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公开(公告)号：US5101003A
公开(公告)日：1992-03-31
申请号：US474411
申请日：1990-02-02
IPC分类号： C08G79/02
CPC分类号： C08G79/02
摘要： The synthesis of the first examples of a new class of inorganic macromolecules, the polythiophosphazenes, is reported. When heated at 90.degree. C., the cyclothiophosphazene N.sub.3 P.sub.2 SCl.sub.5 undergoes ring-opening polymerization to yield the high polymeric polythiophosphazene [N.sub.3 P.sub.2 SCl.sub.5 ].sub.n. The latter functions as a reactive macromolecular intermediate and undergoes halogen replacement with sodium phenoxide and sodium o-phenylphenoxide to afford the polymers [N.sub.3 P.sub.2 S(OPh).sub.5 ].sub.n and [N.sub.3 P.sub.2 S(OC.sub.6 H.sub.4 Ph--o).sub.3.25 Cl.sub.1.75 ].sub.n, respectively.
摘要翻译： 报道了一类新的无机大分子，即聚硫代磷腈的合成。 当在90℃下加热时，环硫基磷腈N 3 P 2 SCl 5进行开环聚合，得到高分子聚硫代磷腈[N 3 P 2 SCl 5] n。 后者用作反应性大分子中间体，并用苯酚钠和邻苯基苯酚钠进行卤素置换，分别得到聚合物[N 3 P 2 S（OPh）5] n和[N 3 P 2 S（OC 6 H 4 Ph-o）3.25 Cl1.75] n。
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公开(公告)号：US5093438A
公开(公告)日：1992-03-03
申请号：US547708
申请日：1990-07-03
申请人： Harry R. Allcock , Ian Manners , Gerhard Renner , Oskar Nuyken
发明人： Harry R. Allcock , Ian Manners , Gerhard Renner , Oskar Nuyken
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： The synthesis of a new class of macromolecules, the polycarbophosphazenes, is reported. When heated at 120.degree. C., the cyclocarbophosphazene N.sub.3 P.sub.2 CCl.sub.5 undergoes ring-opening polymerization to afford the high polymeric polycarbophosphazene [N.sub.3 P.sub.2 CCl.sub.5 ].sub.n. The latter functions as a reactive macromolecular intermediate and undergoes halogen replacement with sodium phenoxide or aniline to afford the hydrolytically stable derivatives [N.sub.3 P.sub.2 C(OPh).sub.5 ].sub.n and [N.sub.3 P.sub.2 C(NHPh).sub.5 ].sub.n.
摘要翻译： 据报道，新一类大分子的合成，即聚碳磷腈。 当加热到120℃时，环磷酰腈N 3 P 2 CCl 5进行开环聚合，得到高聚合物多碳代膦腈[N 3 P 2 CCl 5] n。 后者用作反应性大分子中间体，并用苯酚盐或苯胺进行卤素取代，得到水解稳定的衍生物[N 3 P 2 C（OPh）5] n和[N 3 P 2 C（NHPh）5] n。
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3.发明授权Synthesis polyphosphazenes with controlled molecular weight and polydisperity 失效合成聚磷腈，具有受控的分子量和多不连续性
公开(公告)号：US5914388A
公开(公告)日：1999-06-22
申请号：US917069
申请日：1997-08-22
申请人： Harry R. Allcock , Christopher T. Morrissey , Ian Manners , Charles H. Honeyman , James M. Nelson , Chester A. Crane , Scott D. Reeves , A. Paul Primrose , Thomas J. Hartle , R. Prange
发明人： Harry R. Allcock , Christopher T. Morrissey , Ian Manners , Charles H. Honeyman , James M. Nelson , Chester A. Crane , Scott D. Reeves , A. Paul Primrose , Thomas J. Hartle , R. Prange
IPC分类号： C08G79/02
CPC分类号： C08G79/025
摘要： A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed non-phosphazene polymer containing a main or transition metal chloride, as an initiator. In a preferred embodiment, triarmed-star polyphosphazenes having the formula N{RN(H)R'.sub.2 P--(N.dbd.PR'.sub.2).sub.n }.sub.3 are prepared via this method. Also, a methods for synthesis of the monomer Cl.sub.3 P.dbd.NSiMe.sub.3 and cyclic trimer N.sub.3 P.sub.3 X.sub.6 from the reactants N(SiR.sub.3).sub.3 and PX.sub.5 are also described.
