-
公开(公告)号：US07354457B2
公开(公告)日：2008-04-08
申请号：US10511279
申请日：2003-05-02
IPC分类号： C14C3/08
摘要： Tanning agents can be prepared by reacting at least one aldehyde of formula I, with at least one further identical or different aldehyde of formula I, where Z is a single chemical bond, unsubstituted or substituted C1-C12-alkylene, unsubstituted or substituted C5-C12-cycloalkylene or unsubstituted or substituted C6-C14-arylene, the reaction being carried out in the presence of an acidic catalyst and in the presence of at least one further carbonyl compound of formula II where R1 to R4, independently of one another, are hydrogen, unsubstituted or substituted C1-C12-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C7-C13-aralkyl or unsubstituted or substituted C6-C14-aryl, with the proviso that, where Z is a single chemical bond or a radical without a-hydrogen atoms, at least one further aldehyde of the formula I, in which Z contains α-hydrogen atoms, or at least one further carbonyl compound of formula II is present.
摘要翻译： 鞣制剂可以通过使至少一种式I的醛与至少一种其它相同或不同的式I的醛反应来制备，其中Z是单个化学键，未取代或取代的C 1 -C 未取代或取代的C 1 -C 12 - 亚烷基，未取代或取代的C 5 -C 12 - 亚环烷基或未取代或取代的C 6 -C 该反应在酸性催化剂的存在下进行，并且在至少一种另外的式II的羰基化合物的存在下进行，其中R 1至R 4 - 彼此独立地为氢，未取代或取代的C 1 -C 12 - 烷基，未取代或取代的C 3 - 未取代或取代的C 7 -C 13 - 芳烷基或未取代或取代的C 6 - 其中Z是单一化学键或没有氢原子的基团，至少一个 存在式I的另外的醛，其中Z包含α-氢原子，或至少一种另外的式II的羰基化合物。
-
公开(公告)号：US07404826B2
公开(公告)日：2008-07-29
申请号：US10513800
申请日：2003-05-19
IPC分类号： C14C1/00
CPC分类号： C14C1/06
摘要： Horny substances are removed from hides, pelts or skins of dead animals by treating the hides, pelts or skins in aqueous liquor with one or more compounds of the formula I or their corresponding alkali metal or alkaline earth metal salts or ammonium or phosphonium salts, the variables being defined as follows: R1 is selected from hydrogen and C1-C12-alkyl, unsubstituted or substituted by one or more S—H or O—H groups; X1 to X4 are identical or different and are selected from hydrogen, C1-C4-alkyl, O—H, S—H and N—HR2, R2 is hydrogen or C1-C12-alkyl or a C1-C4-Alkyl-C═O group, at least one radical X1 to X4 being S—H when R1 contains at least one sulfur atom and at least two radicals X1 to X4 being S—H when R1 contains no sulfur atom.
摘要翻译： 通过用一种或多种式I化合物或其相应的碱金属或碱土金属盐或铵盐或鏻盐处理含水液体中的皮革，皮毛或皮肤，从死皮的皮革，毛皮或皮肤中去除角质物质， 变量定义如下：R 1选自氢和C 1 -C 12 - 烷基，未被取代或被一个或多个SH取代 或OH基团; X 1至X 4相同或不同，并且选自氢，C 1 -C 4 - C 4 - 烷基 ，OH，SH和N-HR 2，R 2是氢或C 1 -C 12 - C 12 - 烷基 或C 1 -C 4 - 烷基-CO基团，至少一个X 1至X 4 - 基团， 当R 1含有至少一个硫原子时为SH，当R 1为至少两个X X 1至X 4时，SH 4为SH 不含硫原子。
-
公开(公告)号：US07753964B2
公开(公告)日：2010-07-13
申请号：US10531178
申请日：2003-11-25
申请人： Stephan Hueffer , Stefan Schroeder , Juergen Carle , Thorsten Raedler , Volker Bach , Tilman Luedecke Taeger
发明人： Stephan Hueffer , Stefan Schroeder , Juergen Carle , Thorsten Raedler , Volker Bach , Tilman Luedecke Taeger
摘要： A semifinished leather product is produced from an animal hide by pretanning with the use of a chromium-free tanning agent and of a clay mineral which, after stirring for 30 minutes in water at 50° C. at a circumferential rotor speed of from 5 to 25 m/s, has a number average particle diameter of less than 2 μm or a bimodal particle size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, a proportion of the first, finely divided fraction being from 10 to 90% by weight, and drying of the pretanned animal hide to a water content of from 5 to 45%, based on the total weight of the semifinished leather product.
