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1.发明授权Method for processing silver halide color photographic light-sensitive materials and the bleach-fixer applicable thereto 失效卤化银彩色摄影感光材料的处理方法和适用于其的漂白定影剂
公开(公告)号：US5180656A
公开(公告)日：1993-01-19
申请号：US775244
申请日：1990-10-31
IPC分类号： G03C7/42
CPC分类号： G03C7/42 , Y10S430/164
摘要： A method of processing a silver halide color photographic light-sensitive material and a bleach-fixer applicable in the method are disclosed. The method comprises a step for developing the light-sensitive material with a color developer, and a step for bleach-fixing the developed light-sensitive material with a bleach-fixer. The light-sensitive material contains at least one silver halide emulsion layer comprising silver halide grains having a silver chloride content of not less than 80 mol %; the bleach-fixer contains a ferric organic acid complex in an amount of not less than 0.2 mol per liter and silver halide fixing agent in an amount of not less than 0.7 mol per liter; and the step for treating with the bleach-fixer is performed for a time of not more than 30 seconds. Bleach-fixing process can be performed stably and rapidly without formation of reticulation and staining on edge portion of the light-sensitive.
摘要翻译： 公开了一种处理适用于该方法的卤化银彩色照相感光材料和漂白定影剂的方法。 该方法包括用彩色显影剂显影感光材料的步骤，和用漂白剂定影剂漂白固定显影的感光材料的步骤。 感光材料含有至少一种卤化银乳剂层，其包含氯化银含量不小于80mol％的卤化银颗粒; 漂白剂固定剂含有不低于0.2mol /升的铁有机酸络合物和不低于0.7mol /升的卤化银固定剂; 并且用漂白剂定影剂处理的步骤进行不超过30秒的时间。 漂白定影过程可以稳定和快速地进行，而不会在光敏感的边缘部分上形成网状和染色。
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2.发明授权Method capable of rapidly processing a silver halide color photographic light-sensitive material 失效能够快速处理卤化银彩色照相感光材料的方法
公开(公告)号：US5354646A
公开(公告)日：1994-10-11
申请号：US206283
申请日：1994-03-07
CPC分类号： G03C7/413 , Y10S430/164
摘要： A method of colour-developing a silver halide colour light-sensitive material having plural silver halide emulsion layers each containing substantially silver chlorobromide. At least one of the layers has a silver chloride content of not less than 20 mol %, and a colour developer being used in the colour developing method contains the compounds each represented by the following formula [I]: ##STR1## According to the processing method, a colour photographic image having a satisfactory colour density can be obtained by a rapid development process and the excellent preservability for a long standing of the colour developer can be displayed.
摘要翻译： 一种彩色显影具有多个卤化银乳剂层的卤化银彩色感光材料的方法，每个卤化银乳剂层基本上含有氯溴化银。 所述层中的至少一层的氯化银含量为20摩尔％以上，在显色方法中使用的显色剂含有下述式[I]表示的化合物：式[I] 根据该处理方法，可以通过快速显影处理获得具有令人满意的色浓度的彩色摄影图像，并且可以显示彩色显影剂的长时间的优异的保存性。
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3.发明授权
公开(公告)号：US5206119A
公开(公告)日：1993-04-27
申请号：US908775
申请日：1992-07-01
CPC分类号： G03C7/3924 , G03C7/3046 , Y10S430/164
摘要： Disclosed is a method of processing a light-sensitive silver halide color photographic material subjected to imagewise exposure, substantially through a color developing step, a bleach-fixing step and a stabilizing step in this order, wherein at least one layer of the light-sensitive silver halide color photographic material comprises a silver halide containing not less than 80 mol % of silver chloride, the washing-substitutive stabilizing step is carried out in a processing time of not more than 45 seconds, and a washing-substitutive stabilizing solution used in the washing-substitutive stabilizing step has a salt concentration of at least 1,000 ppm. Disclosed are also a washing-substitutive stabilizing solution and a kit of a stabilizer used for the method of this invention. According to this invention, processing of a light-sensitive material that have better prevented the bluing at exposed areas of color photographic papers and also have suppressed the generation of mildew or bacteria on a processed light-sensitive material, moreover that have been improved in paper jam and the like due to incompleteness of drying and also can conduct rapid processing is enabled.
