公开(公告)号：US06630519B2

公开(公告)日：2003-10-07

申请号：US10168847

申请日：2002-09-27

申请人： Hirotama Fujimaru ,  Kenji Kadonaga ,  Kinya Nagasuna ,  Kenji Minami

发明人： Hirotama Fujimaru ,  Kenji Kadonaga ,  Kinya Nagasuna ,  Kenji Minami

IPC分类号： C08J912

CPC分类号： C08F2/32

摘要： This invention concerns a method for the production of a porous polymer from a water-in-oil type high internal phase emulsion (HIPE). By using an oil-soluble polymerization initiator as the polymerization initiator, the method for producing a porous polymer with outstanding characteristics in a very short period even when the porous polymer is produced from an HIPE exhibiting a viscosity of not more than 500 mPa second at the emulsion formation temperature or when the porous polymer to be produced possesses a number-average pore diameter of not less than 80 &mgr;m is provided.

摘要翻译： 本发明涉及从油包水型高内相乳液（HIPE）生产多孔聚合物的方法。 通过使用油溶性聚合引发剂作为聚合引发剂，即使在多孔性聚合物由HIPE生产时，在非常短的时间内也具有突出特性的多孔性聚合物的制造方法， 乳液形成温度或当要生产的多孔聚合物具有不小于80μm的数均孔径时。

公开(公告)号：US06797735B2

公开(公告)日：2004-09-28

申请号：US10332219

申请日：2003-01-03

申请人： Kinya Nagasuna ,  Kenji Kadonaga ,  Hirotama Fujimaru ,  Kozo Nogi ,  Kenji Minami

发明人： Kinya Nagasuna ,  Kenji Kadonaga ,  Hirotama Fujimaru ,  Kozo Nogi ,  Kenji Minami

IPC分类号： C08J928

CPC分类号： C08J9/28 ,  C08F2/32 ,  C08J2201/028 ,  C08J2201/0504 ,  C08J2333/06

摘要： A method of production is provided which is capable of efficiently producing in a very short period of time a porous polymer possessing a uniform foam structure and truly excelling in absorption properties and physical properties. It is a method for the production of a porous polymer, characterized by comprising (a) an emulsifying step for forming a water-in-oil type high internal phase emulsion (HIPE) by mixing and stirring an oil phase containing a polymerizing monomer component and a surfactant as essential components, (b) a shaping step for shaping the HIPE in a specific form, and (c) a polymerizing step for polymerizing the shaped HIPE and controlling the temperatures of the emulsion at the component steps (a)-(c) so that they may not produce a change exceeding 10° C. or controlling all the component steps so that they may proceed at temperatures of not lower than 80° C.

公开(公告)号：US06395792B1

公开(公告)日：2002-05-28

申请号：US09689350

申请日：2000-10-12

申请人： Kinya Nagasuna ,  Hirotama Fujimaru ,  Kenji Kadonaga ,  Kozo Nogi ,  Katsuhiko Sakamoto ,  Masazumi Sasabe ,  Kenji Minami

发明人： Kinya Nagasuna ,  Hirotama Fujimaru ,  Kenji Kadonaga ,  Kozo Nogi ,  Katsuhiko Sakamoto ,  Masazumi Sasabe ,  Kenji Minami

IPC分类号： C08J928

CPC分类号： C08J9/283 ,  C08F2/32 ,  C08J2201/028

摘要： An object of this invention is to provide a method for the production of a porous cross-linked polymer, which permits the polymerization (curing) of a water in oil type high internal phase emulsion (HIPE) in such an exceptionally brief time as not more than 30 minutes, preferably not more than 10 minutes without impairing the stability of the HIPE. The object of this invention mentioned above can be accomplished by a method for the production of a porous cross-linked polymer which comprises steps of mixing an oil phase containing a polymerizing monomer, a cross-linking monomer, and a surfactant as essential components with a water phase containing water as an essential component thereby obtaining a water in oil type high internal phase emulsion and heating said emulsion to a prescribed curing temperature thereby polymerizing the emulsion, wherein said emulsion is formed in a thickness of not more than 50 mm and the temperature-increasing rate of the emulsion is not less than 5° C./minute.

