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公开(公告)号:US20080167432A1
公开(公告)日:2008-07-10
申请号:US10592537
申请日:2005-03-15
申请人: Hiroki Ohara , Tsuyoshi Furukawa , Takeo Shigemoto , Zen Komiya
发明人: Hiroki Ohara , Tsuyoshi Furukawa , Takeo Shigemoto , Zen Komiya
CPC分类号: C08G18/672 , C03C25/106 , C08L83/12 , C09D175/16 , C08G18/48 , C08L83/00
摘要: The invention aims to provide a curable liquid resin composition which produces a cured product having excellent surface slip characteristics and printability and has excellent liquid resin stability. This problem is solved by providing a curable liquid resin composition, comprising a silicone including an alkyl-modified siloxane unit and a polyether-modified siloxane unit.
摘要翻译: 本发明的目的是提供一种固化液体树脂组合物,该组合物产生具有优异的表面滑动特性和可印刷性的固化产物,并且具有优异的液体树脂稳定性。 该问题通过提供一种可固化的液体树脂组合物来解决,该组合物包含含有烷基改性的硅氧烷单元和聚醚改性的硅氧烷单元的硅氧烷。
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公开(公告)号:US07532795B2
公开(公告)日:2009-05-12
申请号:US10568453
申请日:2004-08-20
申请人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
发明人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
IPC分类号: B32B17/02 , G02B6/02 , G02B6/04 , G02B6/036 , G02B6/44 , C08L75/16 , C09D175/16 , C08F290/06 , C08F2/46
CPC分类号: C09D175/16 , C03C25/106 , C08G18/672 , C08G18/8175 , Y10T428/2938 , C08G18/48
摘要: The invention relates to a radiation-curable liquid resin composition comprising: (A) 20-90 wt % of a urethane(meth)acrylate oligomer, and (B) 1-35 wt % of a monomer shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 and R3 individually represent a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4 represents a hydrogen atom or a methyl group, and n represents an integer of 1-6, or a monomer including a hydroxyl group.
摘要翻译: 本发明涉及一种可辐射固化液体树脂组合物,其包含:(A)20-90重量%的氨基甲酸酯(甲基)丙烯酸酯低聚物和(B)1-35重量%的由下式(1)表示的单体, 其中R1表示氢原子或甲基,R2和R3分别表示氢原子或具有1-4个碳原子的烷基,R4表示氢原子或甲基,n表示1-6的整数 ,或包含羟基的单体。
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公开(公告)号:US20070191505A1
公开(公告)日:2007-08-16
申请号:US10568453
申请日:2004-08-20
申请人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
发明人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
IPC分类号: B29D11/00
CPC分类号: C09D175/16 , C03C25/106 , C08G18/672 , C08G18/8175 , Y10T428/2938 , C08G18/48
摘要: The invention relates to a radiation-curable liquid resin composition comprising: (A) 20-90 wt % of a urethane (meth)acrylate oligomer, and (B) 1-35 wt % of a monomer shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 and R3 individually represent a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4 represents a hydrogen atom or a methyl group, and n represents an integer of 1-6, or a monomer including a hydroxyl group.
摘要翻译: 本发明涉及一种可辐射固化液体树脂组合物,其包含:(A)20-90重量%的氨基甲酸酯(甲基)丙烯酸酯低聚物和(B)1-35重量%的由下式(1)表示的单体, 其中R 1表示氢原子或甲基,R 2和R 3各自表示氢原子或具有1个 -4个碳原子,R 4表示氢原子或甲基,n表示1-6的整数,或包含羟基的单体。
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公开(公告)号:US20070203258A1
公开(公告)日:2007-08-30
申请号:US10571758
申请日:2004-09-17
申请人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
发明人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
CPC分类号: C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要: The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译: 本发明涉及一种可固化液体树脂组合物,其包含:(A)具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,以及 (B)具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,其中组分(A)和组分 (B)为可固化液体树脂组合物的20-95重量%,组分(B)的含量为组分(A)和组分(B)的总量的0.1-30重量%。
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公开(公告)号:US08242202B2
公开(公告)日:2012-08-14
申请号:US10592490
申请日:2005-03-15
申请人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
IPC分类号: C09D11/00 , C08G18/00 , B32B15/00 , C08L75/00 , C08F283/04
CPC分类号: C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要: The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译: 本发明涉及一种包含以下组分(A),(B)和(C)的可固化液体树脂组合物:(A)氨基甲酸酯(甲基)丙烯酸酯低聚物,(B)由下式(1) ,CH2 = CR1COOR2(1)其中R1表示氢原子或甲基,R2表示一价有机基团,作为单体的组分(B)的总量的40重量%以上,其中, 式(1)为非极性有机基团,式(1)中的R 2基为非极性有机基团的成分(B)中的单体以下称为“含有非极性(甲基)丙烯酸酯的单体” ,(C)聚合引发剂。
