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公开(公告)号:US06767646B2
公开(公告)日:2004-07-27
申请号:US10221198
申请日:2002-09-23
申请人: Hermann Seyffer , Titus Leman , Peter Claassen , Kai Olfermann , Thomas Wirth , Jürgen Schmidt-Thümmes
发明人: Hermann Seyffer , Titus Leman , Peter Claassen , Kai Olfermann , Thomas Wirth , Jürgen Schmidt-Thümmes
IPC分类号: B32B2304
CPC分类号: D21H17/39 , B44C5/0469 , D21H17/37 , D21H27/26 , Y10T428/31725 , Y10T428/31775 , Y10T428/3188 , Y10T428/31895 , Y10T428/31899 , Y10T428/31902 , Y10T428/31906 , Y10T428/31971 , Y10T428/31982 , Y10T428/31986 , Y10T428/31989 , Y10T428/31993
摘要: A process for impregnating base paper or fiber webs with an aqueous dispersion of a polymer of free-radically polymerizable compounds (monomers), which comprises from 0.1 to 5% by weight of the monomers being methacrylic acid.
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公开(公告)号:US20100022701A1
公开(公告)日:2010-01-28
申请号:US12519001
申请日:2007-12-11
申请人: Andreas Brockmeyer , Titus Leman , Roland Ettl
发明人: Andreas Brockmeyer , Titus Leman , Roland Ettl
CPC分类号: C08F20/44 , C08F2/10 , C08F2/22 , C08F2/28 , C08F220/18 , C08F220/34 , C08F220/44 , C08F220/60 , C08F257/02 , C08F265/00 , C08F265/04 , C08F265/06 , C08F265/10 , C08L51/003 , C09D133/24 , C09D151/003 , D21H17/37 , D21H17/375 , D21H17/44 , D21H17/45 , D21H21/16 , C08L2666/04 , C08L2666/02
摘要: Finely divided, cationic polymer dispersions which are obtainable by emulsion polymerization of ethylenically unsaturated monomers in an aqueous solution of a cationic prepolymer as a dispersant, wherein a cationic prepolymer is first prepared by polymerization of (a) from 10 to 45% by weight of at least one (meth)acrylate which has an amino group and/or a quaternary ammonium group, and/or one (meth)acrylamide which carries an amino group and/or a quaternary ammonium group, (b) from 40 to 85% by weight of at least one optionally substituted styrene, (c) from 0 to 20% by weight of acrylonitrile or methacrylonitrile, (d) from 1 to 15% by weight of at least one ethylenically unsaturated carboxylic acid or one ethylenically unsaturated carboxylic anhydride and (e) from 0 to 20% by weight of at least one nonionic, ethylenically unsaturated monomer differing from the monomers (b) and (c), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, in a solution polymerization in a water-miscible organic solvent, and the solution of prepolymer thus prepared is diluted with water, and wherein an emulsion polymerization of a monomer mixture comprising (i) from 30 to 80% by weight of acrylonitrile and/or methacrylonitrile, (ii) from 5 to 50% by weight of at least one C1- to C4-alkyl acrylate or at least one C1- to C4-alkyl methacrylate, (iii) from 5 to 50% by weight of at least one C6- to C14-alkyl acrylate or at least one C6- to C14-alkyl methacrylate and (iv) from 0 to 20% by weight of a nonionic monomer differing from the monomers (i), (ii) and (iii), the sum (i)+(ii)+(iii)+(iv) being 100% by weight, is then carried out in the aqueous solution of the prepolymer in the presence of water-soluble polymerization initiators, and the use of the finely divided, cationic polymer dispersions thus obtainable as engine sizes and surface sizes for paper, board and cardboard.
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公开(公告)号:US07081305B2
公开(公告)日:2006-07-25
申请号:US10484720
申请日:2002-07-17
IPC分类号: D21H19/44
CPC分类号: D21H25/14 , D21H19/58 , Y10T428/31895 , Y10T428/31906 , Y10T428/31971
摘要: A paper coating slip containing a mineral pigment and an aqueous polymer dispersion as a binder, wherein the polymer dispersion is obtainable by emulsion polymerization of ethylenically unsaturated compounds (monomers) and the paper coating slip gels at above 35° C., i.e. the viscosity of the paper coating slip at from 35 to 60° C. is at least twice the viscosity at 30° C.
摘要翻译: 包含矿物颜料和作为粘合剂的聚合物水分散体的纸涂层滑爽剂,其中聚合物分散体可通过在35℃以上的烯键式不饱和化合物(单体)和纸涂布滑爽凝胶的乳液聚合获得,即粘度 在35至60℃下的纸涂层滑爽度至少为30℃时的粘度的两倍。
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公开(公告)号:US20100324178A1
公开(公告)日:2010-12-23
申请号:US12518002
申请日:2007-12-11
申请人: Andreas Brockmeyer , Titus Leman , Roland Ettl
发明人: Andreas Brockmeyer , Titus Leman , Roland Ettl
摘要: Finely divided starch-containing polymer dispersions which are obtainable by free radical emulsion copolymerization of ethylenically unsaturated monomers in the presence of a redox initiator and an enzymatically degraded starch, the enzymatic starch degradation being stopped by adding an acid comprising at least one phosphorus atom to the reaction mixture, use of an acid comprising at least one phosphorus atom for stopping the enzymatic degradation of starch and use of the finely divided, starch-containing polymer dispersions of emulsion polymers as size for paper and paper products, in particular as surface size.
摘要翻译: 通过在氧化还原引发剂和酶促降解的淀粉的存在下通过烯键式不饱和单体的自由基乳液共聚获得的细分散的含淀粉聚合物分散体,通过向至少一个磷原子加入包含至少一个磷原子的酸来停止酶淀粉降解 反应混合物,使用包含至少一个磷原子的酸来停止淀粉的酶促降解,并且使用乳状聚合物的细分散的含淀粉聚合物分散体作为纸和纸产品的尺寸,特别是作为表面尺寸。
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