公开(公告)号：US06440623B2

公开(公告)日：2002-08-27

申请号：US09770204

申请日：2001-01-29

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B41M500

CPC分类号： B41N1/14 ,  B41C1/1058 ,  B41C1/1066 ,  B41N3/036 ,  Y10T428/24802 ,  Y10T428/24893

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer comprising inorganic particles and a binder resin, wherein the inorganic particles comprise at least one kind of particles selected from: (i) metal oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising a metal atom selected from Mg, Ba, Ge, Sn, Zn, Pb, La, Zr, V, Cr, Mo, W, Mn, Co, Ni and Cu; and (ii) double oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising at least one metal atom selected from Mg, Al, Si, Ti, Zr, Cr, V, Mo, Sn, W and Nb, and wherein the binder resin comprises a complex comprising: a resin containing a bond in which a metal atom is connected with an oxygen atom; and an organic polymer containing a group capable of forming a hydrogen bond with the resin and at least one polar functional group selected from a carboxy group, a sulfo group and a phosphono group.

摘要翻译： 一种直接拉伸型平版印刷版原版，其特征在于，具有防水载体，其上设置有包含无机颗粒和粘合剂树脂的图像接受层，其中所述无机颗粒包含至少一种选自以下的颗粒：（i）金属氧化物颗粒 平均粒径为0.01〜5μm，包含选自Mg，Ba，Ge，Sn，Zn，Pb，La，Zr，V，Cr，Mo，W，Mn，Co，Ni和Cu的金属原子; 和（ii）平均粒度为0.01〜5μm，并且包含至少一种选自Mg，Al，Si，Ti，Zr，Cr，V，Mo，Sn，W和Nb的金属原子的氧化物粒子，以及 其中所述粘合剂树脂包含复合物，所述络合物包含：含有金属原子与氧原子连接的键的树脂; 和含有能够与树脂形成氢键的基团和至少一个选自羧基，磺基和膦酰基的极性官能团的有机聚合物。

公开(公告)号：US06283029B1

公开(公告)日：2001-09-04

申请号：US09464575

申请日：1999-12-16

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B41C110

CPC分类号： G03G13/28 ,  B41C1/1058 ,  B41C1/1066 ,  G03G13/286

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer, the image-receiving layer being formed from a dispersion comprising: an inorganic pigment comprising silica particles having an average particle diameter of from 1 to 6 &mgr;m and ultra-fine particles of inorganic pigment having an average particle diameter of from 5 to 50 nm, at a weight ratio thereof of from 40:60 to 70:30; and a hydrophilic binder resin comprising at least one modified hydrophilic binder resin which is modified with a silyl functional group represented by the following formula (I): —Si(R)n(OX)3-n  (I) wherein R represents a hydrogen atom or a hydrocarbon group having from 1 to 12 carbon atoms; X represents an aliphatic group having from 1 to 12 carbon atoms; and n represents 0, 1 or 2. Also disclosed are methods of preparing a lithographic printing plate using the direct drawing type lithographic printing plate precursor.

摘要翻译： 一种直接拉伸型平版印刷版原版，其特征在于，具有在其上设置有图像接受层的防水支撑体，所述图像接收层由分散体形成，所述分散体包含：无机颜料，其包含平均粒径为1〜 6μm和平均粒径为5〜50nm的无机颜料的超细颗粒，重量比为40:60〜70:30; 和亲水性粘合剂树脂，其包含至少一种由下式（I）表示的甲硅烷基官能团改性的改性亲水性粘合剂树脂：其中R表示氢原子或具有1至12个碳原子的烃基; X表示具有1至12个碳原子的脂族基团; 并且n表示0,1或2.还公开了使用直接拉伸型平版印刷版原版制备平版印刷版的方法。

公开(公告)号：US5250376A

公开(公告)日：1993-10-05

申请号：US943520

申请日：1992-09-11

申请人： Eiichi Kato ,  Akio Oda ,  Hiroshi Tashiro

发明人： Eiichi Kato ,  Akio Oda ,  Hiroshi Tashiro

IPC分类号： G03G5/05 ,  G03G13/28 ,  G03G5/087

CPC分类号： G03G13/28 ,  G03G5/0589

摘要： An electrophotographic lithographic printing plate, in which the effect by the hydrophilic property of non-image areas is further improved, and which is stable during storage even under very severe conditions and capable of readily realizing the hydrophilic property in a short time during processing of rendering hydrophilic is provided by a process for the production of an electrophotographic lithographic printing plate, comprising subjecting an electrophotographic photoreceptor to imagewise exposure and forming a toner image, the electrophotographic photoreceptor comprising an electroconductive support having provided thereon at least one photoconductive layer containing photoconductive inorganic compound and a binder resin, the binder resin comprising at least one resin (P) as defined herein, and optionally at least one crosslinking agent, and then subjecting a non-image area of the photoconductive layer to an oil-desensitizing processing with a processing solution containing a hydrophilic compound containing a substituent having a Pearson's nucleophilic constant n of at least 5.5.

