公开(公告)号：US6046311A

公开(公告)日：2000-04-04

申请号：US44509

申请日：1998-03-19

Applicant: Wilfried Hansmann ,  Hermann Henk ,  Stefan Ehrenberg ,  Wolfram Reddig

Inventor： Wilfried Hansmann ,  Hermann Henk ,  Stefan Ehrenberg ,  Wolfram Reddig

IPC: C09B62/008 ,  C09B62/01 ,  C09B62/02 ,  C09B62/085 ,  C09B62/20 ,  C09B62/44 ,  C09B62/245

CPC classification number: C09B62/20 ,  C09B62/02 ,  C09B62/4401

Abstract: Dyes containing a 5,6-difluoropyrimidin-4-yl radical as fiber-reactive group are useful for dyeing hydroxy- and/or carboxamido-containing material, including fiber material, for example cellulose fibers, wool and polyamide.

Abstract translation: 含有作为纤维反应性基团的5,6-二氟嘧啶-4-基的染料可用于染色含有羟基和/或羧酰氨基的材料，包括纤维材料，例如纤维素纤维，羊毛和聚酰胺。

公开(公告)号：US4772687A

公开(公告)日：1988-09-20

申请号：US858404

申请日：1986-05-01

Applicant: Hermann Henk

Inventor： Hermann Henk

IPC: C09B45/24 ,  C09B62/012 ,  C09B62/44 ,  C09B62/032 ,  C09B62/515 ,  D06P1/382 ,  D06P1/384

CPC classification number: C09B62/4401 ,  C09B45/24 ,  C09B62/012

Abstract: Metal complex dyestuffs which in the form of the free acid correspond to the formula ##STR1## in which the substituents have the meaning given in the description are, depending on the meanings of the substituents, suitable for use as reactive dyestuffs for cotton, wool or polyamide, as direct dyestuffs for cotton or as pigment dyestuffs. Dyeings are obtained which have good fastness properties, in particular good wet-, light- and chlorine fastness.

Abstract translation: 游离酸形式的金属络合物染料对应于其中取代基具有本说明书给出的含义的式（I）取决于适用于棉花活性染料的取代基的含义 ，羊毛或聚酰胺，作为棉花或颜料染料的直接染料。 得到具有良好牢度性能，特别是良好的耐湿，耐光和耐氯牢度的染色。

公开(公告)号：US4563518A

公开(公告)日：1986-01-07

申请号：US198747

申请日：1980-10-20

Applicant: Hermann Henk

Inventor： Hermann Henk

IPC: C09B62/085 ,  D06P1/382 ,  D06P3/10 ,  D06P3/66

CPC classification number: C09B62/085

Abstract: The invention relates to fibre-reactive monoazo dyestuffs of the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 and n have the meaning given in the text of the application, and also relates to a process for the preparation of these dyestuffs and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as wool and cotton.

Abstract translation: 本发明涉及通式“IMAGE”的纤维反应性单偶氮染料，其中R1，R2，R3，R4，R5和R6和n具有本申请案文中给出的含义，还涉及一种制备方法 的这些染料以及它们用于染色和印刷含有羟基或酰胺基团的物质，例如羊毛和棉花。

公开(公告)号：US4540776A

公开(公告)日：1985-09-10

申请号：US608587

申请日：1984-05-09

Applicant: Hermann Henk ,  Erich Kramer ,  Karl H. Schundehutte ,  Horst Nickel

Inventor： Hermann Henk ,  Erich Kramer ,  Karl H. Schundehutte ,  Horst Nickel

IPC: C09B62/085 ,  C09B62/08 ,  C09B62/095 ,  D06P1/382

CPC classification number: C09B62/085

Abstract: A metal free azo dyestuff of the formula ##STR1## in which K is the radical of a coupling component of pyridone, andR.sub.3 and R.sub.4 each independently is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.1 -C.sub.6 -alkyl substituted by OH, SO.sub.3 H, COOH or OSO.sub.3 H; phenyl; naphthyl; or phenyl or naphthyl substituted by SO.sub.3 H or COOH.

