公开(公告)号：US08187510B2

公开(公告)日：2012-05-29

申请号：US12662122

申请日：2010-03-31

申请人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

发明人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

IPC分类号： B29B9/08

CPC分类号： C08K5/1345 ,  B29B9/02 ,  C08K5/005 ,  C08K5/372 ,  Y02P20/582

摘要： A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 20 parts by weight and not more than 50 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature equal to or lower than the melting point of the binder and equal to or higher than the temperature which is 10° C. lower than the melting point, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size of not more than 5 mm, and a cracking mechanism, to obtain a granule.

摘要翻译： 一种颗粒状组合物的制造方法，其特征在于，包括以下步骤：将含有不少于3重量份且不超过80重量份由式（1）表示的酚化合物的混合物进行搅拌和造粒：其中R1是烷基 具有1至8个碳原子的基团，X是任选含有杂原子，环状基团或杂原子和环状基团的具有1至18个碳原子的n价醇残基，n是1至4的整数，并且 不少于20重量份且不超过50重量份的粘合剂，以获得颗粒聚集体; 在等于或低于粘合剂熔点的温度下，通过配备有分离机构的裂解装置将熔融点熔点等于或高于熔点低10℃的温度下破碎， 回收粒径不大于5mm的颗粒和破裂机理，得到颗粒。

公开(公告)号：US20100252943A1

公开(公告)日：2010-10-07

申请号：US12662121

申请日：2010-03-31

申请人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

发明人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

IPC分类号： B29B9/16

CPC分类号： C08K5/1345 ,  B01J2/10 ,  Y02P20/582

摘要： A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 3 parts by weight and less than 20 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature of not lower than 25° C. and lower than the temperature which is 10° C. lower than the melting point of the binder, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size not more than 5 mm, and a cracking mechanism, to obtain a granule.

摘要翻译： 一种颗粒状组合物的制造方法，其特征在于，包括以下步骤：将含有不少于3重量份且不超过80重量份由式（1）表示的酚化合物的混合物进行搅拌和造粒：其中R1是烷基 具有1至8个碳原子的基团，X是任选含有杂原子，环状基团或杂原子和环状基团的具有1至18个碳原子的n价醇残基，n是1至4的整数，并且 不少于3重量份和少于20重量份的粘合剂，以获得颗粒团块; 并且通过装备有能够回收颗粒的分离机构的裂解机，在不低于25℃并低于粘合剂的熔点低于10℃的温度下将颗粒团聚体裂化 具有不大于5mm的粒度和破裂机理，以获得颗粒。

公开(公告)号：US07732518B2

公开(公告)日：2010-06-08

申请号：US12107896

申请日：2008-04-23

申请人： Hideaki Awa ,  Hajime Shinomiya

发明人： Hideaki Awa ,  Hajime Shinomiya

IPC分类号： C08K5/04

CPC分类号： C08K5/1345 ,  C08J3/203 ,  C08J2323/00 ,  C08K5/098 ,  C08K5/372 ,  C08K7/00 ,  C08L23/02 ,  C08L23/00

摘要： A method for producing a polyolefin composition, which comprises melt-kneading a particulate composition (A) containing a compound represented by formula (1): wherein R1 represents an alkyl group having 1 to 8 carbon atoms, X represents an n-hydric alcohol residue having 1 to 18 carbon atoms which may include a heteroatom and/or a cyclic group, and n is the integer 2 or 4, and a metal soap, and a particulate polyolefin (B), wherein the ratio (a/b) of the average particle diameter (a) of the particulate composition (A) and the an average particle diameter (b) of the particulate polyolefin (B) is adjusted to 3/1 to 1/3, and wherein average particle diameter means the central cumulative value determined from a weight-based particle diameter cumulative distribution for residue on a sieve measured in accordance with JIS K 0069.

摘要翻译： 1.一种聚烯烃组合物的制造方法，其特征在于，将含有式（1）表示的化合物的粒状组合物（A）熔融混炼，其中，R1表示碳原子数1〜8的烷基，X表示正 - 具有1至18个碳原子，其可以包括杂原子和/或环状基团，并且n是整数2或4，以及金属皂和颗粒状聚烯烃（B），其中所述比例（a / b） 粒状组合物（A）的平均粒径（a）和粒状聚烯烃（B）的平均粒径（b）调整为3/1〜1/3，其中平均粒径是指中心累积值 由根据JIS K 0069测量的筛上残留物的重量级粒径累积分布确定。

公开(公告)号：US08178017B2

公开(公告)日：2012-05-15

申请号：US12662121

申请日：2010-03-31

申请人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

发明人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

IPC分类号： B29B9/08

CPC分类号： C08K5/1345 ,  B01J2/10 ,  Y02P20/582

摘要： A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 3 parts by weight and less than 20 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature of not lower than 25° C. and lower than the temperature which is 10° C. lower than the melting point of the binder, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size not more than 5 mm, and a cracking mechanism, to obtain a granule.

