摘要:
Process for the continuous preparation of N-ethyl-2-pyrrolidone (NEP) by reacting gamma-butyrolactone (GBL) with monoethylamine (MEA) in the liquid phase, wherein GBL and MEA are used in a molar ratio in the range from 1:1.08 to 1:2 an the reaction is carried out at a temperature in the range from 320 to 420° C. and an absolute pressure in the range from 70 to 120 bar.
摘要:
Process for the continuous preparation of N-ethyl-2-pyrrolidone (NEP) by reacting gamma-butyrolactone (GBL) with monoethylamine (MEA) in the liquid phase, wherein GBL and MEA are used in a molar ratio in the range from 1:1.08 to 1:2 an the reaction is carried out at a temperature in the range from 320 to 420° C. and an absolute pressure in the range from 70 to 120 bar.
摘要:
A process for preparing nitric acid by: catalytically oxidizing ammonia, to obtain a gas mixture containing NO and O2; cooling and condensing the gas mixture, thereby further oxidizing NO with O2, to obtain a gas stream containing NO2/N2O4 and an aqueous solution containing nitric acid; and countercurrently absorbing the NO2/N2O4 from the gas stream in an absorber with process water (H2O), to obtain nitric acid and an NOx-containing absorber offgas, wherein the water content of the nitric acid is regulated to a concentration in the range from 50 to 77.8% by weight and the NOx content of the absorber offgas to a concentration in the range from 20 to 500 ppm, by continuously measuring the water content of the process air supplied to the catalytic gas phase oxidation and, as a function of this, adjusting the amount of process water (Q-H2O) fed to the absorber.
摘要翻译:一种通过以下方式制备硝酸的方法:催化氧化氨,得到含NO和O2的气体混合物; 冷却并冷凝气体混合物,从而进一步用O 2氧化NO,得到含有NO 2 / N 2 O 4的气流和含有硝酸的水溶液; 并用工艺用水(H 2 O)从吸收器中的气流中逆流吸收NO 2 / N 2 O 4,得到硝酸和含NO x的吸收剂废气,其中将硝酸的含水量调节至 50至77.8重量%,并且通过连续测量供应到催化气相氧化的工艺空气的水含量,吸收器的NOx含量废气至浓度在20至500ppm的范围内,并且作为其功能 ,调节供给到吸收器的工艺用水(Q-H 2 O)的量。
摘要:
What is proposed is a process for preparing nitric acid with a concentration in the range from 50 to 77.8% by weight by catalytic gas phase oxidation of ammonia (1) with a superstoichiometric proportion of process air (2) to obtain a gas mixture (3) comprising NO and O2, cooling/condensation of the gas mixture (3) comprising NO and O2, in the course of which NO is oxidized further by O2 to NO2/N2O4 to obtain an aqueous solution (4) comprising nitric acid and a gas stream (5) comprising NO2/N2O4 and countercurrent absorption of the NO2/N2O4 from the gas stream (5) comprising NO2/N2O4 in process water (H2O) in an absorber (A) to obtain the nitric acid (7) with a concentration in the range from 50 to 77.8% by weight and an NOx comprising absorber offgas (6), wherein the water content of the nitric acid (7) is regulated to a concentration in the range from 50 to 77.8% by weight and the NOx content of the absorber offgas (6) to a concentration in the range from 20 to 500 ppm, by continuously measuring the water content of the process air (2) supplied to the catalytic gas phase oxidation and, as a function of this, adjusting the amount of process water (Q-H2O) fed to the absorber (A).
摘要翻译:提出的方法是用超化学计量比例的工艺空气(2)通过氨(1)的催化气相氧化制备浓度在50至77.8重量%范围内的硝酸的方法以获得气体混合物(3 ),其包含NO和O 2的气体混合物(3)的冷却/冷凝,其中NO通过O 2进一步氧化成NO 2 / N 2 O 4,以获得包含硝酸和气体的水溶液(4) 包含NO 2 / N 2 O 4的流(5)和来自在吸收器(A)中的处理水(H 2 O)中的包含NO 2 / N 2 O 4的气流(5)的NO 2 / N 2 O 4的逆流吸收,以获得具有浓度的硝酸 在50至77.8重量%的范围内,和包含吸收剂废气(6)的NOx,其中将硝酸(7)的含水量调节至50至77.8重量%的浓度,并且NOx含量 的吸收剂废气(6)浓度达到20〜500ppm的浓度 y测量供应到催化气相氧化的工艺空气(2)的含水量,并且作为其功能,调节进料到吸收器(A)的工艺用水(Q-H 2 O)的量。