公开(公告)号：US20140093433A1

公开(公告)日：2014-04-03

申请号：US14095698

申请日：2013-12-03

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap Keung Lee

IPC分类号： C10G49/00

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydroprocessing system involves introducing heavy oil and in situ formed metal sulfide catalyst particles, or a catalyst precursor capable of forming metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The metal sulfide catalyst particles are formed in situ by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the metal sulfide catalyst particles in situ in the heavy oil. The in situ formed metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

摘要翻译： 加氢处理系统包括将重油和原位形成的金属硫化物催化剂颗粒或能够在重油内原位形成金属硫化物催化剂颗粒的催化剂前体引入加氢处理反应器。 金属硫化物催化剂颗粒是通过以下步骤形成的：1）将催化剂前体与烃稀释剂预混合以形成前体混合物，2）将前体混合物与重油混合以形成调节原料，和3）加热经调节的原料以分解 催化剂前体并使来自前体的金属与重油中的硫反应，以在重油中原位形成金属硫化物催化剂颗粒。 原位形成的金属硫化物催化剂颗粒催化重油和氢之间的有益升级反应，消除或减少焦炭前体和沉积物的形成。

公开(公告)号：US10118146B2

公开(公告)日：2018-11-06

申请号：US15354230

申请日：2016-11-17

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap-Keung Lee

IPC分类号： B01J8/08 ,  C10G49/12 ,  C10G45/16 ,  C10G45/56 ,  B01J8/22 ,  C10G47/26 ,  C10G67/08 ,  C10G65/02 ,  C10G49/00 ,  C10G45/04 ,  C10G45/34 ,  C10G45/46 ,  C10G47/06 ,  C10G65/00

摘要： A system and method for preparing and conditioning a heavy oil feedstock for hydroprocessing in a hydroprocessing system includes forming metal sulfide catalyst particles in situ within the heavy oil feedstock. The metal sulfide catalyst particles are formed in situ by (1) premixing a catalyst precursor with a hydrocarbon diluent to form a diluted precursor mixture, (2) mixing the diluted precursor mixture with the heavy oil feedstock to form a conditioned feedstock, and (3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil feedstock to form metal sulfide catalyst particles in situ in the heavy oil feedstock. The in situ formed metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil feedstock and hydrogen and eliminates or reduces formation of coke precursors and sediment.

公开(公告)号：US08673130B2

公开(公告)日：2014-03-18

申请号：US13866220

申请日：2013-04-19

申请人： Headwaters Heavy Oil, LLC

发明人： Roger K. Lott ,  Lap-Keung Lee

IPC分类号： C10G47/26 ,  C10G47/02

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydroprocessing method and system involves introducing heavy oil and well-dispersed metal sulfide catalyst particles, or a catalyst precursor capable of forming the well-dispersed metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The well-dispersed or in situ metal sulfide catalyst particles are formed by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the well-dispersed or in situ metal sulfide catalyst particles. The well-dispersed or in situ metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

摘要翻译： 加氢处理方法和系统包括将重油和分散均匀的金属硫化物催化剂颗粒或能够在重油内原位形成良好分散的金属硫化物催化剂颗粒的催化剂前体引入加氢处理反应器。 通过以下方式形成良好分散或原位的金属硫化物催化剂颗粒：1）将催化剂前体与烃稀释剂预混合以形成前体混合物，2）将前体混合物与重油混合以形成调节原料，和3） 调节原料以分解催化剂前体并引起或允许来自前体的金属与重油中的硫反应以形成良好分散或原位的金属硫化物催化剂颗粒。 良好分散或原位金属硫化物催化剂颗粒催化重油和氢之间的有益升级反应，消除或减少焦炭前体和沉淀物的形成。

公开(公告)号：US20130228494A1

公开(公告)日：2013-09-05

申请号：US13866220

申请日：2013-04-19

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap Keung Lee

IPC分类号： C10G67/08

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydroprocessing method and system involves introducing heavy oil and well-dispersed metal sulfide catalyst particles, or a catalyst precursor capable of forming the well-dispersed metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The well-dispersed or in situ metal sulfide catalyst particles are formed by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the well-dispersed or in situ metal sulfide catalyst particles. The well-dispersed or in situ metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

摘要翻译： 加氢处理方法和系统包括将重油和分散均匀的金属硫化物催化剂颗粒或能够在重油内原位形成良好分散的金属硫化物催化剂颗粒的催化剂前体引入加氢处理反应器。 通过以下方式形成良好分散或原位的金属硫化物催化剂颗粒：1）将催化剂前体与烃稀释剂预混合以形成前体混合物，2）将前体混合物与重油混合以形成调节原料，和3） 调节原料以分解催化剂前体并引起或允许来自前体的金属与重油中的硫反应以形成良好分散或原位的金属硫化物催化剂颗粒。 良好分散或原位金属硫化物催化剂颗粒催化重油和氢之间的有益升级反应，消除或减少焦炭前体和沉淀物的形成。

公开(公告)号：US09920261B2

公开(公告)日：2018-03-20

申请号：US13865726

申请日：2013-04-18

申请人： Headwaters Heavy Oil, LLC

发明人： Roger K. Lott ,  Lap Keung Lee

IPC分类号： C10G47/06 ,  C10G47/26 ,  B01J8/08 ,  C10G45/16 ,  C10G45/56 ,  B01J8/22 ,  C10G67/08 ,  C10G65/02 ,  C10G49/00 ,  C10G49/12 ,  C10G45/04 ,  C10G45/34 ,  C10G45/46 ,  C10G65/00

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydrocracking system is upgraded by modifying an existing ebullated bed initially utilizing a supported ebullated bed catalyst to thereafter utilize a dual catalyst system that includes metal sulfide catalyst particles and supported ebullated bed catalyst. The upgraded hydrocracking system achieves at least one of: (1) hydroprocess lower quality heavy oil; (2) increase conversion of higher boiling hydrocarbons that boil at 524° C. (975° F.) or higher; (3) reduce the concentration of supported ebullated bed catalyst required to operate an ebullated bed reactor at a given conversion level; and/or (4) proportionally convert the asphaltene fraction in heavy oil at the same conversion level as the heavy oil as a whole. The metal sulfide catalyst may include colloidal or molecular catalyst particles less than 1 micron in size and formed in situ within the heavy oil using a catalyst precursor well-mixed within the heavy oil and decomposed to form catalyst particles.

