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公开(公告)号：US4432858A
公开(公告)日：1984-02-21
申请号：US402312
申请日：1982-07-27
申请人： Helmut Schmitt , Helmuth Schurig , Bernd Strasser
发明人： Helmut Schmitt , Helmuth Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： An electrolyzer for producing an aqueous alkali hydroxide solution, halogen, and hydrogen from an aqueous halogenide-bearing electrolyte. The electrolyzer includes a plurality of alternating anolyte and catholyte chambers each formed by a pair of anode plates and cathode plates, respectively. Seals are provided between and around the perimeter of the two anode and cathode plates to define the chambers. A flat membrane member, permeable to ions is disposed between adjacent anode and cathode plates. The anode and cathode plate and seals include passages for the flow of process fluids. Each anode and cathode plate comprises an active portion permeable to the flow of gas and liquid and an inactive portion impermeable to the flow of gas and liquid.
摘要翻译： 一种用于从含有卤化氢的电解质水溶液中生产碱金属氢氧化物水溶液，卤素和氢的电解槽。 电解器包括分别由一对阳极板和阴极板形成的多个交替的阳极电解液和阴极电解液室。 密封件设置在两个阳极板和阴极板的周边之间和周围，以限定室。 在相邻的阳极和阴极板之间设置有可离子离子的平膜组件。 阳极和阴极板和密封件包括用于流动流体流动的通道。 每个阳极和阴极板包括对气体和液体流可渗透的有效部分和不透气体和液体的不活动部分。
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公开(公告)号：US4426270A
公开(公告)日：1984-01-17
申请号：US402313
申请日：1982-07-27
申请人： Helmut Schmitt , Helmuth Schurig , Bernd Strasser
发明人： Helmut Schmitt , Helmuth Schurig , Bernd Strasser
CPC分类号： C25B9/20
摘要： An electrolyzer is provided for processing fluids. The electrolyzer includes electrode plates having laterally extending electrical busses. The electrode plates are mounted in a non-conducting external frame having a plurality of ducts for the flow of process fluids between the electrolyte chamber and the ducts. Seals are provided between the electrode plates and the external frame.
摘要翻译： 提供一种用于处理流体的电解器。 电解器包括具有横向延伸的电气总线的电极板。 电极板安装在具有多个管道的非导电外部框架中，用于在电解质室和导管之间流动工艺流体。 密封件设置在电极板和外部框架之间。
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公开(公告)号：US4299681A
公开(公告)日：1981-11-10
申请号：US118560
申请日：1980-02-04
申请人： Luciano Mose , Helmuth Schurig , Bernd Strasser
发明人： Luciano Mose , Helmuth Schurig , Bernd Strasser
CPC分类号： C25B9/206
摘要： Hydrochloric acid electrolyzers serve to decompose hydrochloric acid to hydrogen and chlorine with the aid of electric current.
摘要翻译： 盐酸电解槽用于借助电流将盐酸分解成氢和氯。
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公开(公告)号：US4392937A
公开(公告)日：1983-07-12
申请号：US372099
申请日：1982-04-26
申请人： Helmut Schmitt , Wolfgang Strewe , Helmuth Schurig
发明人： Helmut Schmitt , Wolfgang Strewe , Helmuth Schurig
摘要： An electrolysis cell having an inlet and an outlet for transient electrolytes and including monopolar electrodes arranged in a staggered pattern such that the electrode plates of one polarity extend into the gaps formed between the electrode plates of the opposite polarity.
摘要翻译： 一种电解槽，其具有用于瞬态电解质的入口和出口，并且包括以交错图案布置的单极电极，使得一个极性的电极板延伸到形成在相反极性的电极板之间的间隙中。
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公开(公告)号：US4444639A
公开(公告)日：1984-04-24
申请号：US402306
申请日：1982-07-27
申请人： Helmuth Schurig , Helmut Schmitt
发明人： Helmuth Schurig , Helmut Schmitt
摘要： An electrolyzer is provided which includes at least one set of closely spaced electrode assemblies consisting of a flat anode and a flat cathode separated by a membrane permeable to ions. One side of the electrode assembly is supported by a rigid pressure plate while a flexible pressure plate disposed along the opposite side of the electrode assembly biased the anode and cathode towards each other. The flexible pressure plate includes a flat portion having contact pads struck and formed therefrom. The contact pads are sized to cover from 30 to 70% of the overall plate surface and include portions which are plane-parallel to the flat portion. The contact pads bent to one side are designed to be vertical on a longitudinal axis after mounting of the flexible pressure plate in an electrolyzer.
