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公开(公告)号：US07129032B2
公开(公告)日：2006-10-31
申请号：US10969067
申请日：2004-10-21
CPC分类号： G03C1/49818 , G03C1/0051 , G03C1/08 , G03C1/46 , G03C5/17 , G03C2001/0056 , G03C2001/03552 , G03C2001/03558 , G03C2001/03594 , G03C2200/43
摘要： The invention provides a black and white photothermographic material including, on at least one surface of a support, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein 50% or more of the total projected area of the photosensitive silver halide grains is occupied by tabular grains having an aspect ratio of 2 or more, and at least one apex portion of each tabular grain has an epitaxial junction. An image forming method is also provided, the method including bringing the photothermographic material into close contact with a fluorescent intensifying screen containing a fluorescent substance, wherein 50% or more of emission light of the fluorescent substance has a wavelength of 350 nm to 420 nm, and applying X-ray exposure. The black and white photothermographic material has high sensitivity and is superior in image storability and raw stock storability.
摘要翻译： 本发明提供一种黑色和白色光热敏成像材料，其在至少一个载体表面上至少包含感光卤化银，非感光性有机银盐，还原剂和粘合剂，其中总计50％以上 感光卤化银颗粒的投影面积占据纵横比为2以上的片状颗粒，并且每个片状颗粒的至少一个顶点部分具有外延结。 还提供了一种图像形成方法，该方法包括使光热敏成像材料与含有荧光物质的荧光增强屏紧密接触，其中荧光物质的发射光的50％以上具有350nm至420nm的波长， 并应用X射线曝光。 黑白光热敏成像材料具有高灵敏度，图像保存性和原始储存性优异。
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公开(公告)号：US20060110691A9
公开(公告)日：2006-05-25
申请号：US10760496
申请日：2004-01-21
IPC分类号： G03C5/16
CPC分类号： G03C1/49845 , G03C1/04 , G03C1/49818 , G03C1/49827 , G03C1/49863 , G03C1/49881 , G03C7/30541 , G03C2005/166 , G03C2200/36 , G03C2200/39
摘要： A photothermographic material including an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on the same surface of a support, wherein the photothermographic material contains a compound having an adsorption group to silver halide and a reducing group, or a precursor of the compound, and satisfies one of the following conditions: 1) the photothermographic material contains a development accelerator; 2) the non-photosensitive organic silver contains silver behenate in an amount of not less than 80% by mole, and the binder has a glass transition temperature (Tg) of 45° C. or less; or 3) the photothermographic material contains at least one compound represented by the following formula (H); Q-(Y)n—C(Z1)(Z2)X wherein, in formula (H), Q represents an alkyl group, an aryl group or a heterocyclic group; Y represents a divalent linking group; n represents 0 or 1; Z1 and Z2 each independently represent a halogen atom; and X represents a hydrogen atom or an electron attracting group.
摘要翻译： 一种光热敏成像材料，其包括在载体的同一表面上至少含有感光卤化银，非感光性有机银盐，还原剂和粘合剂的成像层，其中光热敏成像材料含有具有吸附基团的化合物 卤化银和还原基团或化合物的前体，并且满足以下条件之一：1）光热敏成像材料含有显影促进剂; 2）非感光性有机银含有不小于80摩尔％的山嵛酸银，并且粘合剂的玻璃化转变温度（Tg）为45℃以下; 或3）光热照相材料含有至少一种由下式（H）表示的化合物; <？in-line-formula description =“In-line Formulas”end =“lead”？> Q-（Y） -C（Z 1） 其中，在式（H）中，Q表示烷基，芳基或芳基， 杂环基; Y表示二价连接基团; n表示0或1; Z 1和Z 2各自独立地表示卤素原子; X表示氢原子或吸电子基团。
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公开(公告)号：US20060035181A1
公开(公告)日：2006-02-16
申请号：US11209733
申请日：2005-08-24
IPC分类号： G03C1/00
CPC分类号： G03C1/49845
摘要： The present invention provides a photothermographic material, comprising a photosensitive silver halide, a non-photosensitive organic solvent salt, a reducing agent for a silver ion, and a binder on one face of a support, for being applied by using an organic solvent, the photothermographic material further comprising at least one compound selected from the group of compounds consisting of: a compound represented by the following general formula (1), a compound having a β-lactam ring, a compound having a group that is adsorptive to a silver halide and a group that reduces a silver halide and a precursor thereof:
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公开(公告)号：US5587279A
公开(公告)日：1996-12-24
申请号：US791402
申请日：1991-11-14
CPC分类号： G03C7/3022 , G03C1/035 , G03C1/04 , G03C1/28
摘要： A silver halide photographic emulsion which comprises silver halide grains having a silver chloride content of at least 60 mol % and an octatetracontahedral crystal form of the kind which is constructed of 48 triangular faces, every one of which contacts convexly with each of its two adjoining faces to form a line and concavely with its one adjoining face to form a line, with the grains being formed in the presence of a synthetic polymer peptizer which contains, as repeating units, units derived from a thioether linkage-containing ethylenically unsaturated monomer, in a mole fraction of from about 20 to 100 mole %, thereby achieving low fog and high sensitivity.