摘要翻译： 提供了一种制备聚磷腈的方法，其包括使用主要基团或过渡金属卤化物或其它合适的卤化物盐（包括任何链长的线性磷腈盐）或预成型非离子表面活性剂的正亚胺的阳离子溶液聚合反应， 含有主要或过渡金属氯化物的磷腈聚合物作为引发剂。 在优选的实施方案中，通过该方法制备具有式N {RN（H）R'2P-（N = PR'2）n} 3的三臂星型聚磷腈。 此外，还描述了从反应物N（SiR 3）3和PX 5合成单体Cl 3 P = NSiMe 3和环状三聚体N 3 P 3 X 6的方法。
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4.发明授权Synthesis of polyphosphazenes with controlled molecular weight and polydispersity 失效具有受控分子量和多分散性的聚磷腈的合成
公开(公告)号：US5698664A
公开(公告)日：1997-12-16
申请号：US429521
申请日：1995-04-26
CPC分类号： C08G79/025
摘要： A process for the preparation of polyphosphazenes is provided that includes the cationic solution polymerization reaction of a phosphoranimine, using a main group or transition metal halide, or other appropriate halide salt, including a linear phosphazene salt of any chain length, or a preformed nonphosphazene polymer containing a main or transition metal chloride, as an initiator.
摘要翻译： 提供了一种制备聚磷腈的方法，其包括使用主族或过渡金属卤化物或其它合适的卤化物盐（包括任何链长的线性磷腈盐）或预制的非磷腈聚合物的正亚胺的阳离子溶液聚合反应 含有主要或过渡金属氯化物作为引发剂。
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公开(公告)号：US06361869B1
公开(公告)日：2002-03-26
申请号：US09425176
申请日：1999-10-22
申请人： Ian Manners , Keith G. Balmain , Charles H. Hersom
发明人： Ian Manners , Keith G. Balmain , Charles H. Hersom
IPC分类号： B32B1504
CPC分类号： C08G79/14 , Y10T428/31663 , Y10T428/31678
摘要： The present invention provides a method and materials for reducing or limiting charge accumulation and the resulting arc discharges in components used in space vehicles such as satellites prone to charge buildup due to exposure to a charge flux. The material is found in the poly(metallocene) family. In each member of this family, a metal atom is an integral part of the polymer chain, the whole structure being held together (and the interactions provided) by chemical bonds rather than by the proximity of the components in a heterogeneous mechanical mixture. In a homogeneous dielectric, the needed conductivity may be radiation-induced or it may be achieved as the result of doping. The components may be coated with, or alternatively fabricated from, a material including the poly(metallocene) as a constituent.
摘要翻译： 本发明提供了用于减少或限制电荷累积的方法和材料，以及由于暴露于电荷通量而容易产生电荷的卫星的太空飞行器中使用的部件中产生的电弧放电。 该材料存在于聚（茂金属）族中。 在该族的每个成员中，金属原子是聚合物链的组成部分，整个结构通过化学键而不是通过非均相机械混合物中组分的接近保持在一起（以及提供的相互作用）。 在均匀电介质中，所需的电导率可以是辐射诱导的，或者可以通过掺杂来实现。 组分可以用包括聚（茂金属）作为组分的材料涂覆或替代地制造。
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6.发明申请公开(公告)号：US20080224103A1
公开(公告)日：2008-09-18
申请号：US12046313
申请日：2008-03-11
IPC分类号： H01B1/12
CPC分类号： B82Y20/00 , C09K2019/0496 , G02B6/1225 , G02F1/01 , G02F1/19 , G02F1/21 , G02F2201/305 , G02F2201/346 , G02F2202/022 , G02F2202/32 , G02F2203/055 , Y10T428/1023
摘要： The present invention discloses a widely wavelength tunable polychrome colloidal photonic crystal device whose optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimension, effected by a predetermined change in the electronic configuration of the composite material. In its preferred embodiment, the material is a composite in the form of a film or a patterned film or shape of any dimension or array of shapes of any dimension comprised of an organized array of microspheres in a matrix of a cross-linked metallopolymer network with a continuously variable redox state of charge and fluid content. The chemo-mechanical and electro-mechanical optical response of the colloidal photonic crystal-metallopolymer gel is exceptionally fast and reversible, attaining its fully swollen state from the dry shrunken state and vice versa on a sub-second time-scale. These composite materials can be inverted by removal of the constituent microspheres from the aforementioned colloidal photonic crystal metallopolymer-gel network to create a macroporous metallopolymer-gel network inverse colloidal photonic crystal film or patterned film or shape of any dimension optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be redox tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimensions.
