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公开(公告)号：US4973779A
公开(公告)日：1990-11-27
申请号：US434964
申请日：1989-11-09
申请人： Tamotsu Imai , Hayim Abrevaya
发明人： Tamotsu Imai , Hayim Abrevaya
IPC分类号： B01J23/62 , B01J23/656 , B01J35/00 , C10G45/00
CPC分类号： B01J23/622 , B01J23/6567 , B01J35/0006 , C10G45/00
摘要： A hydrocarbon conversion process which utilizes a novel catalytic composite is disclosed. The catalyst composite comprises a platinum group metal component, a first modifier selected from Group IA and IIA elements of the Periodic Table, a second modifier component selected from the group of elements consisting of palladium, iridium, and osmium, and a third modifier component selected from the elements of Group IVA of the Periodic Table of the Elements. All of the catalytic components are located on a refractory oxide support having a nominal diameter (d) of from 50 to 10,000 microns. The catalytic composite is characterized in that the second modifier components is surface-impregnated upon the support in such a manner that the average concentration of the surface-impregnated second modifier component on the outside 0.2d micron catalyst layer is at least 2 times the average concentration of the second modifier component in 0.4d micron diameter center core of the catalyst where d is the nominal diameter, and wherein the first modifier metal component is uniformly impregnated. The process has been found to be most useful in the dehydrogenation of dehydrogenatable hydrocarbons.
摘要翻译： 公开了一种利用新型催化复合材料的烃转化方法。 催化剂复合材料包括铂族金属组分，选自元素周期表IA和IIA族元素的第一改性剂，选自钯，铱和锇的元素组的第二改性剂组分和选自第三种改性剂组分 从元素周期表第IVA部分的要素。 所有催化组分位于公称直径（d）为50至10,000微米的难熔氧化物载体上。 催化复合材料的特征在于，第二改性剂组分以这样的方式表面浸渍在载体上，使得外部0.2d微米催化剂层上的表面浸渍的第二改性剂组分的平均浓度为平均浓度的至少2倍 的第二改性剂组分在催化剂的0.4d微米直径中心核心中，其中d是公称直径，并且其中第一改性剂金属组分被均匀地浸渍。 已经发现该方法在可脱氢烃的脱氢中最有用。
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公开(公告)号：US4608360A
公开(公告)日：1986-08-26
申请号：US751340
申请日：1985-07-02
申请人： Hayim Abrevaya , Tamotsu Imai
发明人： Hayim Abrevaya , Tamotsu Imai
CPC分类号： C07C5/3337 , B01J23/622 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J35/109
摘要： A novel catalytic composite is disclosed. Also disclosed is a use for the novel composite and a method for preparing the same. The catalytic composite comprises a Group VIII, noble metal component, a co-formed IVA metal component, an alkali metal or alkaline earth metal component and an alumina support having a surface area of from 5 to 150 m.sup.2 /g. Additionally the alumina support is such that less than about 18% of the total pore volume of the support is associated with pores having mean diameters of about 300 Angstroms or less and more than about 55% of the total pore volume of the support is associated with pores having mean diameters of about 600 Angstroms or more. The novel catalytic composite has particular utility as a paraffin dehydrogenation catalyst.
摘要翻译： 公开了一种新型催化复合材料。 还公开了新型复合物的用途及其制备方法。 催化复合材料包含VIII族，贵金属组分，共形IVA金属组分，碱金属或碱土金属组分和表面积为5至150m 2 / g的氧化铝载体。 此外，氧化铝载体使得小于载体总孔体积的约18％与平均直径为约300埃或更小的孔相关联，并且超过载体总孔体积的约55％与载体的总孔体积相关 平均直径为约600埃以上的孔。 新型催化复合材料具有石蜡脱氢催化剂的特殊用途。
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公开(公告)号：US4786625A
公开(公告)日：1988-11-22
申请号：US131882
申请日：1987-12-11
CPC分类号： C10G45/00 , B01J23/622 , B01J23/6567 , B01J35/0006 , Y10S502/514 , Y10S502/523
摘要： A novel catalytic composite comprising a platinum group metal component; a modifier metal component selected from the group consisting of a tin component, germanium component, rhenium component and mixtures thereof; an optional alkali or alkaline earth metal component or mixtures thereof, an optional halogen component, and an optional catalytic modifier component on a refractory oxide support having a nominal diameter of at least about 850 microns. The distribution of the platinum group metal component is such that the platinum group component is surface-impregnated where substantially all of the platinum group metal component is located at most within a 400 micron exterior layer of the support. The effective amount of the modifier metal component is uniformly dispersed throughout the refractory oxide support. The distribution of the surface-impregnated platinum metal component is such that the novel catalyst has particular utility as a hydrocarbon dehydrogenation catalyst in a hydrocarbon dehydrogenation process.
