摘要:
A solid polymer electrolyte membrane excellent in proton conductivity and methanol barrier property, which is composed of a composite membrane obtained by allowing aniline to be adsorbed by a perfluorosulfonic acid polymer membrane, and subjecting the aniline to oxidative polymerization to form a polyaniline-containing polymer membrane.
摘要:
A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.
摘要:
A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.
摘要:
This invention provides a solid polymer electrolyte which is low in water absorption, from which no dopant runs out even in pressing, and which is excellent in stability in the presence of water or methanol, proton conductivity and methanol barrier properties, in which an imidazole ring-containing polymer such as a polybenzimidazole compound is doped with an acid in which at least one hydrogen atom of an inorganic acid such as phosphoric acid is substituted by a functional group having a phenyl group by blending the imidazole ring-containing polymer with the acid in a solution using a solvent such as trifluoroacetic acid, preferably at a rate of 1 to 10 molecules of the acid per repeating structure unit of a molecular chain of the imidazole ring-containing polymer, the solid polymer electrolyte.
摘要:
Sulfonic acid group-containing polyvinyl alcohol having crosslinked structures, which is obtained by heat treating a mixed solution of polyvinyl alcohol, a sulfonating agent and a crosslinking agent, a composite polymer membrane excellent in proton conductivity and methanol barrier property, which is obtained by applying the mixed solution to a water-absorptive or hydrophilic polymer membrane, followed by sulfonation and crosslinking, and an electrode for a fuel cell excellent in catalytic activity, which comprises sulfonic acid group-containing polyvinyl alcohol having crosslinked structures and fine catalyst particles carried on porous particles.
摘要:
A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.
摘要:
A novel method for producing a meta type polyaniline, comprising polymerizing aniline in at least one organic solvent selected from N-methyl-2-pyrrolidone, N,N-dimethyl sulfoxide, N,N-dimethylacetamide and N,N-dimethylformamide, in the presence of at least one oxidizing agent selected from ammonium peroxodisulfate, iron(III) chloride, manganese dioxide and hydrogen peroxide, at −20° C. to 50° C.
摘要:
An image forming apparatus includes: an image carrier; a latent image forming device; a developing device; an electrode which faces to the image carrier; an electric power source, a toner contamination detecting device for detecting toner contamination onto the electrode; an electrode cleaning device for cleaning the electrode; and a controlling section. The control section controls the electric power source to apply at least an alternating current voltage to the electrode so that toner image is rearranged by reciprocally moving toner of the toner image between the image carrier and the electrode control section and allows the electrode cleaning device to clean the electrode when the toner contamination detecting device detects toner contamination on the electrode, and performs the toner rearrangement by the electrode from which the toner contamination is removed.
摘要:
An image forming apparatus includes: an image carrier; a latent image forming device; a developing device; an electrode which faces to the image carrier; an electric power source, a toner contamination detecting device for detecting toner contamination onto the electrode; an electrode cleaning device for cleaning the electrode; and a controlling section, wherein the control section controls the electric power source to apply at least an alternating current voltage to the electrode so that toner image is rearranged by reciprocally moving toner of the toner image between the image carrier and the electrode control section and allows the electrode cleaning device to clean the electrode when the toner contamination detecting device detects toner contamination on the electrode, and performs the toner rearrangement by the electrode from which the toner contamination is removed.
摘要:
An image forming apparatus includes: a developing device which applies a developing bias voltage obtained by superimposing an AC bias voltage onto a DC bias voltage to a photoreceptor, and develops a latent image on the photoreceptor with a developer to form a toner image. The apparatus has a toner forced discharge mode for forming a toner image for forced discharge in a first image formation area provided in a non-image formation area other than a second image formation area on the photoreceptor to forcibly discharge a toner from the developing device. When the mode is selected, an AC bias voltage at a frequency lower than that in the second image formation area is applied to the first image formation area to develop a latent image for forced discharge, to form a toner image, and a toner of the toner image is collected by a cleaning device.