摘要翻译： 公开了基本上通过彩色显影步骤，漂白定影步骤和稳定步骤依次处理经受成像曝光的感光卤化银彩色照相材料的方法，其中至少一层光敏 卤化银彩色照相材料包含含有不小于80mol％氯化银的卤化银，洗涤代用稳定步骤在不超过45秒的处理时间内进行，洗涤代用稳定溶液用于 洗涤代用稳定步骤的盐浓度至少为1000ppm。 本发明还公开了洗涤代用稳定溶液和用于本发明方法的稳定剂试剂盒。 根据本发明，对感光材料进行处理，其更好地防止了彩色相纸的曝光区域的蓝色，并且还抑制了加工感光材料上的霉菌或细菌的产生，而且已经改进了纸张 由于干燥不完整等原因，也可以进行快速加工。
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4.发明授权
公开(公告)号：US4778743A
公开(公告)日：1988-10-18
申请号：US43041
申请日：1987-04-27
CPC分类号： G03C7/3046 , G03C7/3225
摘要： Disclosed is a method for processing a light-sensitive silver halide color photographic material, which comprises including at least the step of color developing, the step of processing with a liquor having fixing ability and the step of processing with a washing solution substitute as the final processing step, after imagewise exposure of a light-sensitive silver halide color photographic material containing at least one silver halide emulsion layer on a support, characterized in that at least one layer of the silver halide emulsion layer contains at least one coupler selected from the magenta couplers and the cyan couplers; washing solution substitute contains at least one compound selected from the group consisting of from 2.0.times.10.sup.-5 to 2.5.times.10.sup.-2 mol per liter of the washing solution substitute of the aldehydes, from 2.0.times.10.sup.-5 to 8.0.times.10.sup.-2 mol per liter of the washing solution substitute of the aldehyde derivatives and from 2.0.times.10.sup.-5 to 8.0.times.10.sup.-2 mol per liter of the washing solution substitute of the aldehyde derivatives; and the replenished amount of the washing solution substitute is at least 2 to 50-fold of the amount of processing solution in the processing steps prior to the step of processing with the washing solution substitute, which is carried over into the washing solution substitute by the light-sensitive photographic material processed in the step processed with the liquor having fixing ability.
摘要翻译： 公开了一种用于处理感光卤化银彩色照相材料的方法，其包括至少包括彩色显影步骤，用具有定影能力的液体处理步骤和用洗涤液处理的步骤替代为最终 在载体上含有至少一个卤化银乳剂层的感光卤化银彩色照相材料成像曝光之后，其特征在于至少一层卤化银乳剂层含有至少一种选自品红色的偶联剂 耦合器和青色耦合器; 洗涤溶液替代物含有至少一种选自2.0×10-5至2.5×10-2摩尔/升的取代醛的洗涤液中的化合物，2.0升至5×10-2摩尔/升 取代醛衍生物的洗涤液和2.0×10-5至8.0×10-2摩尔/升洗涤液代替醛衍生物; 洗涤液替代物的补充量为洗涤液替代物处理步骤之前的加工工序中处理液的量的至少2〜50倍。 在用具有固定能力的液体处理的步骤中处理的感光照相材料。
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5.发明授权
公开(公告)号：US4983503A
公开(公告)日：1991-01-08
申请号：US488473
申请日：1990-02-26
CPC分类号： G03C7/42 , G03C7/3225
摘要： There are disclosed a method for processing a light-sensitive silver halide color photographic material by subjecting a light-sensitive silver halide color photographic material after color developing to bleach-fixing processing, characterized in that the light-sensitive silver halide color photographic material contains at least one cyan coupler represented by the formula (A), (B) or (C) as specified in the specification, or contains at least one magenta coupler represented by the formula (M-1), the bleach-fixing processing step is a step which is a counter-current system uses two or more tanks of continuous bleach-fixing tanks, and the silver concentration in the bleach-fixing solution in a final tank of the bleach-fixing tanks is maintained at 80% or lower of the silver concentration in a bleach-fixing solution in a first tank, and a method for processing a light-sensitive silver halide color photographic material by subjecting a light-sensitive silver halide color photographic material after color developing to bleach-fixing processing and then to stabilizing processing substituted for water washing, characterized in that the light-sensitive silver halide color photographic material has at least one light-sensitive emulsion layer containing a silver halide emulsion containing 0.5 mole % or more of silver iodide, the bleach-fixing processing step is a step which is a counter-current system by use of an organic acid metal complex as the oxidizing agent and uses two or more tanks of continuous bleach-fixing tanks, and the silver concentration in a final tank of the bleach-fixing tanks is maintained at 80% or lower of the silver concentration in the bleach-fixing solution in a first tank.