摘要翻译： 一种电子照相平版印刷版，其中非图像区域的亲水性的作用进一步提高，即使在非常苛刻的条件下也能在保存期间稳定，并且能够在加工过程中在短时间内容易地实现亲水性 通过生产电子照相平版印刷版的方法提供亲水性，其包括使电子照相感光体经受成像曝光并形成调色剂图像，所述电子照相感光体包含导电载体，所述导电载体上设置有至少一个含有光电导无机化合物的光电导层和 粘合剂树脂，包含至少一种如本文所定义的树脂（P）的粘合剂树脂和任选的至少一种交联剂，然后用含有以下物质的处理溶液对光电导层的非图像区域进行脱油处理 一个水电 含有具有至少5.5的皮尔逊亲核常数n的取代基的亲液性化合物。

公开(公告)号：US06393985B1

公开(公告)日：2002-05-28

申请号：US09473501

申请日：1999-12-28

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B41N114

CPC分类号： B41C1/1066 ,  B41N1/14 ,  Y10T428/256

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer comprising inorganic particles and a binder resin, wherein the inorganic particles comprise at least one kind of particles selected from: (i) metal oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising a metal atom selected from Mg, Ba, Ge, Sn, Zn, Pb, La, Zr, V, Cr, Mo, W, Mn, Co, Ni and Cu; (ii) metal hydroxide particles having an average particle size of from 0.01 to 5 &mgr;m, the metal hydroxide being represented by the formula (I): M(OH)x  (I) wherein M represents a metal atom selected from Mg, Ba, Al, Ti, Zn, Cu, Ni, Sn, Co, Ge, Fe and La, and x represents a valence of the metal M; and (iii) double oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising at least one metal atom selected from Mg, Al, Si, Ti, Zr, Cr, V, Mo, Sn, W and Nb, and wherein the binder resin comprises a complex comprising: a resin containing a siloxane bond in which a silicon atom is connected with an oxygen atom; and an organic polymer containing a group capable of forming a hydrogen bond with the resin containing a siloxane bond.

摘要翻译： 一种直接拉伸型平版印刷版原版，其特征在于，具有防水载体，其上设置有包含无机颗粒和粘合剂树脂的图像接受层，其中所述无机颗粒包含至少一种选自以下的颗粒：（i）金属氧化物颗粒 平均粒径为0.01〜5μm，包含选自Mg，Ba，Ge，Sn，Zn，Pb，La，Zr，V，Cr，Mo，W，Mn，Co，Ni和Cu的金属原子; （ii）平均粒径为0.01〜5μm的金属氢氧化物粒子，所述金属氢氧化物由式（I）表示：其中，M表示选自Mg，Ba，Al，Ti，Zn，Cu， Ni，Sn，Co，Ge，Fe和La，x表示金属M的化合价; 和（iii）平均粒度为0.01〜5μm的二氧化物粒子，其含有选自Mg，Al，Si，Ti，Zr，Cr，V，Mo，Sn，W和Nb中的至少一种金属原子，以及 其中所述粘合剂树脂包含复合物，所述配合物包含：含有硅原子与氧原子连接的硅氧烷键的树脂; 和含有与含有硅氧烷键的树脂形成氢键的基团的有机聚合物。

公开(公告)号：US5939228A

公开(公告)日：1999-08-17

申请号：US787584

申请日：1997-01-22

申请人： Hiroshi Tashiro ,  Seishi Kasai ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Seishi Kasai ,  Eiichi Kato

IPC分类号： G03G5/05 ,  G03G5/08 ,  G03G13/28 ,  G03G5/087

CPC分类号： G03G5/0514 ,  G03G13/28 ,  G03G5/0517 ,  G03G5/0521 ,  Y10T428/24413

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer, wherein the image-receiving layer is formed by film coating a dispersion prepared by wet dispersion processing, with a dispersion medium of a nonaqueous solvent, a mixture comprising at least dry zinc oxide, a binder resin and an organic compound which is soluble in the dispersion medium and contains at least one acid group selected from the group consisting of --CO.sub.2 H, --SO.sub.3 H and --PO.sub.3 H.sub.2, adding a water-soluble low molecular weight organic compound containing at least two or more --PO.sub.3 H.sub.2 groups, which can form a chelate compound with a zinc ion, and further effecting wet dispersion processing.