摘要翻译： 一种颗粒状组合物的制造方法，其特征在于，包括以下步骤：将含有不少于3重量份且不超过80重量份由式（1）表示的酚化合物的混合物进行搅拌和造粒：其中R1是烷基 具有1至8个碳原子的基团，X是任选含有杂原子，环状基团或杂原子和环状基团的具有1至18个碳原子的n价醇残基，n是1至4的整数，并且 不少于3重量份和少于20重量份的粘合剂，以获得颗粒团块; 并且通过装备有能够回收颗粒的分离机构的裂解机，在不低于25℃并低于粘合剂的熔点低于10℃的温度下将颗粒团聚体裂化 具有不大于5mm的粒度和破裂机理，以获得颗粒。

公开(公告)号：US20100256267A1

公开(公告)日：2010-10-07

申请号：US12662122

申请日：2010-03-31

申请人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

发明人： Hideaki Awa ,  Masato Arai ,  Hajime Shinomiya

IPC分类号： C08K5/1545

CPC分类号： C08K5/1345 ,  B29B9/02 ,  C08K5/005 ,  C08K5/372 ,  Y02P20/582

摘要： A method for producing a granular composition including the steps of: stirring and granulating a mixture containing not less than 3 parts by weight and not more than 80 parts by weight of a phenol compound represented by the formula (1): wherein R1 is an alkyl group having 1 to 8 carbon atoms, X is an n-valent alcohol residue having 1 to 18 carbon atoms optionally containing a heteroatom, a cyclic group, or a heteroatom and a cyclic group, and n is an integer of 1 to 4, and not less than 20 parts by weight and not more than 50 parts by weight of a binder to obtain a granular agglomerate; and cracking the granular agglomerate at a temperature equal to or lower than the melting point of the binder and equal to or higher than the temperature which is 10° C. lower than the melting point, through a cracking machine equipped with a separation mechanism capable of recovering a granule having a particle size of not more than 5 mm, and a cracking mechanism, to obtain a granule.

摘要翻译： 一种制备颗粒组合物的方法，包括以下步骤：将由不低于3重量份至不超过80重量份的式（1）表示的酚化合物的混合物进行搅拌和造粒：其中R1是烷基 具有1至8个碳原子的基团，X是任选含有杂原子，环状基团或杂原子和环状基团的具有1至18个碳原子的n价醇残基，n是1至4的整数，并且 不少于20重量份且不超过50重量份的粘合剂，以获得颗粒聚集体; 在等于或低于粘合剂熔点的温度下将粒状附聚物裂化成等于或高于低于熔点10℃的温度，通过装备有能够 回收粒径不大于5mm的颗粒和破裂机理，得到颗粒。

公开(公告)号：US20130035426A1

公开(公告)日：2013-02-07

申请号：US13640763

申请日：2011-04-14

申请人： Yoshikazu Kimura ,  Hideaki Awa

发明人： Yoshikazu Kimura ,  Hideaki Awa

IPC分类号： C08K5/1545 ,  C09K3/00

CPC分类号： C08K5/1345 ,  C08K5/134 ,  C08K5/1545 ,  C08K5/51 ,  C08K5/526

摘要： The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphorous compound, trehalose and a thermoplastic polymer, as well as a stabilizer composition containing a particular phenol compound or organic phosphorous compound and trehalose. A combined use of a particular phenol compound or organic phosphorous compound and trehalose can improve processing stability of a thermoplastic polymer composition.

摘要翻译： 本发明提供含有特定的酚化合物或有机磷化合物，海藻糖和热塑性聚合物的热塑性聚合物组合物，以及含有特定的酚化合物或有机磷化合物和海藻糖的稳定剂组合物。 特定酚化合物或有机磷化合物和海藻糖的组合使用可以提高热塑性聚合物组合物的加工稳定性。

公开(公告)号：US20130032756A1

公开(公告)日：2013-02-07

申请号：US13641292

申请日：2011-04-14

申请人： Yoshikazu Kimura ,  Hideaki Awa

发明人： Yoshikazu Kimura ,  Hideaki Awa

IPC分类号： C08K5/1545 ,  C09K3/00

CPC分类号： C08K5/134 ,  C08K5/1545 ,  C08K5/51 ,  C08K5/526

摘要： The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphoric compound, compound (9) which is compound (9a) represented by CmH2mOm wherein m is an integer of not less than 3 and not more than 10, and having one aldehyde group or ketone group and m−1 hydroxy groups with at least one hydroxy group having been replaced by an alkoxy group represented by —OR26 wherein R26 is a C1-12 alkyl group, and a thermoplastic polymer, and a processing stabilizer containing a particular phenol compound or organic phosphoric compound, and compound (9). A combined use of a particular phenol compound or organic phosphoric compound and compound (9) can improve processing stability of a thermoplastic polymer composition.