Abstract translation: 一种不含金属的偶氮染料，其中K是吡啶酮的偶联组分，R3和R4各自独立地为氢; C 1 -C 6 - 烷基; 被OH，SO 3 H，COOH或OSO 3 H取代的C 1 -C 6烷基; 苯基; 萘基; 或被SO 3 H或COOH取代的苯基或萘基。

公开(公告)号：US06852135B2

公开(公告)日：2005-02-08

申请号：US10312900

申请日：2001-07-14

Applicant: Joachim Steckelberg ,  Hermann Henk

Inventor： Joachim Steckelberg ,  Hermann Henk

IPC: C09B62/095 ,  C09B62/44 ,  C09B62/515 ,  D06P1/382 ,  D06P1/384 ,  D06P1/673 ,  D06P3/10 ,  D06P3/66 ,  D06P5/20

CPC classification number: C09B62/095 ,  C09B62/4416 ,  C09B62/515

Abstract: Dyes of the general formula (1): where M is hydrogen, alkali, ammonium or the equivalent of an alkaline earth metal ion, X is halogen, alkoxy or an N-containing heterocycle, Q is a grouping of the formula (e) where Y is vinyl or an alkali-eliminable grouping and W is alkyl which may be interrupted by an O or an NR group and the radicals R1 and R2 represent alkyl, alkoxy, alkylcarbonylamino, arylcarbonylamino, and also the radicals R3 and R4 are alkyl or hydrogen, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.

Abstract translation: 通式（1）的染料：其中M是氢，碱金属，铵或碱土金属离子当量，X是卤素，烷氧基或含氮杂环，Q是式（e）的组，其中 Y是乙烯基或可碱除去的基团，W是可被O或NR基团中断的烷基，基团R 1和R 2代表烷基，烷氧基，烷基羰基氨基，芳基羰基氨基， 3>和R 4是烷基或氢，它们的制备及其用于染色和印刷含羟基和/或甲酰氨基的材料，优选纤维材料的用途。

公开(公告)号：US5256773A

公开(公告)日：1993-10-26

申请号：US990631

申请日：1992-12-14

Applicant: Klaus Kunde ,  Hermann Henk ,  Karl-Heinz Schundehutte, deceased ,  Frank-Michael Stohr

Inventor： Klaus Kunde ,  Hermann Henk ,  Karl-Heinz Schundehutte, deceased ,  Frank-Michael Stohr

IPC: C09B62/255 ,  D06P1/382

CPC classification number: C09B62/255 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

Abstract: The reactive dyes of the formula ##STR1## in which the substituents and indices have the meaning given in the description, are outstandingly suitable for dyeing or printing naturally occurring or synthetic materials containing hydroxyl or amide groups.

Abstract translation: 其中取代基和指数具有在说明书中给出的含义的式“IMAGE”+ TR 的活性染料非常适合于染色或印刷含有羟基或酰胺基团的天然存在或合成的材料。

公开(公告)号：US5093481A

公开(公告)日：1992-03-03

申请号：US275441

申请日：1988-11-23

Applicant: Hermann Henk ,  Karl-Josef Herd ,  Frank-Michael Stohr

Inventor： Hermann Henk ,  Karl-Josef Herd ,  Frank-Michael Stohr

IPC: C09B62/51 ,  C09B62/44

CPC classification number: C09B62/4401

Abstract: Dyestuffs of the formula ##STR1## where the substituents have the meanings indicated in the description produce on hydroxyl- and amido-containing materials dyeings of excellent fibre-dyestuff bond stability, excellent stability to oxidizing agents and good wet fastness properties.