摘要翻译： 包括在其上设置有图像接收层的耐水支撑体的直接拉伸型平版印刷版原版，其中，图像接收层通过将通过湿分散处理制备的分散体膜涂覆在非水溶剂的分散介质上而形成 ，至少包含干燥的氧化锌，粘合剂树脂和可溶于分散介质并含有至少一种选自-CO 2 H，-SO 3 H和-PO 3 H 2的酸基的有机化合物的混合物， 含有至少两个以上的PO 3 H 2基团的可溶性低分子量有机化合物，其可以与锌离子形成螯合化合物，并进一步进行湿分散处理。

公开(公告)号：US06389970B1

公开(公告)日：2002-05-21

申请号：US09583669

申请日：2000-05-31

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B41C110

CPC分类号： B41C1/1066

摘要： A direct drawing lithographic printing plate precursor, which includes a water-resisting support having provided thereon an image-receiving layer, an image being formed on the image-receiving layer with an oil-based ink by an electrostatic ink jet system, wherein the water-resisting support has at least a resin coating layer on the side opposite to the side on which the image-receiving layer is provided, wherein the resin coating layer includes a mixture containing from 10 to 90 wt % of a low density polyethylene having a density of from 0.915 to 0.930 g/ml and a melt index of from 1.0 to 30.0 g/10 min., wherein the surface of the resin coating layer has a Bekk's smoothness of from 5 to 2,000 sec/10 ml, and wherein the water-resisting support has a conductive layer having a specific electric resistance value of 1010 &OHgr; cm or less on the image-receiving layer side surface thereof and on at least one end face thereof. Also disclosed is a method for preparing a direct drawing lithographic printing plate using the printing plate precursor.

摘要翻译： 一种直接绘制平版印刷版原版，其包括在其上设置有图像接收层的防水支撑体，通过静电喷墨系统用油性油墨形成在图像接收层上的图像，其中水 保留的载体在与设置图像接收层的一侧相对的一侧上具有至少一层树脂涂层，其中树脂涂层包括含有10至90重量％的具有密度的低密度聚乙烯的混合物 为0.915〜0.930g / ml，熔体指数为1.0〜30.0g / 10min，其中树脂被覆层的表面的贝克平滑度为5〜2000秒/ 10毫升， 耐受载体具有在其图像接收层侧表面上和其至少一个端面上具有1010欧标立方厘米或更小的比电阻值的导电层。 还公开了使用印版前体制备直接平版印刷版的方法。

公开(公告)号：US5945240A

公开(公告)日：1999-08-31

申请号：US775007

申请日：1996-12-27

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： G03G5/05 ,  G03G5/08 ,  G03G5/10 ,  G03G13/28 ,  G03G5/087

CPC分类号： G03G13/28 ,  G03G5/0514 ,  G03G5/0517 ,  Y10T428/24413

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support and an image receiving layer provided thereon, wherein a surface of the water-resistant support has the Bekk smoothness in the range of from 900 to 3,000 (second/10 cc) and the image receiving layer contains zinc oxide, a binder resin and a water-soluble organic compound having at least one acidic group selected from --CO.sub.2 H, --SO.sub.3 H and --PO.sub.3 H.sub.2, which is capable of forming a chelate compound with zinc oxide or a zinc ion. The direct drawing type lithographic printing plate precursor provides a lithographic printing plate which produces prints having a clear image without stains even when it is subjected to electrostatic transfer of a toner image formed by an electrophotographic copying machine.

