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    FLUORESCENT COMPLEX AND LIGHTING SYSTEM USING THE SAME
    3.
    发明申请
    FLUORESCENT COMPLEX AND LIGHTING SYSTEM USING THE SAME 审中-公开
    使用相同的荧光复合物和照明系统

    公开(公告)号：US20080001515A1

    公开(公告)日：2008-01-03

    申请号：US11678999

    申请日：2007-02-26

    申请人： Hiroki Iwanaga ,  Akio Amano ,  Fumihiko Aiga

    发明人： Hiroki Iwanaga ,  Akio Amano ,  Fumihiko Aiga

    IPC分类号： H01J1/62 ,  C07F5/00

    CPC分类号： C07F9/65685 ,  C07F9/5304 ,  C07F9/5329 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/182

    摘要： This invention provides a fluorescent complex possessing excellent durability and luminous intensity, and a lighting system utilizing the same. The fluorescent complex comprises a rare earth ion and a β-diketone ligand. In the fluorescent complex, the β-diketone ligand comprises a β-diketone skeleton, a fluoroalkyl group, and an electron donative linking group for linking the β-diketone skeleton to the fluoroalkyl group. The fluorescent complex can be utilized in a lighting system. The rare earth ion is preferably a lanthanoid ion, particularly preferably a europium or terbium ion. When the β-diketone ligand further comprises an aromatic group, the luminous intensity can be further improved.

    摘要翻译： 本发明提供具有优异的耐久性和发光强度的荧光复合体，以及利用该荧光体的照明系统。 荧光复合物包括稀土离子和β-二酮配体。 在荧光复合物中，β-二酮配体包含β-二酮骨架，氟代烷基和用于将β-二酮骨架与氟代烷基连接的给电连接基团。 荧光复合物可用于照明系统。 稀土离子优选为镧系离子，特别优选为铕或铽离子。 当β-二酮配体还包含芳族基团时，可以进一步提高发光强度。

    Light emitting device formed using rare earth complex and luminescent medium
    4.
    发明授权
    Light emitting device formed using rare earth complex and luminescent medium 有权
    使用稀土络合物和发光介质形成的发光器件

    公开(公告)号：US07250117B2

    公开(公告)日：2007-07-31

    申请号：US10873282

    申请日：2004-06-23

    申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    IPC分类号： C09K11/06 ,  H01L51/50

    CPC分类号： C09K11/06 ,  C09K2211/182 ,  H01L51/0089 ,  H05B33/14 ,  Y10S428/917

    摘要： A light emitting device includes a light emitting element and a luminescent medium. The luminescent medium contains a rare earth complex wherein a compound represented by the following formula (1) is employed as a ligand: wherein X and Y are the same or different and are individually O, S or Se; R1, R2, R3 and R4 are the same or different, excluding a situation where R1, R2, R3 and R4 are all the same as each other, and are individually an alkyl or alkoxy group of a linear or branched structure having not more than 20 carbon atoms, a phenyl group, a biphenyl group, a naphthyl group, a heterocyclic group or a substitution product of any of these groups; n is an integer ranging from 2 to 20; and Z and W are the same or different and are individually a hydrogen atom, a deuterium atom, a halogen atom or an alkyl group.

    摘要翻译： 发光器件包括发光元件和发光介质。 发光介质含有稀土配合物，其中使用由下式（1）表示的化合物作为配体：其中X和Y相同或不同，分别为O，S或Se; R 1，R 2，R 3和R 4相同或不同，不包括其中R 1，R 2，R 3和R 4彼此相同的情况，并且分别为直链或支链结构的烷基或烷氧基， 20个碳原子，苯基，联苯基，萘基，杂环基或任何这些基团的取代产物; n为2〜20的整数; Z和W相同或不同，分别为氢原子，氘原子，卤素原子或烷基。

    Light emitting device formed using rare earth complex and luminescent medium
    5.
    发明授权
    Light emitting device formed using rare earth complex and luminescent medium 有权
    使用稀土络合物和发光介质形成的发光器件

    公开(公告)号：US07510784B2

    公开(公告)日：2009-03-31

    申请号：US11763197

    申请日：2007-06-14

    申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    IPC分类号： H01L51/50

    CPC分类号： C09K11/06 ,  C09K2211/182 ,  H01L51/0089 ,  H05B33/14 ,  Y10S428/917

    摘要： A light emitting device includes a light emitting element and a luminescent medium. The luminescent medium contains a rare earth complex wherein a compound represented by the following formula (1) is employed as a ligand: wherein X and Y are the same or different and are individually O, S or Se; R1, R2, R3 and R4 are the same or different, excluding a situation where R1, R2, R3 and R4 are all the same as each other, and are individually an alkyl or alkoxy group of a linear or branched structure having not more than 20 carbon atoms, a phenyl group, a biphenyl group, a naphthyl group, a heterocyclic group or a substitution product of any of these groups; n is an integer ranging from 2 to 20; and Z and W are the same or different and are individually a hydrogen atom, a deuterium atom, a halogen atom or an alkyl group.