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公开(公告)号:US20080254288A1
公开(公告)日:2008-10-16
申请号:US10592490
申请日:2005-03-15
申请人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
CPC分类号: C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要: The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译: 本发明涉及一种包含以下组分(A),(B)和(C)的可固化液体树脂组合物:(A)氨基甲酸酯(甲基)丙烯酸酯低聚物,(B)由下式(1) ,其中R 1表示氢原子或甲基(CH 2)2,其中R 1表示氢原子或甲基 R 2表示一价有机基团,作为单体的成分(B)的总量的40重量%以上,式中R 2〜 (1)是非极性有机基团,式(1)中的R 2-2基团为非极性有机基团的成分(B)中的单体以下称为“非极性( (C)聚合引发剂。
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公开(公告)号:US20050272829A1
公开(公告)日:2005-12-08
申请号:US10507016
申请日:2003-03-27
IPC分类号: G02B6/44 , C03C25/10 , C08F283/00 , C08F283/06 , C08F290/06 , C08G18/48 , C08G18/67 , C09D175/16 , C08G2/00
CPC分类号: C09D175/16 , C03C25/1065 , C08F283/006 , C08F283/06 , C08G18/4854 , C08G18/672 , C08G18/48
摘要: This invention relates to a curable liquid resin composition comprising: (a) 5-94 parts by weight of a urethane (meth)acrylate comprising a polyether backbone, at least one urethane group and at least one (meth)acrylate end group (b) 5-94 parts by weight of a polymerizable monomer, and; (c) 0.01-10 parts by weight of a photoinitiator, in 100 parts by weight of the curable liquid resin composition, wherein the cured product of the composition has a glass transition temperature between 30 and 85° C. or less and a stress relaxation time of 30 minutes or less.
摘要翻译: 本发明涉及一种可固化液体树脂组合物,其包含:(a)5-94重量份的包含聚醚主链,至少一个氨基甲酸酯基和至少一个(甲基)丙烯酸酯端基(b)的氨基甲酸酯(甲基)丙烯酸酯, 5-94重量份的可聚合单体,和 (c)0.01-10重量份的光引发剂,在100重量份的可固化液体树脂组合物中,其中组合物的固化产物的玻璃化转变温度为30-85℃或更低,应力松弛 时间30分钟以内。
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公开(公告)号:US07906566B2
公开(公告)日:2011-03-15
申请号:US10571758
申请日:2004-09-17
申请人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
发明人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
CPC分类号: C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要: The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译: 本发明涉及一种可固化液体树脂组合物,其包含:(A)具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,以及 (B)具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,其中组分(A)和组分 (B)为可固化液体树脂组合物的20-95重量%,组分(B)的含量为组分(A)和组分(B)的总量的0.1-30重量%。
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公开(公告)号:US20080219635A1
公开(公告)日:2008-09-11
申请号:US11660523
申请日:2005-08-30
CPC分类号: C08G18/8175 , C03C25/1065 , C08F290/147 , C08G18/672 , C08L83/12 , C09D175/16 , C08G18/48
摘要: The present invention provides a curable liquid resin composition which, when cured, exhibits excellent removability from an adjacent coating layer and is suitable for an optical fiber upjacket material. The curable liquid resin optical fiber upjacket composition comprising a urethane (meth)acrylate or a (meth)acrylate oligomer, a reactive diluent, a polymerization initiator, and a polyol compound having a molecular weight of 1500 or more.
摘要翻译: 本发明提供了一种可固化液体树脂组合物,其在固化时表现出相邻涂层的优异的可除去性,并且适用于光纤上护套材料。 包含氨基甲酸酯(甲基)丙烯酸酯或(甲基)丙烯酸酯低聚物,反应性稀释剂,聚合引发剂和分子量为1500以上的多元醇化合物的可固化液体树脂光纤上衣组合物。
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10.
公开(公告)号:US20080287605A1
公开(公告)日:2008-11-20
申请号:US11886088
申请日:2006-03-10
CPC分类号: C03C25/1065 , C08K5/3435 , C08K5/5415 , C09D4/00 , C09D7/63
摘要: A curable liquid resin optical fiber coating composition comprising 0.1 to 10 wt %, relative to the total weight of the composition, of an alkoxysilane compound (A) which does not contain a radically polymerizable functional group, and 0.01 to 1 wt %, relative to the total weight of the composition, of a hindered amine compound. (B). This curable liquid resin composition produces a cured product that ensures a high n-value of the coated optical fiber and an excellent fiber strength after coating removal.
摘要翻译: 相对于组合物的总重量为0.1〜10重量%的可固化液晶树脂光纤涂层组合物,相对于不含自由基聚合性官能团的烷氧基硅烷化合物(A)为0.01〜1重量% 组合物的总重量,受阻胺化合物。 (B)。 该可固化液体树脂组合物产生确保涂层光纤的n值高,并且在除去涂层后具有优异的纤维强度的固化产物。
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