摘要翻译： 公开了一种通过在彩色显影之后对感光卤化银彩色照相材料进行漂白定影处理来处理感光卤化银彩色照相材料的方法，其特征在于，感光卤化银彩色照相材料含有 至少一种由说明书中规定的式（A），（B）或（C）表示的青色成色剂，或含有至少一种由式（M-1）表示的品红成色剂，漂白剂固定处理步骤为 使用两个或更多个连续漂白固定槽的逆流系统的步骤，并且漂白定影罐的最终罐中漂白剂固定液中的银浓度保持在银浓度的80％以下 在第一罐中的漂白固定溶液中，以及通过使感光卤化银彩色照相纸经受感光卤化银彩色照相材料的处理方法 在漂白定影处理彩色显影之后，然后进行代替水洗的稳定处理，其特征在于感光卤化银彩色照相材料具有至少一个含有0.5摩尔％或更少的卤化银乳剂的感光乳剂层， 更多的碘化银，漂白定影处理步骤是通过使用有机酸金属络合物作为氧化剂的逆流系统并使用两个或更多个连续漂白固定槽， 漂白剂固定槽的最终罐保持在第一罐中漂白剂固定液中银浓度的80％以下。
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6.发明授权Method for color-developing a silver halide photographic light-sensitive material with a color developer containing an n-hydroxyalkyl-p-phenylenediamine derivative 失效用含有正羟基烷基 - 对苯二胺衍生物的彩色显影剂对卤化银照相感光材料进行彩色显影的方法
公开(公告)号：US4738917A
公开(公告)日：1988-04-19
申请号：US863604
申请日：1986-05-15
CPC分类号： G03C7/4136
摘要： A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.
摘要翻译： 一种通过加工卤化银彩色照相感光材料来处理卤化银照相材料的方法，所述卤化银彩色照相感光材料至少含有卤化银乳剂层，该卤化银乳剂层包含基本上由氯溴化银组成的卤化银颗粒和溶胀率为T 1/2的粘合剂 2秒 至30秒 彩色显影剂在不低于30℃的温度下持续不超过150秒的n-羟基烷基 - 对苯二胺衍生物。 时间和温度对卤化银彩色照相感光材料的处理是有效的，而不降低所得染料图像的稳定性。
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公开(公告)号：US4587195A
公开(公告)日：1986-05-06
申请号：US721781
申请日：1985-04-10
CPC分类号： G03C7/413
摘要： A method of processing a silver halide photographic material using a color developer containing at least two kinds of triazylstilbene brightening agents having maximum fluorescent wavelengths at least 4.mu. apart, said material containing a sensitizing dye and an antiirradiation dye.
摘要翻译： 使用含有至少两种具有至少4微米的最大荧光波长的至少两种三氮杂芴增亮剂的显色剂处理卤化银照相材料的方法，所述材料含有敏化染料和抗辐射染料。
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8.发明授权
公开(公告)号：US5352568A
公开(公告)日：1994-10-04
申请号：US104828
申请日：1993-08-11
CPC分类号： G03C7/421 , G03C7/3022 , Y10S430/164
摘要： A processing method for silver halide color photographic material and a bleaching solution used in the processing are disclosed. Sufficient desilvering in a short time and prevention of bleaching fogging can be obtained by the process. The process is applicable for silver-rich high-sensitivity color light-sensitive material. The bleaching solution comprises a of a ferric complex salts of compounds represented by the following Formula A or B in an amount of at least 0.01 mol per liter of the bleaching solution and a buffer agent capable of adjusting pH value to 3 to 7; and pH value of the bleaching solution is held within the range of from 3 to 7; ##STR1## wherein A.sub.1 through A.sub.4 are each --CH.sub.2 OH, --COOM, or --PO.sub.3 M.sub.1 M.sub.2 ; M, M.sub.1 and M.sub.3 are each a hydrogen atom, a sodium atom, a potassium atom or an ammonium group; X is a substituted or unsubstituted alkylene group having three to six carbon atoms; B.sub.1 and B.sub.2 are a substituted or unsubstituted alkylene group having two to five carbon atoms; n is an integer of 1 to 8.