摘要翻译： 本发明的目的是提供一种生产多孔交联聚合物的方法，其允许在非常短的时间内将油包水型高内相乳液（HIPE）中的聚合（固化）不再多 超过30分钟，优选不超过10分钟，而不损害HIPE的稳定性。 上述本发明的目的可以通过生产多孔交联聚合物的方法来实现，该方法包括以下步骤：将含有聚合单体的油相，交联单体和表面活性剂作为必需组分混合， 水相作为必要成分，由此获得油包水型高内相乳液，并将所述乳液加热到规定的固化温度，从而使乳液聚合，其中所述乳液的形成厚度不大于50mm，温度 - 乳液的增加速度不低于5℃/分钟。

公开(公告)号：US06822010B2

公开(公告)日：2004-11-23

申请号：US10474950

申请日：2003-10-14

申请人： Hirotama Fujimaru ,  Hiroki Inoue ,  Kenji Kadonaga ,  Kinya Nagasuna

发明人： Hirotama Fujimaru ,  Hiroki Inoue ,  Kenji Kadonaga ,  Kinya Nagasuna

IPC分类号： C08J928

CPC分类号： C08J9/28 ,  C08F2/32 ,  C08J2201/028

摘要： A method for producing a porous material excelling in stability of preservation is produced. A method for the production of a porous material comprising a step for obtaining a porous polymer by polymerizing an HIPE containing a polymerizable monomer is disclosed, which method comprises a step for adding a compound capable of reacting with a polymerization initiator and/or a compound capable of reacting with an unsaturated double bond to said emulsion, said porous polymer and/or said porous material having a conversion of not less than 70%. According to this invention, it is made possible to produce a porous material excelling in stability in storage and to decrease the polymerization initiator and the residual monomer very simply.

摘要翻译： 制造出具有良好的保存稳定性的多孔材料的制造方法。 公开了一种生产多孔材料的方法，其包括通过聚合含有可聚合单体的HIPE获得多孔聚合物的步骤，该方法包括添加能够与聚合引发剂和/或化合物反应的化合物的步骤 与所述乳液的不饱和双键反应，所述多孔聚合物和/或所述多孔材料具有不小于70％的转化率。 根据本发明，可以制备出具有良好的储存稳定性的多孔材料，并且非常简单地降低聚合引发剂和残留单体。

公开(公告)号：US06274638B1

公开(公告)日：2001-08-14

申请号：US09712557

申请日：2000-11-14

申请人： Koichi Yonemura ,  Hiroshi Yamazaki ,  Masazumi Sasabe ,  Hirotama Fujimaru ,  Kinya Nagasuna

发明人： Koichi Yonemura ,  Hiroshi Yamazaki ,  Masazumi Sasabe ,  Hirotama Fujimaru ,  Kinya Nagasuna

IPC分类号： C08J928

CPC分类号： C08J9/283 ,  C08F2/32

摘要： This invention is targeted at providing a method for producing a porous cross-linked polymer material excelling in absorption properties and mechanical strength in a short period of time. In the production of a porous cross-linked polymer material from an HIPE, the method of this invention is characterized by comprising a step of polymerizing the HIPE till the bromine value thereof falls to not more than 25% of the value existing prior to the polymerization and a subsequent step of after curing the porous cross-linked polymer material by means of an active energy ray or a temperature higher than the polymerization temperature.

摘要翻译： 本发明的目的在于提供一种制造在短时间内具有优异的吸收性能和机械强度的多孔交联聚合物材料的方法。 在从HIPE生产多孔交联聚合物材料时，本发明的方法的特征在于包括使HIPE聚合直到其溴值下降到聚合之前存在的值的25％以下的步骤 以及随后通过活性能量射线或高于聚合温度的温度固化多孔交联聚合物材料的步骤。

公开(公告)号：US06187872B1

公开(公告)日：2001-02-13

申请号：US09051313

申请日：1998-04-06

申请人： Toru Yanase ,  Kazuki Kimura ,  Shin-ichi Fujino ,  Kinya Nagasuna ,  Kunihiko Ishizaki ,  Hirotama Fujimaru ,  Nobuyuki Harada

发明人： Toru Yanase ,  Kazuki Kimura ,  Shin-ichi Fujino ,  Kinya Nagasuna ,  Kunihiko Ishizaki ,  Hirotama Fujimaru ,  Nobuyuki Harada

IPC分类号： C08F812

CPC分类号： A61L15/60 ,  B01J20/26 ,  C08F8/00 ,  C08F8/44 ,  C08F2800/20 ,  C08F2810/20 ,  C08F220/06

摘要： A hydrogel polymer obtained by polymerizing a monomer component including acrylic acid (salt) is post-neutralized so that each of polymer particles derived from a polymer produced by neutralizing the hydrogel polymer has an allowable neutralization ratio. The polymer as obtained by neutralizing the hydrogel polymer is reacted with a crosslinking agent reactive to a functional group of the polymer. The allowable neutralization ratio, for example, is a neutralization ratio which is not lower, by not less than 20 mole percent, or more than, at least 55 mole percent, than an average neutralization ratio of a mass of the polymer particles, and the post-neutralization is carried out so that a number of polymer particles having a non-allowable neutralization ratio outside the allowable neutralization range is not more than 10 in 200 polymer particles, thus obtaining a water-absorbent agent having high absorbency under no applied pressure and high pressure wherein the amount of water soluble component is lower compared with the conventional water-absorbent agent and a change in pH of a swollen gel is small.

