公开(公告)号：US07670757B2

公开(公告)日：2010-03-02

申请号：US10577218

申请日：2005-06-24

申请人： Shoji Shiba ,  Hiroe Ishikura ,  Akihiko Okano

发明人： Shoji Shiba ,  Hiroe Ishikura ,  Akihiko Okano

IPC分类号： G03F7/40 ,  B41J1/135

CPC分类号： B41J2/1631 ,  B41J2/1603 ,  B41J2/1639 ,  G03F7/0392 ,  G03F7/2024

摘要： To provide a positive type photosensitive resin composition, containing at least an acrylic resin having a carboxylic anhydride structure in a molecule, and a compound that generates an acid when irradiated with light.

摘要翻译： 提供一种含有分子中至少含有羧酸酐结构的丙烯酸树脂的正型感光性树脂组合物和在照射时产生酸的化合物。

公开(公告)号：US07611827B2

公开(公告)日：2009-11-03

申请号：US10577255

申请日：2005-06-24

申请人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

发明人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

IPC分类号： G03F7/26

CPC分类号： G03F7/0392 ,  B41J2/1603 ,  B41J2/1631 ,  B41J2/1639

摘要： A positive type photosensitive resin composition comprises a polyacrylate resin having, in the structure, at least a structural unit represented by the following general formula (1): wherein X represents a hydroxyl group, an alkylol group having 2 to 4 carbon atoms, or a methylolamino group; R1 and R2 independently represents a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms; R3 represents an alkyl group having 1 to 3 carbon atoms, an alkoxyl group having 1 to 3 carbon atoms, or an aralkyl group having an aryl group or alkyl group with 1 to 2 carbon atoms; n represents a positive integer; and m represents 0 or a positive integer, and a condensable crosslinker.

摘要翻译： 正型感光性树脂组合物包含在结构中至少具有以下通式（1）表示的结构单元的聚丙烯酸酯树脂：其中X表示羟基，具有2〜4个碳原子的羟烷基，或 羟甲基氨基; R1和R2独立地表示氢原子或碳原子数1〜3的烷基。 R3表示碳原子数1〜3的烷基，碳原子数1〜3的烷氧基或具有1〜2个碳原子的芳基或烷基的芳烷基。 n表示正整数; m表示0或正整数，可缩合交联剂。

公开(公告)号：US20080292993A1

公开(公告)日：2008-11-27

申请号：US11954689

申请日：2007-12-12

申请人： Hiroe Ishikura ,  Shoji Shiba ,  Shinsuke Tsuji ,  Akihiko Okano

发明人： Hiroe Ishikura ,  Shoji Shiba ,  Shinsuke Tsuji ,  Akihiko Okano

IPC分类号： G03F7/20 ,  C08K5/34 ,  C08K5/45 ,  C08K5/28 ,  B41J2/105

CPC分类号： B41J2/1603 ,  B41J2/1623 ,  B41J2/1629 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2/1645 ,  C08L63/00 ,  C08L77/06 ,  G03F7/008 ,  G03F7/038

摘要： A liquid discharge head having a substrate provided with energy generating elements for generating energy to discharge a liquid, discharge portions including discharge ports for discharging the liquid, and flow paths supplying the liquid to the discharge portions and a method for its manufacture are provided. The method includes the steps of forming a layer of a negative type photosensitive resin on the substrate, and exposing the layer to light having a wavelength of 365 nm to form the discharge portions.

摘要翻译： 一种液体排出头，其具有设置有用于产生排出液体的能量产生元件的基板，包括用于排出液体的排出口的排出部以及将液体供给到排出部的流路以及其制造方法。 该方法包括以下步骤：在衬底上形成负型感光树脂层，并将该层暴露于波长为365nm的光以形成放电部分。

公开(公告)号：US20060117564A1

公开(公告)日：2006-06-08

申请号：US11291956

申请日：2005-12-02

申请人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

发明人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

IPC分类号： B21D53/76 ,  B41J2/01

CPC分类号： B41J2/1603 ,  B41J2/1629 ,  B41J2/1631 ,  B41J2/1632 ,  B41J2/1634 ,  B41J2/1639 ,  B41J2/1645 ,  Y10T29/49401

摘要： The present invention provides a method for manufacturing a high quality ink jet head, and an ink jet head manufactured by such a method, in which, in a case where a coating resin layer constituting ink flow path walls is formed, even when a solvent having a strong dissolving force is used, it is not feared that a configuration of an ink flow path pattern is distorted. In the method, a photosensitive resin composition layer in which an inter-molecule bridging reaction proceeds by irradiation of an ionization radiant ray having a first wavelength band and a molecule decaying reaction of main chain decomposing type of the resin proceeds by irradiation of an ionization radiant ray having a second wavelength band different from the first wavelength band is formed on a substrate on which energy generating elements were provided. Thereafter, an ink flow path pattern is formed by the irradiation of the ionization radiant ray having the first wavelength band and a developing process. Then, a coating resin layer constituting ink flow path walls is formed on the ink flow path pattern. After ink discharge ports are formed, the photosensitive resin composition layer forming the ink flow path pattern is dissolved and removed by irradiating the ionization radiant ray having the second wavelength band.