摘要翻译： 本发明提供一种含有特定酚化合物或有机磷化合物的热塑性聚合物组合物，化合物（9），其为由CmH2mOm表示的化合物（9a），其中m为不小于3并且不大于10的整数，并且具有一个 醛基或酮基和具有至少一个羟基的m-1羟基被由-OR 26表示的烷氧基代替，其中R26是C1-12烷基，和热塑性聚合物，以及含有特定的 酚化合物或有机磷化合物和化合物（9）。 特定的酚化合物或有机磷化合物和化合物（9）的组合使用可以改善热塑性聚合物组合物的加工稳定性。

公开(公告)号：US08097748B2

公开(公告)日：2012-01-17

申请号：US12753552

申请日：2010-04-02

申请人： Kenji Kimura ,  Kazuhiro Kitamura ,  Hideaki Awa

发明人： Kenji Kimura ,  Kazuhiro Kitamura ,  Hideaki Awa

IPC分类号： C07F9/145

CPC分类号： C07F9/65744

摘要： An amorphous compound of the formula (1): wherein the temperature showing an endothermic peak by differential scanning calorimetry (DSC) is 40 to 80° C. and the solution rate into n-hexane at 25° C. in the following test system is 1.5 mg/sec or more. At 25° C., 1 g of a specimen is charged into a vessel containing 50 g of n-hexane (capacity: 100 ml, outer diameter: 55 mm, height: 70 mm), a 38 mm diameter fan type stirring blade is rotated at a revolution of 100 rpm, and the time until dissolution of the specimen is measured.

摘要翻译： 式（1）的无定形化合物：其中通过差示扫描量热法（DSC）显示吸热峰的温度为40至80℃，在以下测试系统中在25℃下在正己烷中的溶解速率为 1.5mg / sec以上。 <溶解速度的试验体系>在25℃下，将1g试样装入含有50g正己烷（容量：100ml，外径：55mm，高度：70mm），38 mm直径的风扇式搅拌叶片以100rpm的转速旋转，并且测量直到试样溶解的时间。

公开(公告)号：US20130035427A1

公开(公告)日：2013-02-07

申请号：US13641413

申请日：2011-04-14

申请人： Yoshikazu Kimura ,  Hideaki Awa

发明人： Yoshikazu Kimura ,  Hideaki Awa

IPC分类号： C08L101/00 ,  C08K5/527 ,  C08K5/524 ,  C08K5/101 ,  C08K5/05

CPC分类号： C08K5/51 ,  C08K5/134 ,  C08K5/1545 ,  C08K5/526

摘要： The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphorous compound, glucose and a thermoplastic polymer, as well as a processing stabilizer containing a particular phenol compound or organic phosphorous compound and glucose. A combined use of a particular phenol compound or organic phosphorous compound and glucose can improve processing stability of a thermoplastic polymer composition.

摘要翻译： 本发明提供含有特定的酚化合物或有机磷化合物，葡萄糖和热塑性聚合物的热塑性聚合物组合物，以及含有特定的酚化合物或有机磷化合物和葡萄糖的加工稳定剂。 特定酚化合物或有机磷化合物和葡萄糖的组合使用可以改善热塑性聚合物组合物的加工稳定性。

公开(公告)号：US20130041086A1

公开(公告)日：2013-02-14

申请号：US13641231

申请日：2011-04-14

申请人： Yoshikazu Kimura ,  Hideaki Awa

发明人： Yoshikazu Kimura ,  Hideaki Awa

IPC分类号： C08K5/101 ,  C09K15/08 ,  C09K15/32 ,  C07C69/54

CPC分类号： C08K5/134 ,  C08K5/053 ,  C08K5/151 ,  C08K5/51 ,  C08K5/526

摘要： The present invention provides a thermoplastic polymer composition containing a particular phenol compound or organic phosphorous compound, a compound represented by the formula (9) and a thermoplastic polymer, as well as a processing stabilizer containing a particular phenol compound or organic phosphorous compound and a compound represented by the formula (9). A combined use of a particular phenol compound or organic phosphorous compound and a compound represented by the formula (9) can improve processing stability of a thermoplastic polymer composition. wherein in the formula (9), m is an integer of 2 or more.

摘要翻译： 本发明提供含有特定的酚化合物或有机磷化合物，式（9）表示的化合物和热塑性聚合物的热塑性聚合物组合物，以及含有特定的酚化合物或有机磷化合物的化合物和化合物 由式（9）表示。 特定酚化合物或有机磷化合物和由式（9）表示的化合物的组合使用可以改善热塑性聚合物组合物的加工稳定性。 式（9）中，m为2以上的整数。