公开(公告)号：US11969724B2

公开(公告)日：2024-04-30

申请号：US18038547

申请日：2021-12-07

申请人： SABIC Global Technologies B.V.

发明人： Wugeng Liang ,  Hector Perez ,  Pankaj Gautam Singh ,  David West

IPC分类号： B01J8/04 ,  B01J21/04 ,  B01J23/63 ,  C07C2/84

CPC分类号： B01J8/0438 ,  B01J8/0492 ,  B01J21/04 ,  B01J23/63 ,  C07C2/84 ,  C07C2521/04 ,  C07C2523/63

摘要： The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C2+ hydrocarbon product mixture using the present reactor system.

公开(公告)号：US20230372911A1

公开(公告)日：2023-11-23

申请号：US18320931

申请日：2023-05-19

申请人： UNM Rainforest Innovations

发明人： Kannan Ramaiyan ,  Angelica Benavidez ,  Femando Garzon ,  Luke Denoyer

IPC分类号： B01J23/847 ,  C07C2/84 ,  B01J23/20 ,  B01J23/00 ,  C01G33/00

CPC分类号： B01J23/8474 ,  C07C2/84 ,  B01J23/20 ,  B01J23/002 ,  C01G33/006 ,  C07C2529/076 ,  C01P2002/52 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2002/85

摘要： A catalyst comprising a barium niobate-based cubic perovskite structure where, Mg and Ca has been used to dope the niobium sites along with Fe, Ni, Co, Y, and Pr.

公开(公告)号：US20230365477A1

公开(公告)日：2023-11-16

申请号：US18355466

申请日：2023-07-20

申请人： Kara Technologies Inc.

发明人： Hua Song ,  Hao Xu ,  Zhaofei Li ,  Yimeng Li

IPC分类号： C07C2/84

CPC分类号： C07C2/84 ,  C07C2529/48

摘要： A method of desulfurizing a sulfur-containing hydrocarbon feedstock includes introducing the sulfur-containing hydrocarbon feedstock within a reactor in the presence of a gas atmosphere and a catalyst structure, where the catalyst structure comprises a zeolite porous support structure including gallium (Ga) and molybdenum (Mo) loaded in the zeolite porous support structure. The gas atmosphere can include methane. At least 50% of sulfur content can be removed from the feedstock as a result of the desulfurizing method.

公开(公告)号：US20230347309A1

公开(公告)日：2023-11-02

申请号：US18038547

申请日：2021-12-07

申请人： SABIC Global Technologies B.V.

发明人： Wugeng LIANG ,  Hector PEREZ ,  Pankaj Gautam SINGH ,  David WEST

IPC分类号： B01J8/04 ,  C07C2/84 ,  B01J23/63 ,  B01J21/04

CPC分类号： B01J8/0438 ,  C07C2/84 ,  B01J8/0492 ,  B01J23/63 ,  B01J21/04 ,  C07C2521/04 ,  C07C2523/63

摘要： The invention relates to a reactor system for oxidative coupling of methane (OCM), comprising: reactor system for oxidative coupling of methane (OCM), comprising: (a) an inlet configured to receive a reactant mixture; (b) a reaction chamber having an upstream end and a downstream end such that the reaction chamber extends from the upstream end to the downstream end, and the reaction chamber comprises a catalyst bed having a catalyst composition having at least two catalyst components: (i) a low selectivity catalyst component; and (ii) a high selectivity catalyst component; and (c) an outlet configured to recover a C2+ hydrocarbon product mixture from the reactor system; wherein the reactor system is configured such that the reactant mixture substantially contacts the high selectivity catalyst component prior to contacting the low selectivity catalyst component. The invention further describes a process for the production of C2+ hydrocarbon product mixture using the present reactor system.

公开(公告)号：US20230330650A1

公开(公告)日：2023-10-19

申请号：US18337070

申请日：2023-06-19

申请人： CHINA AUTOMOTIVE TECHNOLOGY AND RESEARCH CENTER CO., LTD ,  CATARC AUTOMOTIVE TEST CENTER (TIANJIN) CO., LTD

发明人： Kaixiang LI ,  Zhenguo LI ,  Xiaoning REN ,  Yuankai SHAO ,  Jianhai WANG ,  Li ZHANG ,  Lingfeng JIA ,  Cheng LV

IPC分类号： B01J29/80 ,  B01J29/76 ,  B01J29/83 ,  B01J29/85 ,  B01J29/00 ,  B01J37/00 ,  B01J37/03 ,  B01J37/02 ,  B01J37/06 ,  B01J37/08 ,  C07C2/84 ,  C10G11/05

CPC分类号： B01J29/80 ,  B01J29/763 ,  B01J29/83 ,  B01J29/85 ,  B01J29/005 ,  B01J37/0018 ,  B01J37/036 ,  B01J37/033 ,  B01J37/0236 ,  B01J37/06 ,  B01J37/082 ,  C07C2/84 ,  C10G11/05 ,  B01J2029/062

摘要： The present disclosure provides molecular sieves with intergrown phases of AEI and CHA topologies and a catalyst thereof. A preparation method for the molecular sieves include the following steps: mixing a hydroxyphosphono organic alkali R with an aluminum source and a silicon source to obtain a sol-gel precursor, putting the sol-gel precursor into a closed hydrothermal synthesis reactor for reaction, filtering the reaction solution, washing, drying, and calcination to obtain the molecular sieves with intergrown phases of AEI and CHA topologies. The molecular sieves and the catalyst thereof can be directly synthesized under mild conditions with a hydroxyphosphono organic alkali as a structure-directing agent and a phosphorus source, have a pH value of 6-9 and low requirements for corrosion resistance of production devices, and are suitable for large-scale production.

