公开(公告)号：US10720664B2

公开(公告)日：2020-07-21

申请号：US14008285

申请日：2012-03-29

申请人： Hideo Sakata ,  Meiten Koh ,  Akiyoshi Yamauchi ,  Hitomi Nakazawa ,  Tomoyo Sanagi ,  Aoi Nakazono ,  Yuki Adachi ,  Kyouhei Sawaki ,  Akinori Tani ,  Masahiro Tomita ,  Michiru Kagawa

发明人： Hideo Sakata ,  Meiten Koh ,  Akiyoshi Yamauchi ,  Hitomi Nakazawa ,  Tomoyo Sanagi ,  Aoi Nakazono ,  Yuki Adachi ,  Kyouhei Sawaki ,  Akinori Tani ,  Masahiro Tomita ,  Michiru Kagawa

IPC分类号： H01M10/0564 ,  H01M10/0569 ,  H01M10/052 ,  H01M10/0567

摘要： The present invention provides a lithium ion secondary cell excellent in high-temperature storage characteristics and high voltage cycle characteristics; and a nonaqueous electrolyte for the cell.The present invention relates to a lithium ion secondary cell, comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte containing nonaqueous solvents and an electrolyte salt, the nonaqueous solvents comprising a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2  (1) wherein Rf1 and Rf2 are the same as or different from each other, each being a C1-10 alkyl group or a C1-10 fluoroalkyl group; and at least one of Rf1 and Rf2 is a fluoroalkyl group, and the following compounds (I) and (II): (I) a fluorine-containing unsaturated compound; and (II) a hydroxy group-containing compound represented by the formula (2): Rf1OH  (2) wherein Rf1 is the same as above, and the nonaqueous solvents comprising the compounds (I) and (II) in a total amount of 5000 ppm or less for the fluorine-containing ether.

公开(公告)号：US20140017560A1

公开(公告)日：2014-01-16

申请号：US14008285

申请日：2012-03-29

申请人： Hideo Sakata ,  Meiten Koh ,  Akiyoshi Yamauchi ,  Hitomi Nakazawa ,  Tomoyo Sanagi ,  Aoi Nakazono ,  Yuki Adachi ,  Kyouhei Sawaki ,  Akinori Tani ,  Masahiro Tomita ,  Michiru Kagawa

发明人： Hideo Sakata ,  Meiten Koh ,  Akiyoshi Yamauchi ,  Hitomi Nakazawa ,  Tomoyo Sanagi ,  Aoi Nakazono ,  Yuki Adachi ,  Kyouhei Sawaki ,  Akinori Tani ,  Masahiro Tomita ,  Michiru Kagawa

IPC分类号： H01M10/0564

CPC分类号： H01M10/0564 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0028

摘要： The present invention provides a lithium ion secondary cell excellent in high-temperature storage characteristics and high voltage cycle characteristics; and a nonaqueous electrolyte for the cell.The present invention relates to a lithium ion secondary cell, comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte containing nonaqueous solvents and an electrolyte salt, the nonaqueous solvents comprising a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2  (1) wherein Rf1 and Rf2 are the same as or different from each other, each being a C1-10 alkyl group or a C1-10 fluoroalkyl group; and at least one of Rf1 and Rf2 is a fluoroalkyl group, and the following compounds (I) and (II): (I) a fluorine-containing unsaturated compound; and (II) a hydroxy group-containing compound represented by the formula (2): Rf1OH  (2) wherein Rf1 is the same as above, and the nonaqueous solvents comprising the compounds (I) and (II) in a total amount of 5000 ppm or less for the fluorine-containing ether.

摘要翻译： 本发明提供高温保存特性和高电压循环特性优异的锂离子二次电池， 和用于电池的非水电解质。 锂离子二次电池本发明涉及一种锂离子二次电池，其包含正极，负极和含有非水溶剂和电解质盐的非水电解质，所述非水溶剂包含由式（1）表示的含氟醚：Rf1 -O-Rf2（1）其中Rf1和Rf2彼此相同或不同，各自为C1-10烷基或C1-10氟代烷基; Rf1和Rf2中的至少一个为氟代烷基，以下化合物（I）和（II）：（I）含氟不饱和化合物; 和（II）式（2）表示的含羟基的化合物：Rf1OH（2）其中Rf1与上述相同，并且包含化合物（I）和（II）的非水溶剂的总量为5000 ppm以下的含氟醚。

公开(公告)号：US08415056B2

公开(公告)日：2013-04-09

申请号：US13003286

申请日：2009-07-06

申请人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

发明人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

IPC分类号： H01M6/16 ,  H01G9/02

CPC分类号： H01M10/0569 ,  H01M10/052 ,  H01M10/0568 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/004 ,  Y02T10/7011

摘要： There is provided a non-aqueous electrolytic solution assuring good solubility of an electrolyte salt and having enough cell characteristics (charge and discharge cycle characteristic, discharge capacity, and the like), and the non-aqueous electrolytic solution comprises a solvent for dissolving an electrolyte salt comprising (A) at least one fluorine-containing solvent selected from the group consisting of fluorine-containing ethers and fluorine-containing carbonates, (B) a non-fluorine-containing cyclic carbonate and (C) a chain ester represented by the formula (C): R1COOR2, wherein R1 is an alkyl group having 2 to 4 carbon atoms; R2 is an alkyl group having 1 to 4 carbon atoms or a fluorine-containing alkyl group having 1 to 4 carbon atoms, and (II) an electrolyte salt.