摘要翻译： 通过使用无铬鞣剂和粘土矿物预处理从动物皮制造半成品皮革制品，其在50℃的水中搅拌30分钟，周向转子速度为5至 25m / s，数均粒径小于2μm，或双峰粒径分布为数均粒径小于0.5μm的第一精细分数，第二较粗颗粒的数均粒径 通过组合的激光衍射和光散射，通过根据ISO 13320-1的方法在每种情况下测定，小于5μm，第一细碎部分的比例为10至90重量％，并将 基于半成品皮革制品的总重量，预制动物的含水量为5至45％。
-
4.发明授权Use of C4-C6-polymercaptopolyols as regulators in solution or precipitation polymerization 失效在溶液或沉淀聚合中使用C4-C6聚合物多元醇作为调节剂公开(公告)号：US07084224B2
公开(公告)日：2006-08-01
申请号：US10887833
申请日：2004-07-12
申请人： Kathrin Michl , Tilman L. Taeger , Gunther Pabst , Philippe Lamalle , Stephan Hueffer , Stefan Schroeder
发明人： Kathrin Michl , Tilman L. Taeger , Gunther Pabst , Philippe Lamalle , Stephan Hueffer , Stefan Schroeder
IPC分类号： C08F2/38
摘要： The present invention relates to C4–C6-polymercaptopolyols as regulators in the free-radically initiated solution and precipitation polymerization of ethylenically unsaturated monomers.
摘要翻译： 本发明涉及作为自由基引发溶液中的调节剂和烯键式不饱和单体的沉淀聚合的C 4 -C 6 - 共聚物己内酯多元醇。
-
公开(公告)号：US20050125906A1
公开(公告)日：2005-06-16
申请号：US10511279
申请日：2003-05-02
申请人： Stephan Hüffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Gerhard Wolf
发明人： Stephan Hüffer , Gunther Pabst , Tilman Taeger , Stefan Schroeder , Gerhard Wolf
摘要： The invention relates to a tanning agent that is produced by reacting at least one aldehyde of general formula (I) with at least another identical or different aldehyde of formula (I), wherein the variables are defined as follows: Z is a single chemical bond, an optionally substituted C1-C12-alkyl, an optionally substituted C5-C12-cycloalkyl or an optionally substituted C6-C14-aryl, wherein the reaction is carried out in the presence of an acid catalyst and optionally in the presence of at least another carbonyl compound of formula (II), R1 to R4 represent, independent of one another, hydrogen, optionally substituted C1-C12-allyl, optionally substituted C3-C12-cycloalkyl, optionally substituted C7-C13-aralkyl or optionally substituted C6-C14-aryl, provided that at least another aldehyde of formula (I) in which the radical of Z contains α hydrogen atoms or at least another carbonyl compound of formula (I) is present when Z is a single chemical bond or a radical without any hydrogen atoms. The invention also relates to a method for the production of said tanning agent, to the utilization thereof as curing agent, particularly for pretannage, tannage or retannage of animal skins using the inventive tanning agents. The invention further relates to a powder active agent containing one or more of said inventive tanning agents, to a method for the production of said powder active agents and to the use thereof as curing agent and to leather produced using the inventive tanning agents or the inventive method.
摘要翻译： 本发明涉及通过使至少一种通式（I）的醛与至少另一相同或不同的式（I）的醛反应制备的鞣制剂，其中变量定义如下：Z是单一化学键 ，任选取代的C 1 -C 12 - 烷基，任选取代的C 5 -C 12 - 环烷基 或任选取代的C 6 -C 14 - 芳基，其中反应在酸催化剂的存在下进行，并且任选地在至少另外一种羰基化合物存在下进行 式（II）中，R 1至R 4彼此独立地表示氢，任选取代的C 1 -C 4烷基， 12-烯丙基，任选取代的C 3 -C 12 - 环烷基，任选取代的C 7 -C 13 - 或其任选取代的C 6 -C 14 - 芳基，条件是至少另一种式（I）的醛，其中th 当Z是单个化学键或没有任何氢原子的基团时，Z的基团含有α氢原子或至少另外一个式（I）的羰基化合物。 本发明还涉及一种用于生产所述鞣剂的方法，其用作固化剂，特别是使用本发明的鞣剂对动物皮肤进行预处理，鞣制或回火处理。 本发明还涉及含有一种或多种所述本发明的鞣剂的粉末活性剂，用于制备所述粉末活性剂的方法及其作为固化剂的用途，以及使用本发明的鞣剂或本发明制备的皮革 方法。
-
6.发明授权Adducts based on cyclic compounds and the use thereof as tanning agents and curing agents 失效基于环状化合物的加合物及其作为鞣剂和固化剂的用途公开(公告)号：US07410504B2
公开(公告)日：2008-08-12
申请号：US10543495
申请日：2004-01-21
申请人： Stephan Hueffer , Oliver Reese , Walter Gramlich , Stefan Schroeder , Guenter Scherr , Volker Bach
发明人： Stephan Hueffer , Oliver Reese , Walter Gramlich , Stefan Schroeder , Guenter Scherr , Volker Bach
IPC分类号： C14C3/18 , C07D309/30
CPC分类号： C07D307/32 , C07D309/30 , C14C3/18 , C14C9/02
摘要： Adducts are obtained by reacting carbonyl compounds of the formula I where R1 and R2 are as defined, with cyclic compounds of the formula II where X is selected from oxygen, sulfur and N—R8, R3-R8 are as defined, and n is an integer from 1 to 4, which adducts are useful as tanning agents and preservatives.