    摘要翻译： 发光器件包括发光元件和发光介质。 发光介质含有稀土配合物，其中使用由下式（1）表示的化合物作为配体：其中X和Y相同或不同，分别为O，S或Se; R 1，R 2，R 3和R 4相同或不同，不包括其中R 1，R 2，R 3和R 4彼此相同的情况，并且分别为直链或支链结构的烷基或烷氧基， 20个碳原子，苯基，联苯基，萘基，杂环基或任何这些基团的取代产物; n为2〜20的整数; Z和W相同或不同，分别为氢原子，氘原子，卤素原子或烷基。

    Fluorescent rare earth complex, and light-emitting element, security medium and lighting device using the same
    6.
    发明授权
    Fluorescent rare earth complex, and light-emitting element, security medium and lighting device using the same 失效
    荧光稀土复合体，发光元件，安全介质及使用其的照明装置

    公开(公告)号：US08173271B2

    公开(公告)日：2012-05-08

    申请号：US12124786

    申请日：2008-05-21

    申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

    发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

    IPC分类号： C09K11/06 ,  H01L51/54

    CPC分类号： C07F9/5345 ,  H01L51/004 ,  H01L51/0071 ,  H01L51/0089 ,  H01L51/5012 ,  Y10S428/917

    摘要： The present invention provides a fluorescent rare earth complex having high solubility to a medium, showing fluorescence of high intensity and possessing excellent durability, and also provides a light-emitting element using that complex. The rare earth complex comprises a rare earth ion and a phosphine oxide ligand, and the phosphine oxide ligand contains a phosphorus atom connecting to at least one phenyl group. In the phenyl group, at least one of the meta-positions is substituted. It is also necessary that the para-position of the phenyl group be not substituted.

    摘要翻译： 本发明提供了一种对介质具有高溶解性的荧光稀土配合物，显示出高强度的荧光并且具有优异的耐久性，并且还提供了使用该复合物的发光元件。 稀土配合物包含稀土离子和氧化膦配体，氧化膦配体含有连接至少一个苯基的磷原子。 在苯基中，至少一个间位被取代。 苯基的对位也不是取代的。

    LIGHT EMITTING DEVICE FORMED USING RARE EARTH COMPLEX AND LUMINESCENT MEDIUM
    8.
    发明申请
    LIGHT EMITTING DEVICE FORMED USING RARE EARTH COMPLEX AND LUMINESCENT MEDIUM 有权
    使用稀土复合物和发光介质形成的发光装置

    公开(公告)号：US20070236129A1

    公开(公告)日：2007-10-11

    申请号：US11763197

    申请日：2007-06-14

    申请人： Hiroki IWANAGA ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    发明人： Hiroki IWANAGA ,  Fumihiko Aiga ,  Naomi Shida ,  Akio Amano

    IPC分类号： H01J1/63

    CPC分类号： C09K11/06 ,  C09K2211/182 ,  H01L51/0089 ,  H05B33/14 ,  Y10S428/917

    摘要： A light emitting device includes a light emitting element and a luminescent medium. The luminescent medium contains a rare earth complex wherein a compound represented by the following formula (1) is employed as a ligand: wherein X and Y are the same or different and are individually O, S or Se; R1, R2, R3 and R4 are the same or different, excluding a situation where R1, R2, R3 and R4 are all the same as each other, and are individually an alkyl or alkoxy group of a linear or branched structure having not more than 20 carbon atoms, a phenyl group, a biphenyl group, a naphthyl group, a heterocyclic group or a substitution product of any of these groups; n is an integer ranging from 2 to 20; and Z and W are the same or different and are individually a hydrogen atom, a deuterium atom, a halogen atom or an alkyl group.

    摘要翻译： 发光器件包括发光元件和发光介质。 发光介质含有稀土配合物，其中使用由下式（1）表示的化合物作为配体：其中X和Y相同或不同，分别为O，S或Se; R 1，R 2，R 3和R 4各自相同或不同，不包括R R 1，R 2，R 3和R 4都彼此相同，并且分别为 不大于20个碳原子的直链或支链结构的烷基或烷氧基，苯基，联苯基，萘基，杂环基或任何这些基团的取代产物; n为2〜20的整数; Z和W相同或不同，分别为氢原子，氘原子，卤素原子或烷基。

    FLUORESCENT RARE EARTH COMPLEX, AND LIGHT-EMITTING ELEMENT, SECURITY MEDIUM AND LIGHTING DEVICE USING THE SAME
    10.
    发明申请
    FLUORESCENT RARE EARTH COMPLEX, AND LIGHT-EMITTING ELEMENT, SECURITY MEDIUM AND LIGHTING DEVICE USING THE SAME 失效
    荧光稀土复合物，发光元件，安全中和使用其的照明装置

    公开(公告)号：US20080303426A1

    公开(公告)日：2008-12-11

    申请号：US12124786

    申请日：2008-05-21

    申请人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

    发明人： Hiroki Iwanaga ,  Fumihiko Aiga ,  Takahiro Sato

    IPC分类号： H01L51/52 ,  C07F19/00

    CPC分类号： C07F9/5345 ,  H01L51/004 ,  H01L51/0071 ,  H01L51/0089 ,  H01L51/5012 ,  Y10S428/917

    摘要： The present invention provides a fluorescent rare earth complex having high solubility to a medium, showing fluorescence of high intensity and possessing excellent durability, and also provides a light-emitting element using that complex. The rare earth complex comprises a rare earth ion and a phosphine oxide ligand, and the phosphine oxide ligand contains a phosphorus atom connecting to at least one phenyl group. In the phenyl group, at least one of the meta-positions is substituted. It is also necessary that the para-position of the phenyl group be not substituted.

    摘要翻译： 本发明提供了一种对介质具有高溶解性的荧光稀土配合物，显示出高强度的荧光并且具有优异的耐久性，并且还提供了使用该复合物的发光元件。 稀土配合物包含稀土离子和氧化膦配体，氧化膦配体含有连接至少一个苯基的磷原子。 在苯基中，至少一个间位被取代。 苯基的对位也不是取代的。