公开(公告)号：US11673121B2

公开(公告)日：2023-06-13

申请号：US17553795

申请日：2021-12-17

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Jeong-Myeong Ha ,  Lien Thi Do ,  Jae Wook Choi ,  Dong Jin Suh ,  Young Hyun Yoon ,  Gi Seok Yang ,  Hyun Joo Lee

IPC分类号： B01J23/30 ,  B01J23/34 ,  B01J21/06 ,  B01J23/00 ,  B01J37/04 ,  B01J37/08 ,  B01J37/00 ,  C07C2/84

CPC分类号： B01J23/30 ,  B01J21/063 ,  B01J23/002 ,  B01J23/34 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/08 ,  C07C2/84 ,  C07C2523/02 ,  C07C2523/30 ,  C07C2523/34

摘要： Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.

公开(公告)号：US11666879B2

公开(公告)日：2023-06-06

申请号：US16981444

申请日：2019-04-18

申请人： SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Wugeng Liang ,  Sagar Sarsani ,  David West ,  James Kauffman ,  Jonathan Banke ,  Hector Perez ,  Robert C. Schucker ,  Tian Gu ,  Vemuri Balakotaiah

IPC分类号： B01J8/02 ,  C07C2/84

CPC分类号： B01J8/0278 ,  B01J8/0285 ,  C07C2/84 ,  B01J2208/00115 ,  B01J2208/022 ,  C07C2523/10

摘要： Disclosed herein are systems and processes for the conversion of a methane feedstock to C2+ hydrocarbons.

公开(公告)号：US20230149915A1

公开(公告)日：2023-05-18

申请号：US16970682

申请日：2020-05-29

申请人： KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Hyunjoo LEE ,  Gihun KWON

IPC分类号： B01J37/00 ,  C07C2/84 ,  B01J23/63 ,  B01J6/00

CPC分类号： B01J37/00 ,  C07C2/84 ,  B01J23/63 ,  B01J6/001 ,  C07C2523/63

摘要： Disclosed are: a catalyst for oxidative coupling of methane, the catalyst comprising palladium supported on a cerium palladium solid solution; and a method for oxidative coupling using the same, wherein highly oxidative Pd/CePdO and CePdO catalysts can be used in the production of C2 hydrocarbon compounds through oxidative coupling of methane, hereinafter OCM) at low temperatures.

公开(公告)号：US10076739B1

公开(公告)日：2018-09-18

申请号：US14801004

申请日：2015-07-16

申请人： Precision Combustion, Inc.

发明人： Jeffrey Weissman

IPC分类号： B01J19/00 ,  B01J19/24 ,  C07C2/84 ,  C07C2/58 ,  C07C29/50

CPC分类号： B01J19/002 ,  B01D61/145 ,  B01D63/06 ,  B01D69/04 ,  B01D69/145 ,  B01D2313/22 ,  B01J19/2475 ,  B01J19/249 ,  B01J2219/00076 ,  B01J2219/00245 ,  B01J2219/2401 ,  B01J2219/2454 ,  B01J2219/246 ,  B01J2219/2475 ,  B01J2219/2479 ,  C07C2/58 ,  C07C2/84 ,  C07C29/50 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/30 ,  C07C2523/34 ,  C07C2529/40 ,  C07C31/04 ,  C07C9/16 ,  C07C11/04

摘要： A chemical reactor for use in a chemical process wherein a reactant and/or a target product is prone to produce undesirable byproducts through secondary reactions. The reactor is configured with a first flow passage for passing a flow of an overly reactive reactant; a permeable first wall for controlled flow of the overly reactive reactant into a second flow passage providing a flow of a second reactant; a permeable second wall having a catalyst supported on an inner surface thereof for catalyzing reaction of the reactants flowing in the second flow passage; the permeable second wall passing through a flow containing the target product; and a non-permeable third wall defining a third flow passage for exiting the product mixture. The reactor can be employed in selective oxidation, oxidative dehydrogenation, and alkylation processes to reduce the formation of byproducts.

公开(公告)号：US20180222827A1

公开(公告)日：2018-08-09

申请号：US15944890

申请日：2018-04-04

申请人： SABIC Global Technologies B.V.

发明人： Kaiwalya SABNIS ,  Dustin FICKEL ,  Heng SHOU ,  Edouard MAMEDOV

IPC分类号： C07C17/154 ,  C07C19/03 ,  B01J27/10 ,  B01J29/06 ,  B01J29/85

CPC分类号： C07C17/154 ,  B01J23/10 ,  B01J27/10 ,  B01J29/06 ,  B01J29/85 ,  B01J35/0006 ,  B01J2231/46 ,  C07C1/26 ,  C07C2/84 ,  C07C17/37 ,  C07C19/03 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

摘要： A chemical reactor system includes: a feed; a methane oxychlorination catalyst, wherein a product of an oxychlorination reaction is dichloromethane; and a dichloromethane conversion catalyst, wherein the dichloromethane conversion catalyst provides a product stream having a dichloromethane selectivity less than 5%. The addition of the dichloromethane conversion catalyst to the reactor bed can decrease the amount of dichloromethane produced and increase the amount of monochloromethane produced. Accordingly, dichloromethane does not have to be separated from the product stream and the monochloromethane can then be used to produce other products, such as olefins.