摘要翻译： 一种卤化银照相乳剂，其包含氯化银含量为至少60摩尔％的卤化银颗粒和由48个三角形面构成的八面体结晶形式，每个三角形面都与其两个邻接面中的每一个凸起接触 以形成一条线并且与其一个相邻的表面凹入以形成一条线，其中在合成聚合物胶溶剂的存在下形成晶粒，该合成聚合物胶溶剂包含作为重复单元的衍生自含硫醚键的烯属不饱和单体的单元， 摩尔分数为约20至100摩尔％，从而实现低雾和高灵敏度。
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公开(公告)号：US5342750A
公开(公告)日：1994-08-30
申请号：US51691
申请日：1993-04-23
CPC分类号： G03C1/09
摘要： A silver halide photographic material comprises a silver halide emulsion layer provided on a support. In the photographic material of the present invention, the silver halide emulsion layer contains a tellurium compound represented by the formula (I) or (II): ##STR1## in which each of R.sup.11 and R.sup.12 is --OR.sup.13, --NR.sup.14 R.sup.15, --SR.sup.16 or hydrogen; R.sup.11 and R.sup.12 may be combined with each other to form a heterocyclic ring; each of R.sup.21 and R.sup.22 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group, --OR.sup.23, --NR.sup.24 R.sup.25, --SR.sup.26 or hydrogen; R.sup.21 and R.sup.22 may be combined with each other to form a heterocyclic ring; each of X.sup.1 and X.sup.2 is oxygen, sulfur or .dbd.NR.sup.17 ; each of X.sup.3 and X.sup.4 is oxygen, sulfur or .dbd.NR.sup.27 ; each of R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, R.sup.23, R.sup.24, R.sup.25, R.sup.26 and R.sup.27 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group or hydrogen; R.sup.14 and R.sup.15 may be combined with each other to form a heterocyclic ring; and R.sup. 24 and R.sup.25 may be combined with each other to form a heterocyclic ring.
摘要翻译： 卤化银照相材料包括设置在载体上的卤化银乳剂层。 在本发明的照相材料中，卤化银乳剂层含有由式（I）或（II）表示的碲化合物：其中R11和R12各自为-OR13，-NR14R15，-SR16或 氢; R 11和R 12可以相互结合形成杂环; R 21和R 22各自为烷基，烯基，炔基，芳烷基，芳基或杂环基，-OR 23，-NR 24 R 25，-SR 26或氢; R 21和R 22可以相互结合形成杂环; X1和X2各自为氧，硫或= NR17; X3和X4各自为氧，硫或= NR27; R 13，R 14，R 15，R 16，R 17，R 23，R 24，R 25，R 26和R 27中的每一个是烷基，烯基，炔基，芳烷基，芳基或杂环基或氢; R 14和R 15可以相互结合形成杂环; 并且R 24和R 25可以彼此结合形成杂环。
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6.发明授权
公开(公告)号：US4914017A
公开(公告)日：1990-04-03
申请号：US62642
申请日：1987-06-16
申请人： Hiroyuki Mifune
发明人： Hiroyuki Mifune
CPC分类号： G03C1/09 , G03C1/015 , G03C1/025 , G03C1/12 , G03C2001/0152 , G03C2001/0158 , G03C2001/091 , G03C2200/04
摘要： A gold-sensitized silver halide emulsion of surface latent image type exhibits improved shelf stability while maintaining high sensitivity when at least 80% of the gold sensitizer is contained in the silver halide grain phase. A photographic silver halide light-sensitive material is prepared as comprising at least one emulsion layer which contains the improved silver halide emulsion.
摘要翻译： 当卤化银颗粒相中含有至少80％的金增感剂时，表面潜影型的金致敏卤化银乳剂显示出改善的储存稳定性，同时保持高灵敏度。 制备照相卤化银感光材料，其包含至少一个包含改进的卤化银乳剂的乳剂层。
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7.发明授权
公开(公告)号：US4863845A
公开(公告)日：1989-09-05
申请号：US82922
申请日：1987-08-06
申请人： Ashita Murai , Hiroyuki Mifune , Tatsuo Heki
发明人： Ashita Murai , Hiroyuki Mifune , Tatsuo Heki
CPC分类号： G03C1/48576 , Y10S430/141 , Y10S430/144
摘要： In an internal latent image type direct positive silver halide emulsion containing core/shell type silver halide grains wherein at least light-sensitive sites of the silver halide internal core which has been subjected to doping with metal ions or chemical sensitization, or both, is covered with a silver halide outer shell, the improvement wherein a photographic additive which is adsorbed on silver halide in said emulsion or interacts with silver ion, said additive being a compound which functions to change the crystal form or particle size of the silver halide grains in the case of the formation thereof or acts as a sensitizer or a sensitizing assistant in the case of chemically sensitizing the core particles but has a harmful influence on photographic properties if it remains after use of it, is deactivated by a deactivator prior to completion of the formation of said core/shell type silver halide grains or completion of surface chemical ripening of said grains. A process for producing the above internal latent image type direct positive silver halide emulsion is also disclosed.