摘要翻译： 本发明公开了一种广泛波长可调谐的多色胶体光子晶体器件，其光学布拉格衍射阻挡带和更高能带的波长，宽度和强度可以以连续和精细，快速和可逆，可再现和可预测的方式调谐，并且在宽光谱 通过胶体光子晶格尺寸的受控扩展或收缩，由复合材料的电子构型的预定变化来实现。 在其优选实施方案中，该材料是膜或图案化膜的形式的复合材料或任何尺寸或任何尺寸形状阵列的形状的复合材料，其包含在交联金属聚合物网络的基质中的有组织的微球阵列， 不断变化的氧化还原电荷和流体含量。 胶体光子晶体金属聚合物凝胶的化学机械和机电光学响应特别快速和可逆，在亚秒级时间范围内从干收缩状态获得完全膨胀的状态，反之亦然。 这些复合材料可以通过从上述胶体光子晶体金属聚合物 - 凝胶网络中除去组成微球而反转，以产生大孔金属聚合物 - 凝胶网络反胶体光子晶体膜或任何尺寸的光学布拉格衍射阻带的图案化膜或更高的形状 能带的波长，宽度和强度可以通过胶体光子晶格尺寸的受控扩展或收缩，以连续和精细，快速和可逆，可再现和可预测的方式以及在宽光谱范围内进行氧化还原。
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公开(公告)号：US06565992B1
公开(公告)日：2003-05-20
申请号：US09189437
申请日：1998-11-10
申请人： Ian Manners , Xijia Gu , Zhen Pang , Mitchell A. Winnik , Yizeng Ni
发明人： Ian Manners , Xijia Gu , Zhen Pang , Mitchell A. Winnik , Yizeng Ni
IPC分类号： G01N2100
CPC分类号： G01N21/643 , G01L11/02 , G01N2021/6432 , Y10T436/207497
摘要： A pressure sensor comprising a stable polymer having a backbone containing nitrogen and one or more of sulfur or phosphorous, and including a phosphorescent dye agent.
摘要翻译： 一种压力传感器，包括具有含有氮和硫或磷中的一种或多种的骨架的稳定聚合物，并且包括磷光染料剂。
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公开(公告)号：US07616376B2
公开(公告)日：2009-11-10
申请号：US12046313
申请日：2008-03-11
CPC分类号： B82Y20/00 , C09K2019/0496 , G02B6/1225 , G02F1/01 , G02F1/19 , G02F1/21 , G02F2201/305 , G02F2201/346 , G02F2202/022 , G02F2202/32 , G02F2203/055 , Y10T428/1023
摘要： A method of wavelength tuning a composite material. The method includes the steps of: producing an ordered array of first constituents having a first refractive index embedded within a cross-linked metallopolymer network having a second refractive index different than the first refractive index, the ordered array of first constituents having a lattice spacing giving rise to Bragg diffraction when the composite material is illuminated; and switching the electronic configuration of the cross-linked metallopolymer network so that the cross-linked polymer network changes dimensions and modulates the lattice spacing of the ordered array of first constituents, which shifts the Bragg diffraction wavelength to a pre-selected wavelength.
