公开(公告)号：US07527652B2

公开(公告)日：2009-05-05

申请号：US10571772

申请日：2004-09-10

申请人： Holger Buehler ,  Joaquim Henrique Teles ,  Gunther Pabst ,  Tilman Luedecke Taeger

发明人： Holger Buehler ,  Joaquim Henrique Teles ,  Gunther Pabst ,  Tilman Luedecke Taeger

IPC分类号： C14C1/00 ,  C07D301/12 ,  C07C323/02 ,  C07F11/00

CPC分类号： C07D407/04 ,  C07C323/12

摘要： Mixtures of (A) from 55 to 65 mol % of erythro-dithiol of formula erythro-IV: and (B) from 35 to 45 mol % of threo-dithiol of formula threo-IV or threo-IV′: and their corresponding alkali metal salts and ammonium salts, are useful for treating animal hides.

摘要翻译： （A）55至65摩尔％的赤藓-4-肟的赤式二硫醇和（B）35至45摩尔％的式Ⅳ-Ⅳ或钍-IV'的二硫代硫醇的混合物及其相应的碱 金属盐和铵盐可用于治疗动物皮肤。

公开(公告)号：US07250062B2

公开(公告)日：2007-07-31

申请号：US10531167

申请日：2003-10-14

申请人： Hans-Georg Lemaire ,  Tilman Luedecke Taeger ,  Gunther Pabst ,  Philippe Lamalle ,  Michael Breuer ,  Burkhard Kroeger ,  Thomas Subkowski

发明人： Hans-Georg Lemaire ,  Tilman Luedecke Taeger ,  Gunther Pabst ,  Philippe Lamalle ,  Michael Breuer ,  Burkhard Kroeger ,  Thomas Subkowski

IPC分类号： C14C1/06

CPC分类号： C14C1/065

摘要： The invention relates to a method for removing horn substances from animal skin. The method is characterized in that animal skins are treated in an aqueous bath containing between 0.05 and 5 wt. %, in relation to the weight of the salt, of at least one compound of general formula I or the corresponding alkali metallic salts or alkaline-earth metallic salts thereof or ammonium or phosphonium salts. The aqueous bath also comprises at least one compound which catalyses the hydrolysis of peptide compounds

摘要翻译： 本发明涉及从动物皮肤去除角质物质的方法。 该方法的特征在于动物皮肤在含有0.05至5wt。 至少一种通式I的化合物或其相应的碱金属盐或碱土金属盐或铵盐或鏻盐，相对于盐的重量计算。 水浴还包含至少一种催化肽化合物水解的化合物

公开(公告)号：US07404826B2

公开(公告)日：2008-07-29

申请号：US10513800

申请日：2003-05-19

申请人： Tilman Luedecke Taeger ,  Gunther Pabst ,  Philippe Lamalle ,  Stephan Hueffer ,  Stefan Schroeder

发明人： Tilman Luedecke Taeger ,  Gunther Pabst ,  Philippe Lamalle ,  Stephan Hueffer ,  Stefan Schroeder

IPC分类号： C14C1/00

CPC分类号： C14C1/06

摘要： Horny substances are removed from hides, pelts or skins of dead animals by treating the hides, pelts or skins in aqueous liquor with one or more compounds of the formula I or their corresponding alkali metal or alkaline earth metal salts or ammonium or phosphonium salts, the variables being defined as follows: R1 is selected from hydrogen and C1-C12-alkyl, unsubstituted or substituted by one or more S—H or O—H groups; X1 to X4 are identical or different and are selected from hydrogen, C1-C4-alkyl, O—H, S—H and N—HR2, R2 is hydrogen or C1-C12-alkyl or a C1-C4-Alkyl-C═O group, at least one radical X1 to X4 being S—H when R1 contains at least one sulfur atom and at least two radicals X1 to X4 being S—H when R1 contains no sulfur atom.