摘要翻译： 提供了一种确保电解质盐的良好溶解性并具有足够的电池特性（充放电循环特性，放电容量等）的非水电解液，非水电解液包含溶解电解质的溶剂 盐，其包含（A）至少一种选自含氟醚和含氟碳酸酯的含氟溶剂，（B）非含氟环状碳酸酯和（C）由式 （C）：R1COOR2，其中R1是具有2至4个碳原子的烷基; R2是碳原子数1〜4的烷基或碳原子数1〜4的含氟烷基，（II）电解质盐。

公开(公告)号：US20110123872A1

公开(公告)日：2011-05-26

申请号：US13003286

申请日：2009-07-06

申请人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

发明人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

IPC分类号： H01M10/0564

CPC分类号： H01M10/0569 ,  H01M10/052 ,  H01M10/0568 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/004 ,  Y02T10/7011

摘要： There is provided a non-aqueous electrolytic solution assuring good solubility of an electrolyte salt and having enough cell characteristics (charge and discharge cycle characteristic, discharge capacity, and the like), and the non-aqueous electrolytic solution comprises a solvent for dissolving an electrolyte salt comprising (A) at least one fluorine-containing solvent selected from the group consisting of fluorine-containing ethers and fluorine-containing carbonates, (B) a non-fluorine-containing cyclic carbonate and (C) a chain ester represented by the formula (C): R1COOR2, wherein R1 is an alkyl group having 2 to 4 carbon atoms; R2 is an alkyl group having 1 to 4 carbon atoms or a fluorine-containing alkyl group having 1 to 4 carbon atoms, and (II) an electrolyte salt.

摘要翻译： 提供了一种确保电解质盐的良好溶解性并具有足够的电池特性（充放电循环特性，放电容量等）的非水电解液，非水电解液包含溶解电解质的溶剂 盐，其包含（A）至少一种选自含氟醚和含氟碳酸酯的含氟溶剂，（B）非含氟环状碳酸酯和（C）由式 （C）：R1COOR2，其中R1是具有2至4个碳原子的烷基; R2是碳原子数1〜4的烷基或碳原子数1〜4的含氟烷基，（II）电解质盐。

公开(公告)号：US08372547B2

公开(公告)日：2013-02-12

申请号：US13003286

申请日：2009-07-06

申请人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

发明人： Meiten Koh ,  Hitomi Nakazawa ,  Hideo Sakata ,  Michiru Kagawa ,  Akiyoshi Yamauchi

IPC分类号： H01M6/16 ,  H01G9/02

摘要： There is provided a non-aqueous electrolytic solution assuring good solubility of an electrolyte salt and having enough cell characteristics (charge and discharge cycle characteristic, discharge capacity, and the like), and the non-aqueous electrolytic solution comprises a solvent for dissolving an electrolyte salt comprising (A) at least one fluorine-containing solvent selected from the group consisting of fluorine-containing ethers and fluorine-containing carbonates, (B) a non-fluorine-containing cyclic carbonate and (C) a chain ester represented by the formula (C): R1COOR2, wherein R1 is an alkyl group having 2 to 4 carbon atoms; R2 is an alkyl group having 1 to 4 carbon atoms or a fluorine-containing alkyl group having 1 to 4 carbon atoms, and (II) an electrolyte salt.

公开(公告)号：US08835696B2

公开(公告)日：2014-09-16

申请号：US12999843

申请日：2009-06-11

申请人： Michiru Kagawa ,  Aoi Nakazono ,  Akiyoshi Yamauchi ,  Meiten Koh

发明人： Michiru Kagawa ,  Aoi Nakazono ,  Akiyoshi Yamauchi ,  Meiten Koh

IPC分类号： C07C41/42 ,  C07C41/06 ,  C07B41/04

CPC分类号： C07B41/04 ,  C07C41/06 ,  Y02P20/582 ,  C07C43/123

摘要： There is provided a method of preparing a high purity fluorine-containing ether which inhibits a side reaction generating an unsaturated bond and assures low cost and simple steps. When preparing the fluorine-containing ether by allowing a fluorine-containing alkyl alcohol to react with a fluorinated olefin in the presence of a basic compound, a reaction is terminated at a stage before a conversion ratio of the fluorine-containing alkyl alcohol reaches 75%.

