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公开(公告)号：US4952681A
公开(公告)日：1990-08-28
申请号：US205359
申请日：1988-07-27
IPC分类号： C09B29/00 , C09B62/35 , C09B29/033 , C09B29/33 , C09B29/36
CPC分类号： C09B29/0059
摘要： Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.
摘要翻译： 1.式I的化合物参见图示：EP0201896，P71，F3，其中X是氟，氯，溴，SO2E，OH，OCH3，OC2H5，OC3H7，OC4H9，OCH2 C6H5，OC6H11，OC6H5 ，OC 6 H 4 CH 3，OC 6 H 4 Cl，SH，SCH 3，SC 2 H 5，SC 3 H 7，SC 4 H 9，SCH 2 C 6 H 5，SC 2 H 4 OH，SCH 2 COOCH 3，SCH 2 COOC 2 H 5，SC 6 H 11，SC 6 H 5或SC 6 H 4 CH 2，E是烷基 ，链烯基，环烷基，芳烷基，芳基，氯，OH，CH3O，C2H5O，C3H7O，C4H9O，C6H5 -CH2O，C6H5 -CH2 -CH2O，C6H5O，CIC6H4O， CH 3 C 4 H 4 O，NH 2，NHCH 3，N（CH 3）2，NHC 2 H 5，N（C 2 H 5）2，NCH 4 H 9，N（C 4 H 9）2，NHC 6 H 5，NHC 6 H 4 -CH 3，NHC 6 H 4 Cl或NCH 3 C 6 H 5 ，Y是氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C 1 -C 4烷基，NO，NO 2，SO 3 H，CHO，CN， ，C 2 H 5 CO，C 6 H 5 CO，CH 3 SO 2，C 2 H 5 SO 2，C 6 H 5 SO 2或式-CH = B的基团，其中B是亚甲基活性化合物或胺的基团，K是 激进或 耦合部件。
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公开(公告)号：US5352774A
公开(公告)日：1994-10-04
申请号：US125666
申请日：1993-09-23
IPC分类号： C09B29/00 , C09B29/033 , C09B29/40 , D06P1/18
CPC分类号： C09B29/0059
摘要： The compounds of the general formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are very useful for dyeing synthetic fibers or plastics.
摘要翻译： 其中X是氟，氯，溴，SO2E或未取代或取代的羟基或巯基的通式I的化合物，E是烷基，烯基，环烷基，芳烷基，芳基，氯或未取代或取代的羟基或氨基，Y 氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C1-C4-烷基，可以通过亲电取代引入的基团或式 -CH = B，其中B是亚甲基活性化合物或胺的基团，K是偶合组分的基团，对于合成纤维或塑料的染色非常有用。
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公开(公告)号：US5283326A
公开(公告)日：1994-02-01
申请号：US884472
申请日：1992-05-13
IPC分类号： C09B29/00 , C09B29/033 , C09B29/06 , C09B29/36 , D06P1/18
CPC分类号： C09B29/0059
摘要： The compounds of the general formula ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are very useful for dyeing synthetic fibers or plastics.
摘要翻译： 其中X为氟，氯，溴，SO 2 E或未取代或取代的羟基或巯基的通式为“IMAGE”的化合物，E为烷基，烯基，环烷基，芳烷基，芳基，氯或未取代或取代的羟基或氨基，Y为 氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，T是氢，C 1 -C 4烷基，可以通过亲电取代引入的基团或式 - CH = B，其中B是亚甲基活性化合物或胺的基团，K是偶合组分的基团，对于合成纤维或塑料的染色非常有用。
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公开(公告)号：US4774324A
公开(公告)日：1988-09-27
申请号：US838195
申请日：1986-03-07
申请人： Hermann Loeffler , Ernst Schefczik
发明人： Hermann Loeffler , Ernst Schefczik
CPC分类号： C09B29/3639 , C09B29/0081
摘要： Compounds of the general formula I ##STR1## where X is unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, Y is chlorine, bromine, carbamyl or cyano, Z is hydrogen, carbamyl, cyano or acetyl, R is hydrogen or C.sub.1 -C.sub.3 -alkyl, R.sup.1 and R.sup.3 independently of one another are each hydrogen or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl, R.sup.2 is hydrogen or unsubstituted or substituted alkyl and R.sup.1 and R.sup.2, together with the nitrogen atom, form a saturated 5-membered or 6-membered ring, are particularly useful for dyeing textile fibers.
