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1.发明授权Curable composition containing an oxypropylene polymer and calcium carbonate which has been surface treated with a fatty acid 失效含有已经用脂肪酸表面处理的氧化丙烯聚合物和碳酸钙的可固化组合物
公开(公告)号：US5703146A
公开(公告)日：1997-12-30
申请号：US655307
申请日：1996-05-21
IPC分类号： C08G65/336 , C08K9/00
CPC分类号： C08G65/336
摘要： A curable composition includes (A) 100 parts by weight of an oxypropylene polymer having groups containing silicon atoms bonded to a hydroxy group and/or a hydrolyzable group and capable of crosslinking by forming a siloxane bond, a maximum Mw/Mn of 1.6, and an average molecular weight of at least 6,000, (B) from 100 to 200 parts by weight of calcium carbonate containing at least 30% by weight calcium carbonate of an average particle size of not larger than 0.5 .mu.m and surface-treated with a fatty acid, (C) from 30 to 100 parts by weight of a plasticizer containing at least 5% by weight phthalic acid ester plasticizer, (D) from 0.5 to 10 parts by weight of a compound represented by the formula R.sup.1 Si(OCH.sub.3).sub.3 and/or Si(OCH.sub.2 CH.sub.3).sub.4 (wherein R.sup.1 represents a monovalent organic group containing no amino groups), (E) from 0.5 to 10 parts by weight of a compound represented by following formula (1), and (F) from 0.5 to 5 parts by weight of an organotin curing catalyst, the total amount of components (D) and (E) being at least 2 parts by weight, and component (A) occupying from 15 to 35% by weight; R.sup.2 Si(CH.sub.3).sub.n (OR.sup.3).sub.3-n ( 1) wherein R.sup.2 represents a monovalent organic group having at least one amino group; R.sup.3 represents CH.sub.3 or CH.sub.2 CH.sub.3 ; and n represents 0 or 1.
摘要翻译： 可固化组合物包括（A）100重量份具有与羟基键合的硅原子的基团的氧化丙烯聚合物和/或可水解基团，并且能够通过形成硅氧烷键交联，最大Mw / Mn为1.6，和 平均分子量为6,000以上，（B）100〜200重量份的含有至少30重量％平均粒径不大于0.5μm的碳酸钙并用脂肪表面处理的碳酸钙 酸，（C）30〜100重量份含有至少5重量％邻苯二甲酸酯增塑剂的增塑剂，（D）0.5〜10重量份式R 1 Si（OCH 3）3表示的化合物和 /或Si（OCH 2 CH 3）4（其中R 1表示不含氨基的一价有机基团），（E）0.5至10重量份由下式（1）表示的化合物和（F）0.5至5 有机锡固化催化剂重量份，组合物总量 （D）和（E）为至少2重量份，成分（A）占15〜35重量％; R2Si（CH3）n（OR3）3-n（1）其中R2表示一价有机物 具有至少一个氨基的基团; R3代表CH3或CH2CH3; n表示0或1。
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公开(公告)号：US5223597A
公开(公告)日：1993-06-29
申请号：US941915
申请日：1992-09-08
IPC分类号： C08G65/336 , C08L71/02
CPC分类号： C08G65/336 , C08L71/02
摘要： A curable composition comprising (A) a reactive silicon group-containing oxypropylene polymer having a ratio of Mw.sup.1 /Mn.sup.1 of higher than 1.6 and (B) a reactive silicon group-containing oxypropylene polymer having a ratio of Mw.sup.2 /Mn.sup.2 of not higher than 1.6 and a number-average molecular weight (Mn.sup.2) of not less than the number-average molecular weight (Mn.sup.1) of the oxypropylene polymer (A). A problem caused by the high viscosity of the oxypropylene polymer having a ratio of Mw.sup.1 /Mn.sup.1 of higher than 1.6 can be solved and the viscosity the polymer (A) before curing can be lowered without greatly lowering excellent rubber elasticity of cured articles by mixing the polymer (A) with the oxypropylene polymer (B) having a ratio of Mw.sup.2 /Mn.sup.2 of not higher than 1.6.