摘要翻译： 提供了一种电解器，其包括至少一组紧密间隔的电极组件，该电极组件包括由可透过离子的膜隔开的平坦阳极和平坦阴极。 电极组件的一侧由刚性压力板支撑，而沿着电极组件的相对侧布置的柔性压力板将阳极和阴极朝向彼此偏置。 柔性压板包括具有触点并由其形成的接触垫的平坦部分。 接触垫的尺寸设置成覆盖整个板表面的30至70％，并且包括平面平行于平坦部分的部分。 弯曲到一侧的接触垫在将柔性压力板安装在电解器中之后被设计成在纵向轴线上垂直。
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公开(公告)号：US4664770A
公开(公告)日：1987-05-12
申请号：US818790
申请日：1986-01-14
申请人： Helmut Schmitt , Helmuth Schurig , Dieter Bergner , Kurt Hannesen
发明人： Helmut Schmitt , Helmuth Schurig , Dieter Bergner , Kurt Hannesen
IPC分类号： C25B9/00 , C25B1/34 , C25B1/46 , C25B9/06 , C25B9/08 , C25B9/20 , C25B11/02 , C25B9/04 , C25B11/03
摘要： An electrolyzer for the production of chlorine from an aqueous alkaline halide solution includes a plurality of electrolysis cells each having a housing of two half-shells. The bottom side of each of the half-shells is in a plane parallel to a plane of an adjacent anode or cathode, the space between the bottom side and the anode or the cathode being provided with framework-pattern metallic reinforcements. Each bottom side has one or more contact strips attached to its outer surface which are arranged in a congruent position to the contact strips on the bottom side of the adjacent electrolysis cell, and extend over the length or width of the cell. The contact strips are aligned with and connected by electrically conducting means to part of the framework-pattern reinforcements and the unperforated sections of the adjacent anode or cathode. The two half-shells and a membrane partition wall are assembled to form an electrolysis cell sealed by two gaskets.
摘要翻译： 用于从碱性卤化物水溶液生产氯的电解器包括多个电解槽，每个电解槽具有两个半壳的外壳。 每个半壳的底侧在平行于相邻阳极或阴极的平面的平面内，底侧和阳极或阴极之间的空间设置有框架图案金属增强件。 每个底侧具有附接到其外表面的一个或多个接触条，其被布置在相邻电解槽的底侧上的接触条的一致位置，并且在电池的长度或宽度上延伸。 接触条与导电装置对准并连接到框架图案加强件的一部分和相邻阳极或阴极的未穿孔部分。 将两个半壳和隔膜分隔壁组装形成由两个垫圈密封的电解池。
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公开(公告)号：US4469577A
公开(公告)日：1984-09-04
申请号：US498009
申请日：1983-05-25
申请人： Helmut Schmitt , Helmuth Schurig , Wolfgang Strewe
发明人： Helmut Schmitt , Helmuth Schurig , Wolfgang Strewe
摘要： The invention relates to a membrane electrolysis cell of the filter press type with one or more plate-type electrode pairs, each comprising at least one non-continuous active central part, with a membrane provided between the electrode pairs, and with a seal installed between each electrode and membrane rim. The membrane cell is suitable for the production of an aqueous alkali metal hydroxide solution (cell liquor) as well as of halogen and hydrogen by electrolyzing an aqueous halide-bearing electrolyte (brine).The non-continuous central part of the electrodes has a grid-type structure, the grid rods of the electrode pairs are staggered by a maximum of half the rod width, the grid rods of the electrodes are arranged so that their interspace is smaller than the projection of their width, the grid rods have a convex face at least on the active side, and the thickness of the seals between the electrode and membrane rims is equal or inferior to the height of the grid rod portion protruding over the electrode rim.
摘要翻译： 本发明涉及一种具有一个或多个平板型电极对的压滤型膜分离电解槽，每个包括至少一个非连续的活性中心部分，其中设置在电极对之间的膜， 每个电极和膜缘。 膜电池适用于通过电解含卤素的电解质（盐水）来生产碱金属氢氧化物水溶液（电池液）以及卤素和氢气。 电极的非连续中心部分具有栅格型结构，电极对的栅极棒以最大一半的杆宽度交错排列，电极的栅极棒排列成使其间隙小于 其宽度的突出部分，网格杆至少在活动侧具有凸面，并且电极和膜边缘之间的密封件的厚度等于或低于在电极边缘上突出的网格杆部分的高度。
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公开(公告)号：US4378286A
公开(公告)日：1983-03-29
申请号：US220595
申请日：1980-12-29
CPC分类号： C25B9/20
摘要： A filter press type electrolytic cell for the electrolysis of brine to produce chlorine and caustic includes a plurality of rectangular frames having U-shaped or channel-shaped walls, the open sides of each of which wall members face inwardly, and a downcomer tube in each frame for conducting product from near the top of the frame to the bottom thereof for withdrawal. The downcomer tubes are located near a framing side but are not within a framing channel. The openings of the framing walls are partially covered by cross members of the same material as the framing to improve the resistance thereof to distortion during closing of the cell. Utilization of the downcomer tubes, preferably of polytetrafluoroethylene for the catholyte compartment and titanium or titanium clad material for the anolyte compartment, allows the maintaining of the framing channel open so that inner walls thereof are electrolytically protected against corrosion. Otherwise, when enclosed or tubular framing members are employed inner wall portions thereof can become corroded after relatively short periods of use. The invention also relates to frames for use in filter press type electrolytic cells and to a method of electrolyzing, wherein such frames and cells may be employed.
摘要翻译： 用于电解盐水以产生氯和苛性碱的压滤式电解槽包括多个具有U形或槽形壁的矩形框架，每个壁构件的开口侧面向内，每个壁构件的开口侧面向内 用于从靠近框架的顶部到底部进行产品以用于抽出。 降液管位于框架边附近，但不在框架通道内。 框架壁的开口部分地被与框架相同的材料的横向构件覆盖，以提高其在闭孔期间的变形阻力。 利用降液管，优选聚四氟乙烯用于阴极电解液室和用于阳极电解液室的钛或钛包层材料，允许保持框架通道打开，使得其内壁被电解保护以免受腐蚀。 否则，当使用封闭或管状框架构件时，其内壁部分在相对短的使用时间后可能被腐蚀。 本发明还涉及用于压滤式电解槽的框架和电解方法，其中可以采用这种框架和单元。
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