公开(公告)号：US5078672A
公开(公告)日：1992-01-07
申请号：US572591
申请日：1990-08-27
IPC分类号： C01B15/037 , C09K15/30
CPC分类号： C01B15/037
摘要： A method for stabilizing hydrogen peroxide and the stabilized composition are claimed employing as a stabilizer a tin (II) salt of an acid selected from the group hydrofluoric acid, C6 to C17 saturated monocarboxylic acids and C2 to C6 saturated polycarboxylic acids, preferably oxalic acid. The tin content of hydrogen peroxide prepared from a tin (II) oxalate stock solution can be reduced by filtration to less than 1 mg/l if the tin oxalate stock solution has been properly aged.
摘要翻译： 要求使用选自氢氟酸，C 6至C 17饱和一元羧酸和C 2至C 6饱和多元羧酸，优选草酸的酸的锡（II）盐作为稳定剂来稳定过氧化氢和稳定组合物的方法。 由草酸锡（II）制备的过氧化氢的锡含量可以通过过滤降低至小于1mg / l，如果草酸锡原液已经适当老化。
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公开(公告)号：US4507495A
公开(公告)日：1985-03-26
申请号：US510846
申请日：1983-07-05
摘要： In the process of producing ethyl acrylate by the reaction of ethylene and acrylic acid in the presence of sulfuric acid, using phenolic type inhibitors, soluble manganese or cerium salts are additionally utilized.
摘要翻译： 在使用酚类抑制剂的情况下，通过乙烯和丙烯酸的反应在硫酸的存在下生产丙烯酸乙酯的过程中，还可以使用可溶性的锰或铈盐。
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