摘要翻译： 在包含核/壳型卤化银颗粒的内部潜像型直接正卤化银乳剂中，其至少覆盖已经被金属离子掺杂或化学增感的卤化银内核的光敏部位或两者覆盖 具有卤化银外壳的改进，其中吸附在所述乳液中的卤化银上或与银离子相互作用的照相添加剂，所述添加剂是用于改变卤化银颗粒的结晶形式或粒度的化合物 形成的情况或作为敏化剂或敏化助剂，在对核心颗粒进行化学敏化的情况下，但如果在使用之后仍然对照相特性有影响，则在形成之前由钝化剂失活 的所述核/壳型卤化银颗粒或完成所述颗粒的表面化学成熟。 还公开了制备上述内部潜像型直接正卤化银乳剂的方法。
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公开(公告)号：US4568635A
公开(公告)日：1986-02-04
申请号：US574437
申请日：1984-01-27
摘要： A silver halide light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. The emulsion layer contains a silver halide prepared in the presence of a tetrasubstituted thiourea as a silver halide solvent and was hardened with a hardener containing a vinylsulfonyl group. Combined use of the tetrasubstituted thiourea and the hardener of the above-described kinds increases the storability of the light-sensitive material.
摘要翻译： 公开了一种卤化银感光材料，其包括其上设置有至少一个卤化银乳剂层的载体。 乳液层含有在四取代硫脲作为卤化银溶剂存在下制备的卤化银，并用含有乙烯基磺酰基的固化剂硬化。 四取代硫脲和上述种类的固化剂的组合使用增加了感光材料的保存性。
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公开(公告)号：US4469784A
公开(公告)日：1984-09-04
申请号：US423331
申请日：1982-09-24
申请人： Tatsuo Heki , Hiroyuki Mifune
发明人： Tatsuo Heki , Hiroyuki Mifune
CPC分类号： G03C1/015 , G03C2001/03535 , G03C2001/03558
摘要： A silver halide emulsion is disclosed which contains silver halide grains formed in the presence of a silver halide solvent. The solvent is a benzimidazole derivative having a hydrogen atom connected to the nitrogen atom at the 1st position thereof. By using this particular solvent a regular silver halide photographic emulsion having high sensitivity causing less fog is obtained. The silver halide solvent is unexpectedly advantageous in that can be almost completely desorbed from the silver halide grains by washing.
摘要翻译： 公开了一种卤化银乳剂，其含有在卤化银溶剂存在下形成的卤化银颗粒。 溶剂是具有与第1位置的氮原子连接的氢原子的苯并咪唑衍生物。 通过使用这种特定溶剂，获得具有高灵敏度的常规卤化银照相乳剂，其雾度较低。 卤化银溶剂出人意料地是有利的，因为可以通过洗涤几乎完全从卤化银颗粒中脱附。
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公开(公告)号：US4469783A
公开(公告)日：1984-09-04
申请号：US500707
申请日：1983-06-03
CPC分类号： G03C1/015
摘要： A silver halide photographic emulsion is described, which has halogen composition comprises at least 60 mole % of silver chloride, 40 mole % or less of silver bromide, and 5 mole % or less of silver bromide. Grain formation is performed in the presence of a silver halide solvent selected from the group consisting of tetrasubstituted thioureas and organic thioethers, and from 10.sup.-8 to 10.sup.-5 mole of a water-soluble iridium compound per mole of silver halide. This photographic emulsion exhibits high sensitivity and provides high contrast even by flash exposure. Thus, it is useful for the production of light-sensitive materials to be used in the production of printing plates in accordance with photographic engraving.
摘要翻译： 描述了卤化银照相乳剂，其具有包含至少60摩尔％的氯化银，40摩尔％或更少的溴化银和5摩尔％或更少的溴化银的卤素组合物。 在选自四取代硫脲和有机硫醚的卤化银溶剂存在下进行晶粒形成，每摩尔卤化银为10-8至10-5摩尔水溶性铱化合物。 这种摄影乳剂显示出高灵敏度，并且甚至通过闪光曝光提供高对比度。 因此，根据照相雕刻生产用于印刷版的感光材料是有用的。
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