Abstract translation: 具有式（1）所示的取代基的染料在含有羟基和酰氨基的材料上具有优异的纤维 - 染料键合稳定性，优异的氧化剂稳定性和良好的耐湿牢度性能的染色中产生。

公开(公告)号：US4670548A

公开(公告)日：1987-06-02

申请号：US133072

申请日：1980-03-24

Applicant: Jochen Westphal ,  Hermann Henk

Inventor： Jochen Westphal ,  Hermann Henk

IPC: C09B31/16 ,  C09B31/30

CPC classification number: C09B31/16 ,  C09B31/30

Abstract: Water-soluble dyestuffs of the formulaA--N.dbd.N--B--N.dbd.N--C--N.dbd.N--KwhereinA denotes sulphophenyl or sulphonaphthyl, which are optionally further substituted,B denotes sulpho-1,4-naphthylene, which is optionally further substituted,C denotes 1,4-phenylene or 1,4-naphthylene, which are optionally further substituted, andK denotes the radical of an optionally functionally modified coupling component of the hydroxybenzene series, aminobenzene series, aminopyrazole series, pyridone series or acetoacetic acid arylide series, or of barbituric acid or citrazinic acid,and their use for dyeing nitrogen-containing fibre materials, such as wool and polyamide, and for dyeing leather.

Abstract translation: 式AN = NBN = NCN = NK的水溶性染料其中A表示任选进一步取代的磺基苯基或磺基萘表示任选进一步取代的磺基-1,4-亚萘基，C表示1,4-亚苯基 或1,4-亚萘基，其任选进一步被取代，并且K表示羟基苯系列，氨基苯系列，氨基吡唑系列，吡啶酮系列或乙酰乙酸芳基化合物系列或巴比妥酸或柠檬酸的任选功能改性的偶联组分的基团 酸和它们用于染色含氮纤维材料如羊毛和聚酰胺以及染色皮革的用途。

公开(公告)号：US4548761A

公开(公告)日：1985-10-22

申请号：US502077

申请日：1983-06-08

Applicant: Martin Michna ,  Hermann Henk

Inventor： Martin Michna ,  Hermann Henk

IPC: C07C67/00 ,  C07C301/00 ,  C07C303/00 ,  C07C303/16 ,  C07C303/32 ,  C07C309/45 ,  C07C309/46 ,  C07C143/58

CPC classification number: C07C303/16

Abstract: Process for the preparation of 1-aminobenzene-2-sulphonic acids of the formula ##STR1## wherein R.dbd.H or a substituent andn=1-4,and their salts, in particular their alkali metal salts, by oxidation of compounds of the formula ##STR2## wherein R.sub.1 .dbd.H, a cation, in particular an alkali metal cation, or a radical of the formula ##STR3## characterized in that the oxidation is carried out in a weakly acidic to alkaline pH range. The process can also be carried out as a one-pot process, using the corresponding benzothiazoles as starting materials.

Abstract translation: 制备式“IMAGE”的1-氨基苯-2-磺酸的方法，其中R = H或取代基，n = 1-4，以及它们的盐，特别是其碱金属盐，通过氧化化合物 其中R1 = H，阳离子，特别是碱金属阳离子或式“IMAGE”的基团，其特征在于氧化在弱酸性至碱性pH范围内进行。 该方法也可以作为一锅法进行，使用相应的苯并噻唑作为起始原料。

公开(公告)号：US4514188A

公开(公告)日：1985-04-30

申请号：US538686

申请日：1983-10-03

Applicant: Martin Michna ,  Hermann Henk

Inventor： Martin Michna ,  Hermann Henk

IPC: C09B45/18 ,  C09B45/28 ,  D06P1/10 ,  D06P3/24 ,  D21H1/46

CPC classification number: C09B45/28 ,  D06P1/10 ,  Y10S534/01 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/919

Abstract: Use of mono-copper complexes of dyestuffs of the formula ##STR1## wherein X is H or SO.sub.3 H andR is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, halogen or sulpho,and of mixtures thereof with the bis-copper complexes of (II) in amounts of up to 50% by weight, for dyeing natural and synthetic materials, in particular cellulose materials, leather, wool and polyamide.

Abstract translation: 其中X为H或SO 3 H，R为H，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，羧基，卤素或磺酸基的式（II）的染料单铜配合物及其混合物 与（II）的双铜络合物的量为至多50重量％，用于染色天然和合成材料，特别是纤维素材料，皮革，羊毛和聚酰胺。