摘要翻译： 通过使包含丙烯酸（盐）的单体组分聚合而获得的水凝胶聚合物被后中和，使得通过中和水凝胶聚合物产生的聚合物衍生的各聚合物颗粒具有允许的中和比。 通过中和水凝胶聚合物获得的聚合物与与聚合物的官能团反应的交联剂反应。 例如，容许的中和比例是中和比，其比不到聚合物颗粒的质量的平均中和比不低于20摩尔％，或至多55摩尔％，而且 进行中和后，使得在200个聚合物粒子中，许多中和比例不超过允许中和比例的聚合物颗粒数不超过10个，从而获得在无施加压力下具有高吸收性的吸水剂， 其中水溶性成分的量与常规吸水剂相比较低，并且溶胀凝胶的pH变化很小。

公开(公告)号：US06323250B1

公开(公告)日：2001-11-27

申请号：US09712558

申请日：2000-11-14

申请人： Kenji Kadonaga ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masazumi Sasabe ,  Kazutomo Takahashi ,  Masuji Izubayashi

发明人： Kenji Kadonaga ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masazumi Sasabe ,  Kazutomo Takahashi ,  Masuji Izubayashi

IPC分类号： C08J928

CPC分类号： C08F2/32

摘要： An object of this invention is to provide a method for the production of a porous material by polymerizing a water-in-oil type high internal phase emulsion in a briefer time than a conventional technique without impairing the stability of the emulsion. The object of this invention can be accomplished by a method for the production of a porous material comprising a step of polymerizing a water-in-oil type high internal phase emulsion containing a polymerization initiator, wherein the polymerization initiator is a redox type initiator combining an oil-soluble oxidizing agent and a reducing agent, either of the oil-soluble oxidizing agent or the reducing agent is preparatorily added to form the emulsion, and thereafter the remainder of the reducing agent or the oil-soluble oxidizing agent is added to the emulsion to polymerize the added emulsion.

摘要翻译： 本发明的目的是提供一种通过在比传统技术更短的时间内将油包水型高内相乳液聚合而不损害乳液的稳定性来生产多孔材料的方法。 本发明的目的可以通过一种生产多孔材料的方法来实现，该方法包括使包含聚合引发剂的油包水型高内相乳液聚合的步骤，其中聚合引发剂是氧化还原型引发剂， 油溶性氧化剂和还原剂，油溶性氧化剂或还原剂中的任一种被预先加入以形成乳液，然后将剩余的还原剂或油溶性氧化剂加入到乳液中 以使所加入的乳液聚合。

公开(公告)号：US06395793B1

公开(公告)日：2002-05-28

申请号：US09712723

申请日：2000-11-14

申请人： Kenji Kadonaga ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masazumi Sasabe ,  Kazutomo Takahashi ,  Masuji Izubayashi

发明人： Kenji Kadonaga ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masazumi Sasabe ,  Kazutomo Takahashi ,  Masuji Izubayashi

IPC分类号： C08J928

CPC分类号： C08F2/32 ,  C08J2201/028

摘要： An object of this invention is to provide a method for the production of a porous material by polymerizing a water-in-oil type high internal phase emulsion in a briefer time than a conventional technique without impairing the stability of the emulsion. The object of this invention can be accomplished by a method for the production of a porous material comprising a step of polymerizing a water-in-oil type high internal phase emulsion containing a polymerization initiator, wherein the polymerization initiator is a redox type initiator combining a water-soluble oxidizing agent and a reducing agent, the reducing agent is preparatorily added to form the emulsion, and thereafter the water-soluble oxidizing agent is added to the emulsion to polymerize the added emulsion.