摘要翻译： 本发明提供一种制造高品质喷墨头的方法和通过这样一种方法制造的喷墨头，其中在形成油墨流路壁的涂布树脂层的情况下，即使当具有 使用强的溶解力，不怕油墨流路图案的构造变形。 在该方法中，通过照射具有第一波长带的电离辐射线和主链分解型树脂的分子衰减反应进行分子间桥接反应的感光性树脂组合物层通过照射电离辐射 在具有能量产生元件的基板上形成具有与第一波长带不同的第二波长带的光线。 此后，通过照射具有第一波长带和显影处理的电离辐射线形成墨流路图案。 然后，在油墨流路图案上形成构成油墨流路壁的涂布树脂层。 在形成喷墨口之后，通过照射具有第二波长带的电离辐射线来溶解形成油墨流路图形的感光性树脂组合物层。

公开(公告)号：US07592131B2

公开(公告)日：2009-09-22

申请号：US10615289

申请日：2003-07-09

申请人： Masahiko Kubota ,  Yoshinori Tagawa ,  Wataru Hiyama ,  Tatsuya Masukawa ,  Shoji Shiba ,  Yoshiaki Kurihara ,  Hiroe Ishikura ,  Akihiko Okano

发明人： Masahiko Kubota ,  Yoshinori Tagawa ,  Wataru Hiyama ,  Tatsuya Masukawa ,  Shoji Shiba ,  Yoshiaki Kurihara ,  Hiroe Ishikura ,  Akihiko Okano

IPC分类号： G03F7/40 ,  B41J2/05 ,  B41J2/16

CPC分类号： B41J2/1645 ,  B41J2/1603 ,  B41J2/1629 ,  B41J2/1631 ,  B41J2/1639

摘要： The invention is to provide a method for producing a fine structured member and a fine hollow structure, useful for producing a liquid discharge head which is inexpensive, precise and highly reliable, also to provide a method for producing a liquid discharge head utilizing such producing method for the fine structured member and the fine hollow structure and a liquid discharge head obtained by such producing method. A positive-working photosensitive material, including a ternary polymer containing an acrylate ester as a principal component, acrylic acid for thermal crosslinking and a monomer unit for expanding a sensitivity region, is used as a material for forming the Line structured member.

摘要翻译： 本发明提供一种制造精细的结构构件和精细中空结构的方法，该方法可用于制造廉价，精确和高度可靠的液体排出头，还提供一种使用这种制造方法制造排液头的方法 用于精细结构构件和细小中空结构以及通过这种制造方法获得的液体排出头。 使用包含以丙烯酸酯为主要成分的三元聚合物的正性感光材料，用于热交联的丙烯酸和用于扩大感光度区域的单体单元作为用于形成线结构体的材料。

公开(公告)号：US07473520B2

公开(公告)日：2009-01-06

申请号：US11291956

申请日：2005-12-02

申请人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

发明人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

IPC分类号： B41J2/16

CPC分类号： B41J2/1603 ,  B41J2/1629 ,  B41J2/1631 ,  B41J2/1632 ,  B41J2/1634 ,  B41J2/1639 ,  B41J2/1645 ,  Y10T29/49401

摘要： The present invention provides a method for manufacturing a high quality ink jet head in which, in a case where a coating resin layer constituting ink flow path walls is formed, even when a solvent having a strong dissolving force is used, it is not feared that a configuration of an ink flow path pattern is distorted. In the method, a photosensitive resin composition layer in which an inter-molecule bridging reaction proceeds by irradiation of an ionization radiant ray having a first wavelength band and a molecule decaying reaction of main chain decomposing type of the resin proceeds by irradiation of an ionization radiant ray having a second wavelength band different from the first wavelength band is formed on a substrate on which energy generating elements were provided. Thereafter, an ink flow path pattern is formed by the irradiation of the ionization radiant ray having the first wavelength band and a developing process. Then, a coating resin layer constituting ink flow path walls is formed on the ink flow path pattern. After ink discharge ports are formed, the photosensitive resin composition layer forming the ink flow path pattern is dissolved and removed by irradiating the ionization radiant ray having the second wavelength band.

