Process for the continuous coagulation of vinyl polymer latices
    2.
    发明授权
    Process for the continuous coagulation of vinyl polymer latices 失效
    乙烯基聚合物胶乳的连续凝结方法

    公开(公告)号:US5314990A

    公开(公告)日:1994-05-24

    申请号:US692496

    申请日:1991-04-29

    IPC分类号: C08J3/16 C08F6/22 C08F6/16

    CPC分类号: C08F6/22

    摘要: A process for the continuous processing of vinyl polymer latices to produce thermoplastically processible vinyl polymer powder by coagulating a stream of a vinyl polymer latex by the addition of a stream of a coagulant with intensive mixing and shearing in a cascade of vessels at an average residence time per vessel of 10 to 60 minutes and at temperatures from 50 to 120.degree. C., volatile auxiliary substances and residual monomers in the polymer being optionally removed by steam distillation and part of the serum separated from the vinyl polymer being added to the stream of coagulant.

    摘要翻译: 一种连续处理乙烯基聚合物胶乳以通过凝结乙烯基聚合物胶乳物流的方式连续处理乙烯基聚合物胶乳的方法,该方法是通过在凝结剂流中加入混合物并在平均停留时间的梯级下进行剪切 每个容器10至60分钟,温度为50至120℃,通过蒸汽蒸馏任选除去聚合物中的挥发性辅助物质和残留单体,并将部分从乙烯基聚合物中分离的血清加入到凝结剂流中 。

    Mixtures of thermoplastic polymers in powder form
    3.
    发明授权
    Mixtures of thermoplastic polymers in powder form 失效
    粉末形式的热塑性聚合物的混合物

    公开(公告)号:US5112910A

    公开(公告)日:1992-05-12

    申请号:US743678

    申请日:1991-08-12

    摘要: Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.

    摘要翻译: 制备粉末形式的热塑性聚合物的混合物的方法,该方法由以下混合物的水性乳液制备:a)丙烯酸C 2 -C 8烷基酯和/或丁二烯与(基于共聚物)的至少40重量%的颗粒部分交联的橡胶状共聚物。 丙烯腈,苯乙烯或甲基丙烯酸C 1 -C 4烷基酯,b)热塑性树脂,如果合适,c)在二烯或烷基上的苯乙烯,α-甲基苯乙烯,丙烯腈,甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶,其橡胶含量为50〜95重量% %,其中a)和b)和如果合适的水性乳液c)具有15至50重量%的聚合物含量。 %与凝固溶液同时混合,但在单独的流中,在20℃至100℃连续或半连续,聚合物a)和b),如果合适,c)凝结,将流合并,聚合物 混合物然后分离出来。

    Sequential copolymers based on cyclic carbonates and esters
    6.
    发明授权
    Sequential copolymers based on cyclic carbonates and esters 失效
    基于环状碳酸酯和酯的顺序共聚物

    公开(公告)号:US4965300A

    公开(公告)日:1990-10-23

    申请号:US443041

    申请日:1989-11-27

    IPC分类号: C08G63/64 C08G64/00 C08G64/18

    CPC分类号: C08G64/18

    摘要: Polymers having a sequential structure of the following formula--A--X--B].sub.r (I)with r=1 to 20, in which --A-- is a polymer of a cyclic carbonate, --B-- is a polymer of a lactone and --X-- is a link, with a decreasing concentration of residues of the cyclic carbonate in the --B-- direction and a decreasing concentration of residues of the lactone in the --A-- direction, and the use of the these products as molding compositions.

    摘要翻译: 具有以下式的顺序结构的聚合物-AXB] r(I),其中r = 1至20,其中-A-是环状碳酸酯的聚合物,-B-是内酯的聚合物,-X-是 一个环节,环状碳酸酯在-B-方向的残留浓度降低,内酯残留在-A-方向上的浓度降低,以及这些产物用作模塑组合物。