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公开(公告)号：US5286780A
公开(公告)日：1994-02-15
申请号：US941804
申请日：1992-09-08
IPC分类号： C08G65/336 , C08L71/02 , C08G65/32 , C08L83/10
CPC分类号： C08G65/336 , C08L71/02
摘要： A curable composition is disclosed, including (A) an oxypropylene polymer having a narrow molecular weight distribution which does not have any branched chain, is linear and has at least one reactive silicon atom-containing group; and (B) an oxypropylene polymer having a narrow molecular weight distribution which has at least one branched chain and at least one reactive silicon atom-containing group. Cured articles obtained from the curable composition have a tear strength which is unexpectedly higher than the tear strength of the cured article of the component (A) alone or the component (B) alone.
摘要翻译： 公开了一种可固化组合物，其包括（A）具有窄分子量分布的氧化丙烯聚合物，其不具有任何支链，是线性的并且具有至少一个含活性硅原子的基团; 和（B）具有窄分子量分布的氧化丙烯聚合物，其具有至少一个支链和至少一个含活性硅原子的基团。 从可固化组合物获得的固化物具有突然高于单独的组分（A）的固化制品或单独的组分（B）的撕裂强度的撕裂强度。
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公开(公告)号：US5342914A
公开(公告)日：1994-08-30
申请号：US43865
申请日：1993-04-07
IPC分类号： C08K5/54 , C08G65/336 , C08K5/5415 , C08L71/02 , C09K3/10 , C08G77/20
CPC分类号： C08L71/02 , C08G65/336 , C08K5/5415
摘要： A curable composition comprising an oxyalkylene polymer having a silicon-containing hydrolyzable group and a low-molecular silicon compound having a hydrolyzable group bonded to a silicon atom which is more reactive to H.sub.2 O than the oxyalkylene polymer, with the mole number of the total hydrolyzable groups in said low-molecular silicon compound being not more than that of the hydrolyzable groups in said oxyalkylene polymer. A sealing compound having well-balanced storage stability and rapid curability is provided.
摘要翻译： 一种可固化组合物，其包含具有含硅可水解基团的氧化烯聚合物和具有与氧原子聚合物更能对H 2 O反应的硅原子键合的可水解基团的低分子硅化合物，以及总可水解基团的摩尔数 在所述低分子硅化合物中的摩尔数不大于所述氧化烯聚合物中的可水解基团。 提供了具有良好平衡的储存稳定性和快速固化性的密封剂。
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公开(公告)号：US06486289B1
公开(公告)日：2002-11-26
申请号：US09529168
申请日：2000-06-14
IPC分类号： C08G7708
CPC分类号： C08K5/17 , C08G65/336 , C08K5/09 , C08K5/57 , C08L71/02
摘要： The present invention has its object to provide a curable composition insuring a reduced stress without sacrificing restoring force and other physical properties and having a sufficient degree of adhesiveness. The present invention is related to a curable composition comprising comprising an oxyalkylene polymer having at least one reactive silicon group per molecule (A-1), an acid (B), an amine (C), and a tin-series curing catalyst (D). This composition optionally contains a vinyl polymer having at least one reactive silicon group.