摘要翻译： 通过用一种或多种式I化合物或其相应的碱金属或碱土金属盐或铵盐或鏻盐处理含水液体中的皮革，皮毛或皮肤，从死皮的皮革，毛皮或皮肤中去除角质物质， 变量定义如下：R 1选自氢和C 1 -C 12 - 烷基，未被取代或被一个或多个SH取代 或OH基团; X 1至X 4相同或不同，并且选自氢，C 1 -C 4 - C 4 - 烷基 ，OH，SH和N-HR 2，R 2是氢或C 1 -C 12 - C 12 - 烷基 或C 1 -C 4 - 烷基-CO基团，至少一个X 1至X 4 - 基团， 当R 1含有至少一个硫原子时为SH，当R 1为至少两个X X 1至X 4时，SH 4为SH 不含硫原子。

公开(公告)号：US07354457B2

公开(公告)日：2008-04-08

申请号：US10511279

申请日：2003-05-02

申请人： Stephan Hueffer ,  Gunther Pabst ,  Tilman Luedecke Taeger ,  Stefan Schroeder ,  Gerhard Wolf

发明人： Stephan Hueffer ,  Gunther Pabst ,  Tilman Luedecke Taeger ,  Stefan Schroeder ,  Gerhard Wolf

IPC分类号： C14C3/08

CPC分类号： C07C45/72 ,  C14C3/16

摘要： Tanning agents can be prepared by reacting at least one aldehyde of formula I, with at least one further identical or different aldehyde of formula I, where Z is a single chemical bond, unsubstituted or substituted C1-C12-alkylene, unsubstituted or substituted C5-C12-cycloalkylene or unsubstituted or substituted C6-C14-arylene, the reaction being carried out in the presence of an acidic catalyst and in the presence of at least one further carbonyl compound of formula II where R1 to R4, independently of one another, are hydrogen, unsubstituted or substituted C1-C12-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C7-C13-aralkyl or unsubstituted or substituted C6-C14-aryl, with the proviso that, where Z is a single chemical bond or a radical without a-hydrogen atoms, at least one further aldehyde of the formula I, in which Z contains α-hydrogen atoms, or at least one further carbonyl compound of formula II is present.

摘要翻译： 鞣制剂可以通过使至少一种式I的醛与至少一种其它相同或不同的式I的醛反应来制备，其中Z是单个化学键，未取代或取代的C 1 -C 未取代或取代的C 1 -C 12 - 亚烷基，未取代或取代的C 5 -C 12 - 亚环烷基或未取代或取代的C 6 -C 该反应在酸性催化剂的存在下进行，并且在至少一种另外的式II的羰基化合物的存在下进行，其中R 1至R 4 - 彼此独立地为氢，未取代或取代的C 1 -C 12 - 烷基，未取代或取代的C 3 - 未取代或取代的C 7 -C 13 - 芳烷基或未取代或取代的C 6 - 其中Z是单一化学键或没有氢原子的基团，至少一个 存在式I的另外的醛，其中Z包含α-氢原子，或至少一种另外的式II的羰基化合物。

公开(公告)号：US07753964B2

公开(公告)日：2010-07-13

申请号：US10531178

申请日：2003-11-25

申请人： Stephan Hueffer ,  Stefan Schroeder ,  Juergen Carle ,  Thorsten Raedler ,  Volker Bach ,  Tilman Luedecke Taeger

发明人： Stephan Hueffer ,  Stefan Schroeder ,  Juergen Carle ,  Thorsten Raedler ,  Volker Bach ,  Tilman Luedecke Taeger

IPC分类号： C14C1/00 ,  C14C3/08

CPC分类号： C14C3/16 ,  C14C3/28

摘要： A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 μm or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45%, based on the total weight of the semifinished leather product.

摘要翻译： 通过使用无铬鞣剂和粘土矿物预处理从动物皮制造半成品皮革制品，其在50℃的水中搅拌30分钟，周向转子速度为5至 25m / s，数均粒径小于2μm，或双峰粒径分布为数均粒径小于0.5μm的第一精细分数，第二较粗颗粒的数均粒径 通过组合的激光衍射和光散射，通过根据ISO 13320-1的方法在每种情况下测定，小于5μm，第一细碎部分的比例为10至90重量％，并将 基于半成品​​皮革制品的总重量，预制动物的含水量为5至45％。