摘要翻译： 提供一种制备高纯度含氟醚的方法，其抑制副反应产生不饱和键，并确保低成本和简单的步骤。 当在碱性化合物的存在下使含氟烷基醇与氟化烯烃反应制备含氟醚时，在含氟烷基醇的转化率达到75％之前的阶段终止反应， 。

公开(公告)号：US20110098511A1

公开(公告)日：2011-04-28

申请号：US12999843

申请日：2009-06-11

申请人： Michiru Kagawa ,  Aoi Nakazono ,  Akiyoshi Yamauchi ,  Meiten Koh

发明人： Michiru Kagawa ,  Aoi Nakazono ,  Akiyoshi Yamauchi ,  Meiten Koh

IPC分类号： C07C41/06 ,  C07C41/34 ,  C07C41/42

CPC分类号： C07B41/04 ,  C07C41/06 ,  Y02P20/582 ,  C07C43/123

摘要： There is provided a method of preparing a high purity fluorine-containing ether which inhibits a side reaction generating an unsaturated bond and assures low cost and simple steps. When preparing the fluorine-containing ether by allowing a fluorine-containing alkyl alcohol to react with a fluorinated olefin in the presence of a basic compound, a reaction is terminated at a stage before a conversion ratio of the fluorine-containing alkyl alcohol reaches 75%.

摘要翻译： 提供一种制备高纯度含氟醚的方法，其抑制副反应产生不饱和键，并确保低成本和简单的步骤。 当在碱性化合物的存在下使含氟烷基醇与氟化烯烃反应制备含氟醚时，在含氟烷基醇的转化率达到75％之前的阶段终止反应， 。

公开(公告)号：US20120083629A1

公开(公告)日：2012-04-05

申请号：US13377999

申请日：2010-06-15

申请人： Michiru Kagawa ,  Aoi Nakazono ,  Yasuhide Senba ,  Hitoshi Motoyama ,  Toru Yoshizawa ,  Meiten Koh

发明人： Michiru Kagawa ,  Aoi Nakazono ,  Yasuhide Senba ,  Hitoshi Motoyama ,  Toru Yoshizawa ,  Meiten Koh

IPC分类号： C07C41/38 ,  C07C41/42

CPC分类号： C07C41/38 ,  Y02P20/582 ,  C07C43/123

摘要： The present invention provides a method for efficiently producing a highly pure fluoroether containing remarkably low concentration of a fluorine-containing alkyl alcohol. The method is suited for scale-up and specifically includes performing countercurrent separation of a crude solution of fluoroether including a fluorine-containing alkyl alcohol as an impurity using water.

摘要翻译： 本发明提供了一种有效地制备含有极低浓度的含氟烷基醇的高纯度氟醚的方法。 该方法适用于放大，具体包括使用水对包含含氟烷基醇作为杂质的氟代醚的粗溶液进行逆流分离。

公开(公告)号：US20110118485A1

公开(公告)日：2011-05-19

申请号：US13002002

申请日：2009-05-26

申请人： Meiten Koh ,  Michiru Kagawa ,  Akiyoshi Yamauchi

发明人： Meiten Koh ,  Michiru Kagawa ,  Akiyoshi Yamauchi

IPC分类号： C07D317/36

CPC分类号： C07D317/38 ,  C07D317/36

摘要： There is provided a process for preparing a fluoropropylene carbonate safely at high yield by one step (one pot), and the process is characterized by allowing a fluorinating agent to act on a propylene carbonate derivative having a group to be released in a fluorination reaction.

摘要翻译： 提供了通过一步（一锅）以高收率安全地制备碳酸氟丙烯酯的方法，该方法的特征在于使氟化剂作用于具有在氟化反应中被释放的基团的碳酸亚丙酯衍生物。

公开(公告)号：US08519161B2

公开(公告)日：2013-08-27

申请号：US13002002

申请日：2009-05-26

申请人： Meiten Koh ,  Michiru Kagawa ,  Akiyoshi Yamauchi

发明人： Meiten Koh ,  Michiru Kagawa ,  Akiyoshi Yamauchi

IPC分类号： C07D317/36

CPC分类号： C07D317/38 ,  C07D317/36

摘要： There is provided a process for preparing a fluoropropylene carbonate safely at high yield by one step (one pot), and the process is characterized by allowing a fluorinating agent to act on a propylene carbonate derivative having a group to be released in a fluorination reaction.

摘要翻译： 提供了通过一步（一锅）以高收率安全地制备碳酸氟丙烯酯的方法，该方法的特征在于使氟化剂作用于具有在氟化反应中被释放的基团的碳酸亚丙酯衍生物。