专利检索 ap:("Hubert H. Thigpen" OR "Wallace E. Taylor" OR "Arthur W. Schnizer") AND inv:"Wallace E. Taylor" 第 1 页

1.

发明授权
Peracetic acid oxidation of amines to amine oxides 失效
标题翻译：胺对氨氧化物的酸性氧化

公开(公告)号：US3957873A

公开(公告)日：1976-05-18

申请号：US183648

申请日：1971-09-24

申请人： Hubert H. Thigpen , Wallace E. Taylor , Arthur W. Schnizer

发明人： Hubert H. Thigpen , Wallace E. Taylor , Arthur W. Schnizer

IPC分类号： C07C291/04 , C07C87/29 , C07C87/54

CPC分类号： C07C291/04

摘要： An improved process for oxidizing an amine to the corresponding amine oxide with peracetic acid comprises carrying out the reaction in a distillation column, using as oxidant the gaseous mixture of peracetic acid and acetaldehyde resulting from the vapor-phase oxidation of acetaldehyde with oxygen. The amine is introduced in liquid form into the upper portion of the distillation column while the gaseous mixture of peracetic acid and acetaldehyde is simultaneously introduced into an intermediate location in the column. Reaction takes place within the column, with acetic acid and acetaldehyde being withdrawn as vapor from the top while a liquid comprising the amine oxide product is recovered from the base.