摘要翻译： 一种复合材料的波长调谐方法。 该方法包括以下步骤：产生具有嵌入在具有不同于第一折射率的第二折射率的交联金属聚合物网络的第一折射率的第一成分的有序阵列，第一成分的有序阵列具有晶格间距给出 当复合材料被照亮时上升到布拉格衍射; 并且交换交联金属聚合物网络的电子结构，使得交联聚合物网络改变尺寸并调制第一组分的有序阵列的晶格间距，这将布拉格衍射波长移动到预选波长。
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公开(公告)号：US07364673B2
公开(公告)日：2008-04-29
申请号：US10681374
申请日：2003-10-09
CPC分类号： B82Y20/00 , C09K2019/0496 , G02B6/1225 , G02F1/01 , G02F1/19 , G02F1/21 , G02F2201/305 , G02F2201/346 , G02F2202/022 , G02F2202/32 , G02F2203/055 , Y10T428/1023
摘要： The present invention discloses a widely wavelength tunable polychrome colloidal photonic crystal device whose optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimension, effected by a predetermined change in the electronic configuration of the composite material. In its preferred embodiment, the material is a composite in the form of a film or a patterned film or shape of any dimension or array of shapes of any dimension comprised of an organized array of microspheres in a matrix of a cross-linked metallopolymer network with a continuously variable redox state of charge and fluid content. The chemo-mechanical and electro-mechanical optical response of the colloidal photonic crystal-metallopolymer gel is exceptionally fast and reversible, attaining its fully swollen state from the dry shrunken state and vice versa on a sub-second time-scale. These composite materials can be inverted by removal of the constituent microspheres from the aforementioned colloidal photonic crystal metallopolymer-gel network to create a macroporous metallopolymer-gel network inverse colloidal photonic crystal film or patterned film or shape of any dimension optical Bragg diffraction stop bands and higher energy bands wavelength, width and intensity can be redox tuned in a continuous and fine, rapid and reversible, reproducible and predictable fashion and over a broad spectral range by a controlled expansion or contraction of the colloidal photonic lattice dimensions.
摘要翻译： 本发明公开了一种广泛波长可调谐的多色胶体光子晶体器件，其光学布拉格衍射阻挡带和更高能带的波长，宽度和强度可以以连续和精细，快速和可逆，可再现和可预测的方式调谐，并且在宽光谱 通过胶体光子晶格尺寸的受控扩展或收缩，由复合材料的电子构型的预定变化实现。 在其优选实施方案中，该材料是膜或图案化膜的形式的复合材料或任何尺寸或任何尺寸形状阵列的形状的复合材料，其包含在交联金属聚合物网络的基质中的有组织的微球阵列， 不断变化的氧化还原电荷和流体含量。 胶体光子晶体金属聚合物凝胶的化学机械和机电光学响应特别快速和可逆，在亚秒级时间范围内从干收缩状态获得完全膨胀的状态，反之亦然。 这些复合材料可以通过从上述胶体光子晶体金属聚合物 - 凝胶网络中除去组成微球而反转，以产生大孔金属聚合物 - 凝胶网络反胶体光子晶体膜或任何尺寸的光学布拉格衍射阻带的图案化膜或更高的形状 能带的波长，宽度和强度可以通过胶体光子晶格尺寸的受控扩展或收缩，以连续和精细，快速和可逆，可再现和可预测的方式以及在宽光谱范围内进行氧化还原。
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公开(公告)号：US06372873B1
公开(公告)日：2002-04-16
申请号：US09541717
申请日：2000-04-03
申请人： Ian Manners , Hendrik Dorn
发明人： Ian Manners , Hendrik Dorn
IPC分类号： C08G7908
CPC分类号： C08G79/08 , C07F9/5045 , C07F9/5463 , C08G79/02 , C09K21/14
摘要： Linear backbone phosphorus-boron polymers of the general formula (I): wherein R1, R2, R3, and R4, are the same or different and selected from H, optionally substituted alkyl, alkenyl and phenyl; and n is at least 2, and particularly high molecular weight polymers of absolute weight average molecular weight of at least 10,000. The polymers are of use as fire retardants.
摘要翻译： 通式（I）的直链骨架磷 - 硼聚合物：其中R1，R2，R3和R4相同或不同，选自H，任选取代的烷基，烯基和苯基; 且n为至少2，特别是绝对重均分子量至少为10,000的高分子量聚合物。 聚合物用作阻燃剂。
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