摘要翻译： 通过使式I的羰基化合物（其中R 1，R 2和R 2）定义与式II的环状化合物反应，其中X选自氧，硫 和NR 8，R 3 -R 8如上所定义，n为1至4的整数，该加合物可用作鞣制 代理和防腐剂。
-
公开(公告)号：US20060101584A1
公开(公告)日：2006-05-18
申请号：US10524047
申请日：2003-08-14
IPC分类号： C14C3/00
摘要： A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 μm or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.
摘要翻译： 提出了用于无铬或铬鞣制剂的制剂，其包含粘土矿物，其在50℃下在水中剧烈搅拌30分钟后具有小于2μm的数均粒径或双峰尺寸分布 具有数均粒径小于0.5μm的第一细碎部分和数均粒径小于5μm的第二粗纱部分，通过组合的方法按照ISO 13320-1的方法确定 激光衍射和光散射，第一细分的份数为10至90重量％，以及一种或多种下列一种或多种物质：有机聚合物，醛鞣剂，砜鞣剂， 树脂鞣剂，苯酚鞣剂，加脂剂，植物鞣剂，染料和颜料。
-
公开(公告)号：US07771489B2
公开(公告)日：2010-08-10
申请号：US10524047
申请日：2003-08-08
摘要： A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 μm or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.
摘要翻译： 提出了一种用于无铬或铬鞣制剂的制剂，其包括粘土矿物，其在50℃下在水中剧烈搅拌30分钟后具有小于2μm的数均粒径或双峰尺寸分布 具有数均粒径小于0.5μm的第一细碎部分和数均粒径小于5μm的第二较粗部分，其分别通过根据ISO 13320-1的方法通过组合确定 激光衍射和光散射，第一细分的份数为10至90重量％，以及一种或多种下列一种或多种物质：有机聚合物，醛鞣剂，砜鞣剂， 树脂鞣剂，苯酚鞣剂，加脂剂，植物鞣剂，染料和颜料。
-
公开(公告)号：US20050210596A1
公开(公告)日：2005-09-29
申请号：US10505448
申请日：2003-03-12
摘要： A process for the production of semifinished products and intermediates in the production of leather using one or more organic polyelectrolytes comprises at least one of the following steps: (a) Addition of one or more polyelectrolytes and from 0 to 0.7% by weight, based on the salted weight, of lime immediately before or during liming, (b) addition of one or more polyelectrolytes before or during deliming, (c) addition of one or more polyelectrolytes before or during bating, (d) addition of one or more polyelectrolytes and a total of from 0 to 3% by weight, based on the pelt weight, of alkali metal or alkaline earth metal salt immediately before or in the pickle.
摘要翻译： 使用一种或多种有机聚电解质在生产皮革中生产半成品和中间体的方法包括以下步骤中的至少一个步骤：（a）加入一种或多种聚电解质和0至0.7重量％，基于 （b）在剥离之前或期间添加一种或多种聚电解质，（c）在或之前加入一种或多种聚电解质，（d）加入一种或多种聚电解质和 基于皮毛重量的0-3重量％的碱金属或碱土金属盐在紧挨之前或之中。
-
公开(公告)号：US20070022541A1
公开(公告)日：2007-02-01
申请号：US10529744
申请日：2003-10-14
IPC分类号： C14C1/06
CPC分类号： C14C1/065
摘要： Leather is produced by a process comprising at least two of the following process steps A) to D): A) use of one or more polyelectrolytes in the production of semifinished products or intermediate products, comprising the addition of one or more polyelectrolytes in at least one of the steps (a) to (d) (a) together with from 0 to 1.5% by weight, based on the salted weight, of lime, immediately before or during liming, (b) before or during deliming, (c) before or during bating, (d) together with, altogether, from 0 to 3% by weight, based on the pelt weight, of alkali metal or alkaline earth metal salt, immediately before or during pickling; B) treatment of the hides during liming in an aqueous liquor with one or more compounds of the formula B.1 or the corresponding alkali metal, alkaline earth metal, ammonium or phosphonium salts thereof, R10 and X1 to X4 having the meanings stated in the description, with the proviso that at least two mercapto groups are present in the compound or the compounds B.1; C) use of degreasing agents of the formula C.1 for degreasing pelts, hides or other intermediate stages and semifinished products in leather production, n and R16 to R21 having the meanings stated in the description; D) tanning with the use of a tanning agent which can be prepared by reacting at least one aldehyde of the formula D.1, with at least one further identical or different aldehyde of the formula D.1 in the presence of an acidic catalyst and optionally in the presence of at least one further carbonyl compound of the formula D.2 Z and R22 to R25 having the meanings stated in the description, with the proviso that, when Z corresponds to a single chemical bond or a radical without α-hydrogen atoms, at least one further aldehyde of the formula D.1, in which Z contains α-hydrogen atoms, or at least one further carbonyl compound of the formula D.2 is present.
-
-
-
-
-
-
-
-
-
搜索结果
49 条记录 (耗时 0.039 秒)