摘要翻译： 本发明的目的是提供一种固化组合物，其确保减少的应力而不会牺牲恢复力和其它物理性能并具有足够的粘附性。本发明涉及一种可固化组合物，其包含含有至少一种反应性的氧化烯聚合物 （A-1），酸（B），胺（C）和锡系固化催化剂（D）。该组合物任选地含有具有至少一个反应性硅基团的乙烯基聚合物。
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6.发明授权
公开(公告)号：US5880245A
公开(公告)日：1999-03-09
申请号：US980976
申请日：1997-11-13
申请人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
发明人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
IPC分类号： C08G65/336 , C08G77/46 , C08G77/04
CPC分类号： C08G77/46 , C08G65/336
摘要： The present invention provides a process for the preparation of a reactive silicon group-containing polymer. A novel process for the preparation of the polymer includes allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an active hydrogen-containing functional group with which the alkylene oxide is reactive as an initiator in the presence of a catalyst to synthesize a polymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into the polymer. Another process for the preparation of the polymer as defined above is provided, which includes allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an epoxy group in the presence of a catalyst with an active hydrogen-containing compound as an initiator to synthesize a polymer the main chain of which is essentially a copolymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into the polymer.
摘要翻译： 本发明提供了制备含反应性含硅基团的聚合物的方法。 用于制备聚合物的新方法包括使烯化氧与催化剂存在下的具有活性含氢官能团的有机聚硅氧烷化合物进行开环聚合，其中环氧烷作为引发剂反应，合成一种 有机聚硅氧烷和聚氧化烯的聚合物，然后将反应性硅基团引入聚合物中。 提供另一种制备如上所述聚合物的方法，其中包括使烯化氧在具有活性氢化合物作为引发剂的催化剂存在下，与具有环氧基的有机聚硅氧烷化合物进行开环聚合， 合成聚合物，其主链基本上是有机聚硅氧烷和聚氧化烯的共聚物，然后将反应性硅基团引入聚合物中。
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7.发明授权Method of producing crosslinkable silyl group-containing polyoxyalkylene polymers 有权制备可交联甲硅烷基的聚氧化烯聚合物的方法公开(公告)号：US06503995B2
公开(公告)日：2003-01-07
申请号：US09832344
申请日：2001-04-11
申请人： Ryotaro Tsuji , Yousuke Asai , Masayuki Fujita , Hajime Harada , Susumu Kyotani , Takeshi Kawamura , Kenji Kuroda , Hiroshi Iwakiri
发明人： Ryotaro Tsuji , Yousuke Asai , Masayuki Fujita , Hajime Harada , Susumu Kyotani , Takeshi Kawamura , Kenji Kuroda , Hiroshi Iwakiri
IPC分类号： C08G7712
CPC分类号： C08G65/33348 , C08G65/2663 , C08G65/336
摘要： A method of producing a polyoxyalkylene polymer having at least one crosslinkable silyl group and at least one hydroxyl group in each molecule which comprises treating a polyoxyalkylene polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule and an impurity double metal cyanide complex as mixed therein with a metal-coordinating compound and adding a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out the hydrosilylation reaction.
摘要翻译： 一种生产在每个分子中具有至少一个可交联甲硅烷基和至少一个羟基的聚氧化烯聚合物的方法，其包括在每个分子中制备具有至少一个不饱和基团和至少一个醇羟基的聚氧化烯聚合物和杂质双金属氰化物 与金属配位化合物混合并在每个分子中加入具有氢 - 硅键和交联性甲硅烷基的化合物和氢化硅烷化催化剂，从而进行氢化硅烷化反应。
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公开(公告)号：US6077896A
公开(公告)日：2000-06-20
申请号：US151095
申请日：1998-09-10
申请人： Ayako Yano , Masayuki Fujita , Hiroshi Iwakiri
发明人： Ayako Yano , Masayuki Fujita , Hiroshi Iwakiri
IPC分类号： C09K3/10 , C08G65/336 , C08K5/053 , C08L71/02 , C08K5/10
CPC分类号： C08G65/336
摘要： It is an object of the present invention to provide a curable composition capable of providing good rubber-like mechanical properties with low stress and high elongation, without sacrificing tack, recovery, curability, weathering resistance, storage stability and other characteristics.This invention relates to a curable composition which comprises (a) an oxyalkylene polymer containing at least one reactive silyl group per molecule thereof and (b) a compound having an intramolecular .alpha., .beta.-diol or .alpha., .gamma.-diol structure.