摘要翻译： 一种包含铂族金属组分的新型催化复合材料; 选自锡组分，锗组分，铼组分及其混合物的改性金属组分; 任选的碱金属或碱土金属组分或其混合物，任选的卤素组分和在耐火氧化物载体上的任选的催化改性剂组分，其标称直径为至少约850微米。 铂族金属组分的分布使得铂基组分被表面浸渍，其中基本上所有的铂族金属组分位于载体的400微米外层内。 改性金属组分的有效量均匀分散在整个难熔氧化物载体上。 表面浸渍的铂金属组分的分布使得新型催化剂在烃脱氢方法中作为烃脱氢催化剂具有特别的用途。
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公开(公告)号：US4962261A
公开(公告)日：1990-10-09
申请号：US208910
申请日：1988-06-20
申请人： Hayim Abrevaya , Tamotsu Imai
发明人： Hayim Abrevaya , Tamotsu Imai
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/14 , Y10S585/943
摘要： Methane is upgraded to higher molecular weight hydrocarbons in a process using a novel catalyst comprising boron, tin and zinc. The feed admixture also comprises oxygen. The novel catalyst may comprise one or more Group I-A or II-A elements, preferably potassium.
摘要翻译： 在使用包含硼，锡和锌的新型催化剂的方法中，将甲烷升级为较高分子量的烃。 进料混合物还包含氧气。 新型催化剂可以包含一种或多种I-A族或II-A族元素，优选钾。
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5.发明授权
公开(公告)号：US4827072A
公开(公告)日：1989-05-02
申请号：US221977
申请日：1988-07-20
IPC分类号： B01J23/62 , B01J23/656 , B01J35/00 , C10G45/00 , C07C5/32
CPC分类号： B01J23/6567 , B01J23/622 , B01J35/0006 , C10G45/00
摘要： A novel catalytic composite comprising a platinum group metal component; a modifier metal component selected from the group consisting of a tin component, germanium component, rhenium component and mixtures thereof; an optional alkali or alkaline earth metal component or mixtures thereof, an optional halogen component, and an optional catalytic modifier component on a refractory oxide support having a nominal diameter of at least about 850 microns. The distribution of the platinum group metal component is such that the platinum group component is surface-impregnated where substantially all of the platinum group metal component is located at most within a 400 micron exterior layer of the support. The effective amount of the modifier metal component is uniformly dispersed throughout the refractory oxide support. The distribution of the surface-impregnated platinum metal component is such that the novel catalyst has particular utility as a hydrocarbon dehydrogenation catalyst in a hydrocarbon dehydrogenation process.
摘要翻译： 一种包含铂族金属组分的新型催化复合材料; 选自锡组分，锗组分，铼组分及其混合物的改性金属组分; 任选的碱金属或碱土金属组分或其混合物，任选的卤素组分和在耐火氧化物载体上的任选的催化改性剂组分，其标称直径为至少约850微米。 铂族金属组分的分布使得铂基组分被表面浸渍，其中基本上所有的铂族金属组分位于载体的400微米外层内。 改性金属组分的有效量均匀分散在整个难熔氧化物载体上。 表面浸渍的铂金属组分的分布使得新型催化剂在烃脱氢方法中作为烃脱氢催化剂具有特别的用途。
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公开(公告)号：US4677237A
公开(公告)日：1987-06-30
申请号：US930625
申请日：1986-11-14
申请人： Tamotsu Imai , Hayim Abrevaya
发明人： Tamotsu Imai , Hayim Abrevaya
CPC分类号： B01J23/622 , C07C5/3337
摘要： A novel dehydrogenation process is disclosed. This process comprises contacting dehydrogenatable hydrocarbons with a catalytic composite comprising a platinum component, a tin component, a potassium component, a lithium component, and an alumina support, wherein the lithium to potassium atomic ratio of said catalytic composite is in the range of from 3:1 to 5:1. The process of the invention has particular utility for the dehydrogenation of C.sub.3 -C.sub.30 paraffins.
摘要翻译： 公开了一种新的脱氢方法。 该方法包括使可脱氢烃与包含铂组分，锡组分，钾组分，锂组分和氧化铝载体的催化复合物接触，其中所述催化复合材料的锂/钾原子比在3 ：1〜5：1。 本发明的方法对于C3-C30链烷烃的脱氢具有特殊的用途。
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7.发明授权Process and catalyst for upgrading methane to higher carbon number hydrocarbons 失效将甲烷升级为更高碳数烃的工艺和催化剂
公开(公告)号：US5095161A
公开(公告)日：1992-03-10
申请号：US563591
申请日：1990-08-06
申请人： Hayim Abrevaya , Tamotsu Imai , Lisa M. Lane
发明人： Hayim Abrevaya , Tamotsu Imai , Lisa M. Lane
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/14 , Y10S585/943
摘要： Methane is upgraded to higher molecular weight hydrocarbons in a process using a novel catalyst comprising oxides of boron, tin and zinc. The feed admixture also comprises oxygen. The novel catalyst may comprise one or more Group I-A or II-A elements, preferably potassium and is characterized by its method of manufacture.
