摘要:
A conductive powder is provided in which particles having silicon crystallites dispersed in a silicon compound are coated on their surface with carbon. The conductive powder develops a diffraction peak assigned to Si(111) around 2θ=28.4° on x-ray diffractometry (Cu—Kα) using copper as the counter cathode, the peak having a half width of at least 1.0°, and has a specific resistance of up to 50 mΩ. The powder is used as a negative electrode material to construct a non-aqueous electrolyte secondary battery, which has a high charge/discharge capacity and improved cycle performance.
摘要:
A silicon-silicon oxide-lithium composite comprises a silicon-silicon oxide composite having such a structure that silicon grains having a size of 0.5-50 nm are dispersed in silicon oxide, the silicon-silicon oxide composite being doped with lithium. Using the silicon-silicon oxide-lithium composite as a negative electrode material, a lithium ion secondary cell having a high initial efficiency and improved cycle performance can be constructed.
摘要:
A silicon-silicon oxide-lithium composite comprises a silicon-silicon oxide composite having such a structure that silicon grains having a size of 0.5-50 nm are dispersed in silicon oxide, the silicon-silicon oxide composite being doped with lithium. Using the silicon-silicon oxide-lithium composite as a negative electrode material, a lithium ion secondary cell having a high initial efficiency and improved cycle performance can be constructed.
摘要:
A SiCO—Li composite is prepared by causing a reactive silane and/or siloxane having crosslinkable groups to crosslink, sintering the crosslinked product into an inorganic Si—C—O composite, and doping the Si—C—O composite with lithium. When the SiCO—Li composite is used as a negative electrode, a lithium ion secondary cell exhibits good cycle performance, unique discharge characteristics and improved initial efficiency.
摘要:
A negative electrode material comprising an active material and 1-20 wt % of a polyimide resin binder is suitable for use in non-aqueous electrolyte secondary batteries. The active material comprises silicon oxide particles and 1-50 wt % of silicon particles. The negative electrode exhibits improved cycle performance while maintaining the high battery capacity and low volume expansion of silicon oxide. The non-aqueous electrolyte secondary battery has a high initial efficiency and maintains improved performance and efficiency over repeated charge/discharge cycles by virtue of mitigated volumetric changes during charge/discharge cycles.
摘要:
A negative electrode material comprising an active material and 1-20 wt % of a polyimide resin binder is suitable for use in non-aqueous electrolyte secondary batteries. The active material comprises silicon oxide particles and 1-50 wt % of silicon particles. The negative electrode exhibits improved cycle performance while maintaining the high battery capacity and low volume expansion of silicon oxide. The non-aqueous electrolyte secondary battery has a high initial efficiency and maintains improved performance and efficiency over repeated charge/discharge cycles by virtue of mitigated volumetric changes during charge/discharge cycles.
摘要:
A separator 4 for a lithium secondary battery includes a porous film 12 including a polyolefin layer 16 and a lubricant layer 14 disposed on a surface of the porous film 12. The lubricant layer 14 includes a particulate substance 22 and has a three-dimensional surface roughness of 0.15 to 1.45 μm. The particulate substance 22 can adhere to the surface of the porous film 12 by electrostatic attraction. The porous film 12 can further include a heat-resistant porous layer 18 between the polyolefin layer 16 and the lubricant layer 14. The separator 4 allows a winding core for the lithium secondary battery to be pulled out smoothly.
摘要:
An Si—O—Al composite comprising silicon, silicon oxide, and aluminum oxide exhibits a powder XRD spectrum in which the intensity of a signal of silicon at 28.3° is 1-9 times the intensity of a signal near 21°. A negative electrode material comprising the Si—O—Al composite is used to construct a non-aqueous electrolyte secondary battery which is improved in 1st cycle charge/discharge efficiency and cycle performance while maintaining the high battery capacity and low volume expansion upon charging of silicon oxide.
摘要:
In one arrangement, the exposure multiplication indicating means includes an exposure multiplication selector dial having a small window cut therein and numerals marked thereon representing exposure multiplication, a film sensitivity dial, and an indicium. Numerals marked on said film sensitivity dial for representing the film sensitivity are observed, one by one, through said small window cut in the exposure multiplication selector dial, and the exposure multiplication is indicated by the numeral which is marked on the exposure multiplication selector dial in alignment with said indicium. In another arrangement, a main switch energizes the automatic exposure setting circuit and also energizes an element indicating the exposure multiplication setting. A source voltage confirming circuit enables the exposure multiplication indicating means to operate only when the source voltage is of a predetermined value.
摘要:
The present invention provides a method for producing a laminated porous film comprising a porous film substrate and a heat-resistant layer. The method comprises forming a heat-resistant layer mainly comprising a filler on the surface of the porous film substrate by applying a coating slurry comprising a solvent, a binder resin and the filler to the surface of the porous film substrate and then removing the solvent, wherein the coating slurry is prepared so as to have a contact angle of 75° or more with an untreated porous film substrate, and the method comprises conducting surface treatment of a porous film substrate so that the contact angle of the coating slurry with the porous film substrate can be 65° or less before applying the coating slurry to the surface of the porous film substrate.