公开(公告)号：US09605215B2

公开(公告)日：2017-03-28

申请号：US14095698

申请日：2013-12-03

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap Keung Lee

IPC分类号： C10G49/10 ,  B01J8/08 ,  C10G49/00 ,  B01J8/22 ,  C10G47/26 ,  C10G67/08 ,  C10G65/02 ,  C10G49/12

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydroprocessing system involves introducing heavy oil and in situ formed metal sulfide catalyst particles, or a catalyst precursor capable of forming metal sulfide catalyst particles in situ within the heavy oil, into a hydroprocessing reactor. The metal sulfide catalyst particles are formed in situ by 1) premixing a catalyst precursor with a hydrocarbon diluent to form a precursor mixture, 2) mixing the precursor mixture with heavy oil to form a conditioned feedstock, and 3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil to form the metal sulfide catalyst particles in situ in the heavy oil. The in situ formed metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil and hydrogen and eliminates or reduces formation of coke precursors and sediment.

公开(公告)号：US20170066978A1

公开(公告)日：2017-03-09

申请号：US15354230

申请日：2016-11-17

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap-Keung Lee

IPC分类号： C10G65/00 ,  C10G45/04 ,  B01J8/22 ,  C10G45/46 ,  B01J8/08 ,  C10G47/06 ,  C10G45/34

CPC分类号： B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/06 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A system and method for preparing and conditioning a heavy oil feedstock for hydroprocessing in a hydroprocessing system includes forming metal sulfide catalyst particles in situ within the heavy oil feedstock. The metal sulfide catalyst particles are formed in situ by (1) premixing a catalyst precursor with a hydrocarbon diluent to form a diluted precursor mixture, (2) mixing the diluted precursor mixture with the heavy oil feedstock to form a conditioned feedstock, and (3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil feedstock to form metal sulfide catalyst particles in situ in the heavy oil feedstock. The in situ formed metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil feedstock and hydrogen and eliminates or reduces formation of coke precursors and sediment.

摘要翻译： 用于在加氢处理系统中制备和调节用于加氢处理的重油原料的系统和方法包括在重油原料内原位形成金属硫化物催化剂颗粒。 金属硫化物催化剂颗粒通过（1）预先混合催化剂前体与烃稀释剂以形成稀释的前体混合物而原位形成，（2）将稀释的前体混合物与重油原料混合以形成调节原料，和（3 加热经调理的原料以分解催化剂前体并引起或允许来自前体的金属与重油原料中的硫反应，以在重油原料中原位形成金属硫化物催化剂颗粒。 原位形成的金属硫化物催化剂颗粒催化重油原料和氢之间的有益升级反应，消除或减少焦炭前体和沉淀物的形成。

公开(公告)号：US20130233765A1

公开(公告)日：2013-09-12

申请号：US13865726

申请日：2013-04-18

申请人： HEADWATERS HEAVY OIL, LLC

发明人： Roger K. Lott ,  Lap Keung Lee

IPC分类号： C10G65/02

CPC分类号： C10G47/06 ,  B01J8/08 ,  B01J8/22 ,  B01J8/226 ,  C10G45/04 ,  C10G45/16 ,  C10G45/34 ,  C10G45/46 ,  C10G45/56 ,  C10G47/26 ,  C10G49/005 ,  C10G49/12 ,  C10G65/00 ,  C10G65/02 ,  C10G67/08 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/4056 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2300/802

摘要： A hydrocracking system is upgraded by modifying an existing ebullated bed initially utilizing a supported ebullated bed catalyst to thereafter utilize a dual catalyst system that includes metal sulfide catalyst particles and supported ebullated bed catalyst. The upgraded hydrocracking system achieves at least one of: (1) hydroprocess lower quality heavy oil; (2) increase conversion of higher boiling hydrocarbons that boil at 524° C. (975° F.) or higher; (3) reduce the concentration of supported ebullated bed catalyst required to operate an ebullated bed reactor at a given conversion level; and/or (4) proportionally convert the asphaltene fraction in heavy oil at the same conversion level as the heavy oil as a whole. The metal sulfide catalyst may include colloidal or molecular catalyst particles less than 1 micron in size and formed in situ within the heavy oil using a catalyst precursor well-mixed within the heavy oil and decomposed to form catalyst particles.

摘要翻译： 首先通过使用支持的沸腾床催化剂改性现有的沸腾床，然后利用包括金属硫化物催化剂颗粒和负载的沸腾床催化剂的双重催化剂体系来提升加氢裂化系统。 升级的加氢裂化系统达到以下至少一个：（1）加氢处理较低质量的重油; （2）提高在524°C（975°F）或更高沸点的高沸点烃的转化率; （3）降低在给定转化水平下操作沸腾床反应器所需的支撑沸腾床催化剂的浓度; 和/或（4）以与整个重油相同的转化水平比例地将重油中的沥青质馏分成比例地转化。 金属硫化物催化剂可以包括尺寸小于1微米的胶体或分子催化剂颗粒，并使用在重油中充分混合并分解形成催化剂颗粒的催化剂前体在重油内原位形成。