摘要翻译： 在使用包含硼，锡和锌的氧化物的新型催化剂的方法中，将甲烷升级为较高分子量的烃。 进料混合物还包含氧气。 新型催化剂可以包含一种或多种I-A族或II-A族元素，优选钾，并且其特征在于其制备方法。
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公开(公告)号：US4880764A
公开(公告)日：1989-11-14
申请号：US289137
申请日：1988-12-23
申请人： Tamotsu Imai , Hayim Abrevaya
发明人： Tamotsu Imai , Hayim Abrevaya
IPC分类号： B01J23/62 , B01J23/656 , B01J35/00 , C10G45/00
CPC分类号： C10G45/00 , B01J23/622 , B01J23/6567 , B01J35/0006 , Y10S502/514 , Y10S502/523
摘要： A novel catalytic composite and a process of its use is disclosed. The catalyst comprises a platinum group metal component, a first modifier component selected from Group IA and IIA elements of the Periodic Table, a second modifier components selected from the group of elements consisting of palladium, iridum, and osmium, and a third modifier component selected from the elements of Group IVA of the Peridoic Table of the Elements. All of the catalytic components are located on a refractory oxide support having a nominal diameter (d) of from 50 to 1000 microns. The catalytic composite is characterized in that the second modifier component is surface-impregnated upon the support in such a manner that the average concentration of the surface-impregnated second modifier component on the outside 0.2d micron catalyst layer is at least 2 times the average concentration of the second modifier component in 0.4d micron diameter center core of the catalyst where d is the nominal diameter, and wherein the first modifier metal component is uniformly impregnated. The catalytic composite has been found to be most useful in the dehydrogenation of dehydrogenatable hydrocarbons.
摘要翻译： 公开了一种新颖的催化复合材料及其使用方法。 所述催化剂包含铂族金属组分，选自元素周期表IA和IIA族元素的第一改性剂组分，选自钯，铱和锇的元素组的第二改性剂组分和选择的第三改性剂组分 来自元素周期表的IVA组元素。 所有催化组分位于具有50-1000微米的公称直径（d）的难熔氧化物载体上。 催化复合材料的特征在于，第二改性剂组分以这样的方式表面浸渍在载体上，使得外部0.2d微米催化剂层上的表面浸渍的第二改性剂组分的平均浓度为平均浓度的至少2倍 的第二改性剂组分在催化剂的0.4d微米直径中心核心中，其中d是公称直径，并且其中第一改性剂金属组分被均匀地浸渍。 已发现催化复合材料在脱氢烃脱氢中最有用。
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公开(公告)号：US4672146A
公开(公告)日：1987-06-09
申请号：US837985
申请日：1986-03-10
申请人： Hayim Abrevaya , Tamotsu Imai
发明人： Hayim Abrevaya , Tamotsu Imai
CPC分类号： B01J35/10 , B01J23/622 , B01J35/0026 , B01J35/1019 , B01J35/108 , C07C5/3337
摘要： A novel catalytic composite is disclosed. Also disclosed is a use for the novel composite and a method for preparing the same. The catalytic composite comprises a Group VIII, noble metal component, a co-formed IVA metal component, an alkali metal or alkaline earth metal component and an alumina support having a surface area of from 5 to 150 m.sup.2 /g. Additionally the alumina support is such that less than about 18% of the total pore volume of the support is associated with pores having mean diameters of about 300 Angstroms or less and more than about 55% of the total pore volume of the support is associated with pores having mean diameters of about 600 Angstroms or more. The novel catalytic composite has particular utility as a paraffin dehydrogenation catalyst.
摘要翻译： 公开了一种新型催化复合材料。 还公开了新型复合物的用途及其制备方法。 催化复合材料包含VIII族，贵金属组分，共形IVA金属组分，碱金属或碱土金属组分和表面积为5至150m 2 / g的氧化铝载体。 此外，氧化铝载体使得小于载体总孔体积的约18％与平均直径为约300埃或更小的孔相关联，并且超过载体总孔体积的约55％与载体的总孔体积相关 平均直径为约600埃以上的孔。 新型催化复合材料具有石蜡脱氢催化剂的特殊用途。
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公开(公告)号：US4595673A
公开(公告)日：1986-06-17
申请号：US676444
申请日：1984-11-29
申请人： Tamotsu Imai , Hayim Abrevaya
发明人： Tamotsu Imai , Hayim Abrevaya
CPC分类号： B01J23/622 , C07C5/3337
摘要： A novel hydrocarbon conversion catalyst is disclosed. Additionally, a method of preparing the catalyst and a process for its use are disclosed. The catalyst comprises a platinum group component, a Group IVA component and an alkali component on a carrier material. The alkali component further comprises from about 0.05 to about 10.0 wt. %, on the weight of the composite, of a second alkali metal. The catalyst has particular utility as a dehydrogenation catalyst.
摘要翻译： 公开了一种新型烃转化催化剂。 另外，公开了制备催化剂的方法及其使用方法。 催化剂在载体材料上包含铂族组分，IVA族组分和碱性组分。 碱组分还包含约0.05至约10.0重量％ ％，关于复合材料的重量，第二碱金属。 该催化剂作为脱氢催化剂具有特殊的用途。
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