摘要翻译： 通式I的化合物其中X是未取代或取代的烷基，环烷基，芳烷基或芳基，Y是氯，溴，氨基甲酰基或氰基，Z是氢，氨基甲酰基，氰基或乙酰基，R是氢或C1-C3 烷基，R 1和R 3彼此独立地各自为氢或未取代或取代的烷基，烯基，环烷基，芳烷基或芳基，R 2为氢或未取代或取代的烷基，R 1和R 2与氮原子一起形成饱和5 或6元环，特别适用于染色纺织纤维。
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公开(公告)号：US5223607A
公开(公告)日：1993-06-29
申请号：US717048
申请日：1991-06-18
CPC分类号： C09B62/09
摘要： Reactive azo dyes useful for dyeing and printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1##wherem is 0, 1 or 2,n is 1 or 2,R.sup.1 and R.sup.2 are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,T is carboxyl or hydroxysulfonyl,Hal is fluorine or chlorine,Y is fluorine, chlorine or the radical NR.sup.1 R.sup.2, OR.sup.1 or SR.sup.1, where R.sup.1 and R.sup.2 are each as defined above, andthe ring A may be benzofused and/or substituted, with the proviso thata) the sum total of acidic groups is at least 8 and thatb) when the structural element of the formula ##STR2## is present and Y is fluorine or chlorine and T is hydroxysulfonyl, the sum total of hydroxysulfonyl radicals is at least 10.
摘要翻译： 可用于染色和印刷含羟基或含氮底物的活性偶氮染料具有式（1）其中m为0,1或2，n为1或2，R 1和R 2为氢或取代或未取代的式 C 1 -C 4 - 烷基，T是羧基或羟基磺酰基，Hal是氟或氯，Y是氟，氯或NR 1 R 2，OR 1或SR 1，其中R 1和R 2各自如上所定义，并且环A可以是苯并稠合的， /或取代，条件是a）酸性基团的总和至少为8，b）当存在式“IMAGE”的结构元素且Y为氟或氯且T为羟基磺酰基时，总和 的羟基磺酰基至少为10。
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公开(公告)号：US4668774A
公开(公告)日：1987-05-26
申请号：US726372
申请日：1985-04-23
CPC分类号： C09B69/04 , Y10S534/02
摘要： Novel dye salts of anionic dyes of the general formula I ##STR1## where F is a radical of an anionic dye, n is 1, 2, 3 or 4, and B.sup.1 and B.sup.2 independently of one another are each unsubstituted or substituted branched alkyl or alkyl-substituted cycloalkyl having a total of 10 to 36 carbon atoms, are very useful for dyeing solvents, printing inks or polymeric film-forming materials.
摘要翻译： 通式I的阴离子染料的新型染料盐其中F是阴离子染料的基团，n是1,2,3或4，并且彼此独立的B 1和B 2各自是未取代的或取代的支链烷基 或具有总共10至36个碳原子的烷基取代的环烷基对染色溶剂，印刷油墨或聚合物成膜材料非常有用。
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7.发明授权
公开(公告)号：US5330543A
公开(公告)日：1994-07-19
申请号：US141705
申请日：1993-10-27
申请人： Guenter Hansen , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Helmut Degen , Arno Lange , Clemens Grund
发明人： Guenter Hansen , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Helmut Degen , Arno Lange , Clemens Grund
CPC分类号： C09B29/0059 , C09B29/3639 , Y10S8/922
摘要： Azo dyes having the formula ##STR1## wherein the substituents are as defined in the specification and are useful for dyeing or printing textile materials.
摘要翻译： 具有式“IMAGE”的偶氮染料，其中取代基如说明书中所定义，并且可用于染色或印刷纺织材料。
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8.发明授权Cholorotriazine dyes with two azo chromophores exhibiting further reactive groups 失效具有两种AZO色素的氯化铝染料展示进一步的反应性组
公开(公告)号：US5200511A
公开(公告)日：1993-04-06
申请号：US860139
申请日：1992-03-30
申请人： Hermann Loeffler , Manfred Patsch
发明人： Hermann Loeffler , Manfred Patsch
IPC分类号： C09B62/09 , C09B62/04 , C09B62/44 , C09B62/513
CPC分类号： C09B62/043 , C09B62/4415
摘要： Reactive dyes of the formula ##STR1## where m is 0 or 1,A.sup.1 and A.sup.2 are different and each is a fiber-reactive radical or else, in the case of A.sup.2, hydrogen,D.sup.1 and D.sup.2 are substituted or unsubstituted phenylene, substituted or unsubstituted phenylenemethyl, substituted or unsubstituted naphthylene or substituted or unsubstituted naphthylenemethyl,K.sup.1 and K.sup.2 are each the radical of a coupling component of the aminonaphthalenesulfonic acid series andL is a bridge member,are useful for dyeing and printing hydroxyl- or nitrogen-containing substrates.