摘要翻译： 本发明提供一种高品质喷墨头的制造方法，其中，在形成油墨流路壁的涂布树脂层的情况下，即使使用具有强溶解力的溶剂，也不用担心 油墨流路图案的构造变形。 在该方法中，通过照射具有第一波长带的电离辐射线和主链分解型树脂的分子衰减反应进行分子间桥接反应的感光性树脂组合物层通过照射电离辐射 在具有能量产生元件的基板上形成具有与第一波长带不同的第二波长带的光线。 此后，通过照射具有第一波长带和显影处理的电离辐射线形成墨流路图案。 然后，在油墨流路图案上形成构成油墨流路壁的涂布树脂层。 在形成喷墨口之后，通过照射具有第二波长带的电离辐射线来溶解形成油墨流路图形的感光性树脂组合物层。

公开(公告)号：US20070081048A1

公开(公告)日：2007-04-12

申请号：US10577255

申请日：2005-06-24

申请人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

发明人： Hiroe Ishikura ,  Shoji Shiba ,  Akihiko Okano

IPC分类号： B41J2/05

CPC分类号： G03F7/0392 ,  B41J2/1603 ,  B41J2/1631 ,  B41J2/1639

摘要： A positive type photosensitive resin composition comprises a polyacrylate resin having, in the structure, at least a structural unit represented by the following general formula (1): wherein X represents a hydroxyl group, an alkylol group having 2 to 4 carbon atoms, or a methylolamino group; R1 and R2 independently represents a hydrogen atom, or an alkyl group having 1 to 3 carbon atoms; R3 represents an alkyl group having 1 to 3 carbon atoms, an alkoxyl group having 1 to 3 carbon atoms, or an aralkyl group having an aryl group or alkyl group with 1 to 2 carbon atoms; n represents a positive integer; and m represents 0 or a positive integer, and a condensable crosslinker.

摘要翻译： 正型感光性树脂组合物包含在结构中至少具有以下通式（1）表示的结构单元的聚丙烯酸酯树脂：其中X表示羟基，具有2〜4个碳原子的羟烷基，或 羟甲基氨基; R 1和R 2独立地表示氢原子或具有1至3个碳原子的烷基; R 3表示具有1至3个碳原子的烷基，具有1至3个碳原子的烷氧基，或具有芳基或具有1至2个碳原子的烷基的芳烷基; n表示正整数; m表示0或正整数，可缩合交联剂。

公开(公告)号：US07175973B2

公开(公告)日：2007-02-13

申请号：US10914218

申请日：2004-08-10

申请人： Akihiko Okano ,  Shoji Shiba ,  Hiroe Ishikura

发明人： Akihiko Okano ,  Shoji Shiba ,  Hiroe Ishikura

IPC分类号： B41J2/16

CPC分类号： B41J2/1639 ,  B41J2/1603 ,  B41J2/1629 ,  B41J2/1631 ,  B41J2/1632 ,  B41J2/1645 ,  Y10T29/49401

摘要： A method for manufacturing an ink jet recording head comprising: (a) a process of forming a positive resist layer (I) made of a photodegradation positive resist (i) on a surface of a substrate having an energy generation element; (b) a process of removing a predetermined area of the positive resist layer (I) by photolithography to form a micro structure which becomes at least an ink flow path; (c) a process of forming a coating resin layer on the surface of the substrate on which the micro structure has been formed; (d) a process of forming ink discharge ports in a portion where the coating resin layer covers the micro structure by photolithography; and (e) a process of removing the micro structure to form the ink flow path communicated with the ink discharge ports, wherein the photodegradation positive resist (i) includes a polymer having a glutarimide structure shown by the following chemical formula (1) in a molecule; wherein R1 designates a hydrogen atom or an alkyl group, an allyl group, or an aralkyl group which has the carbon number ranging from 1 to 20.

摘要翻译： 一种制造喷墨记录头的方法，包括：（a）在具有能量产生元件的基底的表面上形成由光降解正性抗蚀剂（i）制成的正性抗蚀剂层（I）的工艺; （b）通过光刻法去除正型抗蚀剂层（I）的预定区域以形成至少形成墨水流路的微结构的工艺; （c）在已经形成有微结构的基板的表面上形成涂布树脂层的工艺; （d）通过光刻法在涂覆树脂层覆盖微结构的部分中形成喷墨口的工艺; （e）除去微结构以形成与喷墨口连通的油墨流路的工序，其中，光降解正性抗蚀剂（i）包含具有下述化学式（1）所示的戊二酰亚胺结构的聚合物 分子; 其中R 1表示氢原子或碳数为1至20的烷基，烯丙基或芳烷基。