摘要翻译： 本发明的目的是提供一种通过在比传统技术更短的时间内将油包水型高内相乳液聚合而不损害乳液的稳定性来生产多孔材料的方法。 本发明的目的可以通过一种生产多孔材料的方法来实现，该方法包括使含有聚合引发剂的油包水型高内相乳液聚合的步骤，其中聚合引发剂是氧化还原型引发剂， 水溶性氧化剂和还原剂，预先添加还原剂以形成乳液，然后将水溶性氧化剂加入到乳液中以使所加入的乳液聚合。

公开(公告)号：US06730711B2

公开(公告)日：2004-05-04

申请号：US10149602

申请日：2002-06-13

申请人： Masazumi Sasabe ,  Kenji Kadonaga ,  Hiroki Inoue ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masatoshi Yoshida ,  Masuji Izubayashi ,  Kazutomo Takahashi

发明人： Masazumi Sasabe ,  Kenji Kadonaga ,  Hiroki Inoue ,  Akiko Mitsuhashi ,  Hirotama Fujimaru ,  Masatoshi Yoshida ,  Masuji Izubayashi ,  Kazutomo Takahashi

IPC分类号： C08J928

CPC分类号： C08F8/00 ,  C08F20/00

摘要： A method for the production of a porous cross-linked polymer material by the polymerization of an HIPE containing a cross-linking agent, characterized by the fact at least one species of the cross-linking agent is a compound having a double bond equivalent f not less than 120 g/mol. The cross-linking agent is preferred to be a compound possessed of an alkylene oxide moiety or a vinyl polymer containing not less than two polymerizing double bonds in the molecular unit. Thus, it is made possible to produce a porous cross-linked polymer material excellent in absorbency and flexibility, permit the HIPE to be polymerized in a short time, and therefore improve the efficiency of production.

摘要翻译： 通过含有交联剂的HIPE的聚合制备多孔交联聚合物材料的方法，其特征在于至少一种交联剂是具有双键当量f的化合物 小于120g / mol。 交联剂优选为具有烯化氧部分的化合物或在分子单元中含有不少于两个聚合双键的乙烯基聚合物。 因此，可以制造吸水性和柔软性优异的多孔交联聚合物材料，能够在短时间内使HIPE聚合，从而提高生产效率。

公开(公告)号：US08822373B2

公开(公告)日：2014-09-02

申请号：US12307922

申请日：2007-08-30

申请人： Hirotama Fujimaru ,  Eri Nagasawa ,  Masatoshi Nakamura ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Ryoko Tahara

发明人： Hirotama Fujimaru ,  Eri Nagasawa ,  Masatoshi Nakamura ,  Hiroyuki Ikeuchi ,  Makoto Nagasawa ,  Ryoko Tahara

IPC分类号： B01J20/26 ,  B01J20/30 ,  A61L15/24 ,  A61L15/60 ,  C08F120/06 ,  C08F220/06 ,  A61F13/53

CPC分类号： A61L15/60 ,  A61F2013/530481 ,  A61L15/24 ,  C08F120/06 ,  C08F220/06 ,  Y10T428/2982 ,  C08L33/02

摘要： A particulate water absorbing agent includes a polyacrylic acid and/or a salt thereof water absorbent resin as a main component, wherein the water absorbent resin includes α-hydroxycarboxylic acid and/or a salt thereof, and the absorbing agent satisfies a specific particle size distribution and a specific water absorbing performance, thereby solving the conventional problems. Further, a production method of the water absorbing agent is characterized in that α-hydroxycarboxylic acid and/or a salt thereof is added to (a) a monomer aqueous solution whose main component is acrylic acid and/or a salt thereof and which is being cross-linked and polymerized or (b) a hydrogel polymer after the polymerization. As a result, in the particulate water absorbing agent containing the water absorbent resin as a main component, it is possible to realize both excellent water absorbing performance and excellent coloring prevention effect. Further, it is possible to provide an absorbing article particulate water absorbing agent which is suitable for practical use.

摘要翻译： 颗粒状吸水剂包括聚丙烯酸和/或其盐类吸水性树脂作为主要成分，其中吸水性树脂包括α-羟基羧酸和/或其盐，并且吸收剂满足特定的粒度分布 和特定的吸水性能，从而解决了常规问题。 此外，吸水剂的制造方法的特征在于，在（a）主要成分为丙烯酸和/或其盐的单体水溶液中加入α-羟基羧酸和/或其盐，其为 交联并聚合，或（b）聚合后的水凝胶聚合物。 结果，在含有吸水性树脂作为主要成分的颗粒状吸水剂中，可以实现优异的吸水性能和优异的防着色效果。 此外，可以提供适合于实际应用的吸收性物品颗粒状吸水剂。