摘要翻译： 其中m为0或1的反应性染料，A1和A2不同，并且各自为纤维反应性基团，或者在A2的情况下，氢，D1和D2被取代或 未取代的亚苯基，取代或未取代的亚苯基甲基，取代或未取代的亚萘基或取代或未取代的萘基甲基，K1和K2各自为氨基萘磺酸系的偶联组分的基团，L为桥连构件，可用于染色和印刷羟基或 含氮底物。
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9.发明授权Reactive dyes with two or three nitrogen-containing haloheterocycles as reactive system 失效具有两种或三种含有硝酸的氢化物作为反应体系的反应性染料
公开(公告)号：US5149789A
公开(公告)日：1992-09-22
申请号：US490710
申请日：1990-03-08
申请人： Joerg L. Jessen , Klaus Pandl , Hermann Loeffler , Bernd Siegel , Manfred Patsch
发明人： Joerg L. Jessen , Klaus Pandl , Hermann Loeffler , Bernd Siegel , Manfred Patsch
CPC分类号： C09B62/043
摘要： Reactive dyes of the formula ##STR1## where 1 is 0 or 1,n is 0 or 1,E is nitrogen or C--Cl,A is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or --if E is C--C1--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.
摘要翻译： 式1的反应性染料，其中1为0或1，n为0或1，E为氮或C-Cl，A为通过亚氨基或C 1 -C 4烷基连接到三嗪环上的偶氮染料的基团， 烷基亚氨基，B-如果E是氮 - 是偶氮染料或甲an染料的基团，其在任一情况下通过亚氨基或C 1 -C 4 - 烷基亚氨基键合到三嗪环，否则 - 如果n是0- 是氟，氯或未取代或取代的氨基，或 - 如果E是C-C1 - 是氟，氯或甲基，则X1和X2独立于其他氟或氯，X3是氟或氯，或者 - 如果E是C -Cl-甲基磺酰基，Z 1和Z 2独立地为下式的基团：其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基，其中 条件是l和n不同时为0，并且如果E是C-Cl或如果n是0，并且Z1是式“IMAGE”的基团，其中L3和L4各自如上所定义，A也可以是t 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。
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公开(公告)号：US4988802A
公开(公告)日：1991-01-29
申请号：US483647
申请日：1990-02-23
申请人： Hermann Loeffler , Manfred Patsch
发明人： Hermann Loeffler , Manfred Patsch
IPC分类号： C09B62/085 , C09B62/03 , C09B62/09
摘要： Reactive dyes which possess three reactive groups and conform to the formula ##STR1## where R.sup.1 is hydrogen, methyl or ethyl,X is hydrogen or hydroxysulfonyl,Hal is fluorine or chlorine,D is phenylene, carboxyl- hydroxysulfonyl-monosubstituted or -disubstituted phenylene or hydroxysulfonylmonosubstituted or -disubstituted naphthylene, andA is a reactive group which reacts only substitutively with the hydroxyl groups of the cellulose, or A--D together are a benzo-fused reactive group which reacts only substitutively with the hydroxyl groups of the cellulose, are used for dyeing or printing hydroxyl- or nitrogen-containing substrates.
摘要翻译： 具有三个反应性基团并符合式（IMAGE）的反应性染料，其中R1是氢，甲基或乙基，X是氢或羟基磺酰基，Hal是氟或氯，D是亚苯基，羧基 - 羟基磺酰基 - 单取代或二取代的亚苯基或羧基 - 羟基磺酰基单取代或二取代的亚萘基，A是仅与纤维素的羟基取代反应的反应性基团，或AD一起是仅与纤维素的羟基取代的苯并稠合反应性基团，用于染色 或印刷含羟基或含氮底物。
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