公开(公告)号：US06774249B2

公开(公告)日：2004-08-10

申请号：US09965046

申请日：2001-09-27

申请人： Hashem Akhavan-Tafti ,  Richard S. Handley ,  Mark D. Sandison ,  Randall K. Larkin

发明人： Hashem Akhavan-Tafti ,  Richard S. Handley ,  Mark D. Sandison ,  Randall K. Larkin

IPC分类号： C01B1332

CPC分类号： C01B13/02 ,  C08F8/18 ,  C08F8/40 ,  C08F8/26 ,  C08F212/08 ,  C08F212/14 ,  C08F212/36

摘要： Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.

摘要翻译： 公开了改进的聚合物固定化光敏剂以及制备和使用它们的方法。 聚合物固定的光敏剂包括交联的聚合物主链，共价结合到聚合物主链上的多个阳离子铵或鏻基团和固定的光敏剂。 铵或鏻基团中的平均总碳原子数为至少四个，优选至少12.光敏剂可以共价或离子地结合到聚合物上。 本发明的聚合物负载的光敏剂在催化含有碳 - 碳双键的化合物的光敏化氧化方面出人意料地优异。

公开(公告)号：US06545102B1

公开(公告)日：2003-04-08

申请号：US09965692

申请日：2001-09-27

申请人： Hashem Akhavan-Tafti ,  Richard S. Handley ,  Mark D. Sandison ,  Randall K. Larkin

发明人： Hashem Akhavan-Tafti ,  Richard S. Handley ,  Mark D. Sandison ,  Randall K. Larkin

IPC分类号： C08C1924

CPC分类号： C08F8/44 ,  B01J31/0234 ,  B01J31/06 ,  B01J35/004 ,  C08F8/18 ,  C08F8/40 ,  C08F212/08

摘要： Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.

摘要翻译： 公开了改进的聚合物固定化光敏剂以及制备和使用它们的方法。 聚合物固定的光敏剂包括交联的聚合物主链，共价结合到聚合物主链上的多个阳离子铵或鏻基团和固定的光敏剂。 铵或鏻基团中的平均总碳原子数为至少四个，优选至少12.光敏剂可以共价或离子地结合到聚合物上。 本发明的聚合物负载的光敏剂在催化含有碳 - 碳双键的化合物的光敏化氧化方面出人意料地优异。