摘要翻译： 一种直接拉伸型平版印刷版原版，其特征在于，其上设置有防水支撑体和图像接收层，其中，所述防水支撑体的表面的Bekk平滑度在900〜3000（秒/ 10cc）的范围内， 图像接收层含有氧化锌，粘合剂树脂和具有至少一个选自-CO 2 H，-SO 3 H和-PO 3 H 2的酸性基团的水溶性有机化合物，其能够与氧化锌或锌离子形成螯合化合物 。 直接式平版印刷版原版提供了平版印刷版，即使在静电转印由电子照相复印机形成的调色剂图像的情况下，也能产生具有清晰图像的印刷品。

公开(公告)号：US5624777A

公开(公告)日：1997-04-29

申请号：US256558

申请日：1994-09-12

申请人： Eiichi Kato ,  Hiroshi Tashiro ,  Akio Oda ,  Kazuo Ishii

发明人： Eiichi Kato ,  Hiroshi Tashiro ,  Akio Oda ,  Kazuo Ishii

IPC分类号： G03G5/05

CPC分类号： G03G5/0546 ,  G03G5/0589 ,  G03G5/0592

摘要： An electrophotographic lithographic printing plate precursor having a photoconductive layer containing a resin which contains a functional group capable of forming --COOH group and a functional group capable of forming at least one group selected from --SO.sub.3 H group, --SO.sub.2 H group and --PO.sub.3 H group and which has a crosslinking structure.Owing to the specific polar group in the resin, a lithographic printing plate which is free from the occurrence of background stain and has excellent oil-desensitivity and high printing durability is provided.

摘要翻译： PCT No.PCT / JP93 / 00023 Sec。 371日期1994年9月12日 102（e）1994年9月12日PCT PCT 1993年1月11日PCT公布。 公开号WO93 / 14447 日本1993年7月22日具有含有含有能够形成-COOH基的官能团的树脂的光电导层和能够形成选自-SO 3 H基，-SO 2 H基中的至少一个基团的官能团的电子照相平版印刷版原版， -PO 3 H基团，其具有交联结构。 由于树脂中的特定的极性基团，提供了没有背景污点的发生并且具有优异的油分离性和高的印刷耐久性的平版印刷版。

公开(公告)号：US06673435B1

公开(公告)日：2004-01-06

申请号：US09588952

申请日：2000-06-07

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B41N114

CPC分类号： B41C1/1066 ,  Y10T428/24355 ,  Y10T428/256 ,  Y10T428/257 ,  Y10T428/265

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon, an image-receiving layer comprising inorganic particles and a binder resin. The combination of an inorganic particles is made up of at least one kind of metal sulfide particle having an average particle size of sum 0.01 to 5 &mgr;m and at least one kind of particle which may be a metal oxide particle having an average particle size of sum 0.01 to 5 &mgr;m or a metal oxide hydrate having an average particle size of 0.01 to 5 &mgr;m. The binder resin is a complex composed of a resin containing a siloxane bond.

摘要翻译： 包括其上设置有防水支撑体的直接拉伸型平版印刷版原版，包含无机颗粒的图像接收层和粘合剂树脂。 无机颗粒的组合由至少一种平均粒径为0.01〜5μm的金属硫化物颗粒和至少一种可以是平均粒径为和的金属氧化物颗粒的颗粒组成 0.01〜5μm的平均粒径为0.01〜5μm的金属氧化物水合物。 粘合剂树脂是由含有硅氧烷键的树脂构成的络合物。

公开(公告)号：US06472055B1

公开(公告)日：2002-10-29

申请号：US09436807

申请日：1999-11-09

申请人： Hiroshi Tashiro ,  Eiichi Kato

发明人： Hiroshi Tashiro ,  Eiichi Kato

IPC分类号： B32B702

CPC分类号： B41C1/1058 ,  G03G13/28 ,  Y10T428/24942 ,  Y10T428/256

摘要： A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer, the image-receiving layer containing: at least one metal oxide hydrate having an average particle size of from 0.01 to 5 pm and comprising a metal atom selected from Mg, Al, Zn, Ge, Ti, Co, Zr, Sn, Fe, Cu, Ni, Pb, Pd, Cd, Mo, Cr, Ga, Mn, V, Ce and La; and a binder resin containing a complex comprising: a resin containing a siloxane bond in which a silicon atom is connected with an oxygen atom; and an organic polymer containing a group capable of forming a hydrogen bond with the resin containing a siloxane bond.

摘要翻译： 一种直接拉伸型平版印刷版原版，其特征在于，具有在其上设置有图像接收层的防水支撑体，所述图像接受层包含：至少一种平均粒径为0.01〜5μm的金属氧化物水合物， 选自Mg，Al，Zn，Ge，Ti，Co，Zr，Sn，Fe，Cu，Ni，Pb，Pd，Cd，Mo，Cr，Ga，Mn，V，Ce和La中的金属原子; 和含有复合体的粘合剂树脂，其包含：含有硅原子与氧原子连接的硅氧烷键的树脂; 和含有与含有硅氧烷键的树脂形成氢键的基团的有机聚合物。