公开(公告)号：US20060277755A1

公开(公告)日：2006-12-14

申请号：US10565658

申请日：2005-06-27

申请人： Masahiko Kubota ,  Takumi Suzuki ,  Tamaki Sato ,  Ryoji Kanri ,  Maki Hatta ,  Kazuhiro Asai ,  Shoji Shiba ,  Etsuko Hino ,  Hiroe Ishikura ,  Akihiko Okano

发明人： Masahiko Kubota ,  Takumi Suzuki ,  Tamaki Sato ,  Ryoji Kanri ,  Maki Hatta ,  Kazuhiro Asai ,  Shoji Shiba ,  Etsuko Hino ,  Hiroe Ishikura ,  Akihiko Okano

IPC分类号： B21D53/76

CPC分类号： G03F7/038 ,  B41J2/1603 ,  B41J2/1631 ,  B41J2/1639 ,  B41J2002/14475 ,  Y10T29/49401

摘要： According to the present invention, a method for manufacturing a liquid discharge head includes the steps of: forming a solid layer for forming a flow path on a substrate on which an energy generating element is arranged to generate energy that is used to discharge liquid; forming, on the substrate where the solid layer is mounted, a coating layer for coating the solid layer; forming a discharge port used to discharge a liquid, through a photolithographic process, in the coating layer deposited on the solid layer; and removing the solid layer to form a flow path that communicates with the energy element and the discharge port, whereby a material used for the coating layer contains a cationically polymerizable chemical compound, cationic photopolymerization initiator and an inhibitor of cationic photopolymerization, and whereby a material of the solid layer that forms a boundary with a portion where the discharge port of the coating layer are formed contains a copolymer of methacrylic acid and methacrylate ester.

摘要翻译： 根据本发明，液体排出头的制造方法包括以下步骤：在其上布置能量产生元件以产生用于排出液体的能量的基板上形成用于形成流路的固体层; 在固体固体层的基板上形成用于涂覆固体层的涂层; 形成用于通过光刻工艺在沉积在固体层上的涂层中排出液体的排出口; 并且除去固体层以形成与能量元件和排出口连通的流路，由此用于涂层的材料含有阳离子可聚合化合物，阳离子光聚合引发剂和阳离子光聚合抑制剂， 与形成涂层的排出口的部分形成边界的固体层包含甲基丙烯酸和甲基丙烯酸酯的共聚物。

公开(公告)号：US07629111B2

公开(公告)日：2009-12-08

申请号：US10576249

申请日：2005-06-27

申请人： Masahiko Kubota ,  Takumi Suzuki ,  Tamaki Sato ,  Ryoji Kanri ,  Maki Hatta ,  Kazuhiro Asai ,  Shoji Shiba ,  Etsuko Hino ,  Hiroe Ishikura ,  Akihiko Okano

发明人： Masahiko Kubota ,  Takumi Suzuki ,  Tamaki Sato ,  Ryoji Kanri ,  Maki Hatta ,  Kazuhiro Asai ,  Shoji Shiba ,  Etsuko Hino ,  Hiroe Ishikura ,  Akihiko Okano

IPC分类号： B41J2/16

CPC分类号： B41J2/1639 ,  B41J2/1603 ,  B41J2/1631 ,  B41J2002/14475 ,  G03F7/038

摘要： A method for manufacturing a liquid discharge head includes the steps of depositing a solid layer for forming a flow path on a substrate on which an energy generating element is arranged to generate energy that is used to discharge liquid, forming, on the substrate where the solid layer is mounted, a coating layer for coating the solid layer, forming a discharge port used to discharge a liquid, through a photolithographic process, in the coating layer formed on the solid layer, and removing the solid layer to form a flow path that communicates with the energy element and the discharge port, whereby a material used for the coating layer contains a cationically polymerizable chemical compound, a cationic photopolymerization initiator and an inhibitor of cationic photopolymerization, and whereby a material of the solid layer that forms a boundary with a portion where the discharge port of the coating layer is formed contains a copolymer of methacrylic anhydride and methacrylate ester.

摘要翻译： 一种制造液体排出头的方法包括以下步骤：在其上布置能量产生元件的衬底上沉积用于形成流路的固体层，以产生用于排出液体的能量，在衬底上形成固体 层，用于涂覆固体层的涂层，在固体层上形成的涂层中，通过光刻工艺形成用于排出液体的排出口，并除去固体层，形成连通的流路 能量元件和排出口，由此用于涂层的材料含有可阳离子聚合的化合物，阳离子光聚合引发剂和阳离子光聚合抑制剂，由此形成与部分的边界的固体层的材料 其中形成涂层的排出口包含甲基丙烯酸酐和甲基丙烯酸酯的共聚物。