摘要翻译： 本发明的目的是提供一种能够提供良好的橡胶状机械性能，低应力和高伸长率的固化性组合物，而不会牺牲粘性，回复性，固化性，耐候性，储存稳定性等特性。 本发明涉及可固化组合物，其包含（a）每分子含有至少一个反应性甲硅烷基的氧化烯聚合物和（b）具有分子内α，β-二醇或α，γ-二醇结构的化合物。
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9.发明授权
公开(公告)号：US5719249A
公开(公告)日：1998-02-17
申请号：US671076
申请日：1996-06-27
申请人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
发明人： Masayuki Fujita , Hiroshi Iwakiri , Fumio Kawakubo
IPC分类号： C08G65/336 , C08G77/46 , C08L83/12 , C08G77/04
CPC分类号： C08L83/12 , C08G65/336 , C08G77/46
摘要： The present invention provides a reactive silicon group-containing polymer containing at least one reactive silicon group per molecule, the main chain of the polymer being essentially a copolymer of organopolysiloxane and polyoxyalkylene, which causes no macro phase separation during storage and gives a hardened material having an excellent weathering resistance, little residual tack and excellent coating adhesivity. The present invention provides a process for the preparation of the foregoing reactive silicon group-containing polymer. A novel process for the preparation of the polymer as defined above is provided, which comprises allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an active hydrogen-containing functional group with which said alkylene oxide is reactive as an initiator in the presence of a catalyst to synthesize a polymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into said polymer. Another process for the preparation of the polymer as defined above is provided, which comprises allowing an alkylene oxide to undergo ring opening polymerization with an organopolysiloxane compound having an epoxy group in the presence of a catalyst with an active hydrogen-containing compound as an initiator to synthesize a polymer the main chain of which is essentially a copolymer of organopolysiloxane and polyoxyalkylene, and then introducing a reactive silicon group into said polymer.
摘要翻译： 本发明提供了每分子含有至少一个反应性硅基团的含反应性硅基团的聚合物，该聚合物的主链基本上是有机聚硅氧烷和聚氧化烯的共聚物，其在储存期间不会产生宏观相分离并产生具有 耐候性优异，残留粘性小，涂料粘合性优异。 本发明提供了制备上述含反应性含硅基团的聚合物的方法。 提供了一种制备如上所述的聚合物的新方法，其包括使烯化氧与具有活性含氢官能团的有机聚硅氧烷化合物进行开环聚合，所述烯化氧在其中具有反应性作为引发剂 存在催化剂以合成有机聚硅氧烷和聚氧化烯的聚合物，然后将反应性硅基团引入所述聚合物中。 提供了另一种制备如上所述聚合物的方法，其包括使烯化氧在具有活性氢化合物作为引发剂的催化剂存在下，与具有环氧基的有机聚硅氧烷化合物进行开环聚合， 合成聚合物，其主链基本上是有机聚硅氧烷和聚氧化烯的共聚物，然后将反应性硅基团引入所述聚合物。
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公开(公告)号：US07652119B2
公开(公告)日：2010-01-26
申请号：US11667459
申请日：2005-11-09
CPC分类号： C08K5/16 , C08K5/541 , C08L101/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more polymers having a silicon-containing group which is crosslinkable by forming siloxane bonds, (B) an amine compound, and (C) a silicon compound having, as substituents on its silicon, at least one electron withdrawing group, and at least one group selected from the group consisting of alkoxy groups, alkenyloxy groups, acyloxy groups, and a hydroxyl group.
摘要翻译： 本发明的问题是提供一种通过使用除了有机锡催化剂之外的催化剂提供良好固化性的可固化组合物。 上述问题是通过一种可固化组合物来解决的，其包括：（A）一种或多种具有通过形成硅氧烷键可交联的含硅基团的聚合物，（B）胺化合物，和（C）具有如下 其硅上的取代基，至少一个吸电子基团和至少一个选自烷氧基，烯氧基，酰氧基和羟基的基团。
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