摘要翻译： 公开了一种用于卤化银彩色照相材料的处理方法和用于该处理的漂白溶液。 通过该过程可以获得足够的短时间脱壳和防止漂白起雾。 该方法适用于富含银色的高灵敏度彩色感光材料。 该漂白溶液包含一种由下式A或B表示的化合物的铁配合盐，其量为每升漂白溶液至少0.01mol，能够将pH值调节至3至7的缓冲剂; 漂白液的pH值保持在3〜7的范围内; 式A其中A1至A4各自为-CH 2 OH，-COOM或-PO 3 M 1 M 2; M，M1和M3各自为氢原子，钠原子，钾原子或铵基团; X是取代或未取代的具有3-6个碳原子的亚烷基; B1和B2是具有2-5个碳原子的取代或未取代的亚烷基; n为1〜8的整数。
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9.发明授权
公开(公告)号：US4914008A
公开(公告)日：1990-04-03
申请号：US283006
申请日：1988-12-08
IPC分类号： G03C7/42
CPC分类号： G03C7/42
摘要： There is disclosed a processing method of a light-sensitive silver halide color photographic material comprising, in a method of processing a light-sensitive silver halide color photographic material with a bleach-fixing solution after color developing, and successively with a stabilizing solution substituted for water washing, said bleach-fixing solution contains as main components an organic acid ferric complex salt with which a molecular weight of a free acid being not more than 280, a thiosulfate and a sulfite, and a processing time by said stabilizing solution substituted for water washing is 2 minutes or shorter.
摘要翻译： 公开了一种感光卤化银彩色照相材料的处理方法，其包括在彩色显影后用漂白剂固定液处理感光卤化银彩色照相材料的方法，并依次用取代 所述漂白固定液含有作为主要成分的有机酸铁配合盐，游离酸的分子量不大于280，硫代硫酸盐和亚硫酸盐，并且所述稳定溶液的处理时间取代水 洗涤时间为2分钟或更短。
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公开(公告)号：US4863837A
公开(公告)日：1989-09-05
申请号：US149966
申请日：1988-02-02
CPC分类号： G03C7/3046
摘要： In a method of processing a light-sensitive silver halide color photographic material, comprising color developing a light-sensitive silver halide color photographic material and thereafter processing it with a processing solution having fixing ability, followed by processing with a water-washing substitute stabilizing solution in a processing tank or tanks comprising 1 to 4 tanks, the improvement wherein said water-washing substitute stabilizing solution contains at least one of the compounds represented by Formula (I) shown below and at least one of nitrilotriacetic acid and the compounds represented by Formula (II) shown below and wherein said light-sensitive silver halide color photographic material is sensitized with at least one sensitizing dye represented by Formula (III) or Formula (IV) shown below: ##STR1## wherein R represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and M represents a hydrogen atom or an alkali metal atom; ##STR2## wherein A represents a carboxyl group or a hydroxymethyl group; D represents an alkylene group having 2 to 4 carbon atoms and having or not having a hydroxyl group, a cyclohexene group, a group of ##STR3## a group of --C.sub.2 H.sub.4 OC.sub.2 H.sub.4 OC.sub.2 H.sub.4 --; and M represents a hydrogen atom, an alkali metal atom or an ammonium group; ##STR4## wherein Z.sup.1 and Z.sup.2 each represent an atomic group necessary for formation of a benzothiazole nucleus, a naphthoxazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a benzocelenazole nucleus, a naphthocelenazole nucleus, a benzoimidazole nucleus, a naphthoimidazole nucleus, a pyridine nucleus or a quinoline nucleus; R.sup.1 and R.sup.2 each represents a group selected from an alkyl group, an alkenyl group and aryl group; R.sup.3 represents a hydrogen atom, a methyl group or an ethyl group; X.sup.1- represents an anion, and is 0 or 1; and ##STR5## wherein Z.sup.3 and Z.sup.4 each represent an atomic group necessary for formation of a benzene ring or a naphthalene ring condensed at an oxazole ring or a thiazole ring, and A.sup.1 and A.sup.2 are each oxygen or sulfur.
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