Lithium-ion electrochemical cells including fluorocarbon electrolyte additives
    7.
    发明授权
    Lithium-ion electrochemical cells including fluorocarbon electrolyte additives 有权
    锂离子电化学电池包括氟碳电解质添加剂

    公开(公告)号:US09455472B2

    公开(公告)日:2016-09-27

    申请号:US14122596

    申请日:2012-05-30

    摘要: Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.

    摘要翻译: 提供了包括包含锂金属氧化物或锂金属磷酸盐的正极,能够与锂嵌入或合金化的负极以及包含添加剂的电解质的锂离子电化学电池。 添加剂包括具有下式的多官能阴离子:X-SO 2 -R f -SO 2 -Y,其中X和Y独立地是O-或RfSO 2 N-,Rf是具有1-6个碳原子的直链或支链氟烷基部分 原子,并且可以任选地含有一个或多个在链的杂原子,其中R f是具有1至10个碳原子的直链或支链或环状氟代亚烷基,并且可以任选地含有一个或多个链内杂原子,并且其中 Rf和Rf均具有最多20%的非氟取代基。 所提供的添加剂可以提高所提供的电化学电池的性能,水解稳定性和热稳定性。