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公开(公告)号：US10473325B2
公开(公告)日：2019-11-12
申请号：US15535004
申请日：2015-12-01
发明人： Florent Guillou , Beatrice Fischer , Tiago Sozinho , Ann Cloupet , Stephane Bertholin , Mahdi Yazdanpanah , Hélène Stainton
IPC分类号： F23D3/40 , F23C10/01 , B01J8/24 , F23C10/00 , F23C10/20 , B01J8/06 , C01B3/40 , F23C10/04 , F23C10/22
摘要： The invention relates to a plant and to a method for chemical looping oxidation-reduction combustion of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic pre-reforming of the feed is performed in a pre-reforming zone comprising a fixed reforming catalyst, while benefiting from a heat transfer between the reduction or oxidation zone of the chemical loop and the pre-reforming zone adjoining the reduction or oxidation zone. Pre-reforming zone (130) and oxidation zone (110) or pre-reforming zone (130) and reduction zone (120) are thus thermally integrated within the same reactor (100) while being separated by at least one thermally conductive separation wall (140).
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2.发明申请METHOD AND DEVICE FOR CHEMICAL LOOP COMBUSTION OF LIQUID HYDROCARBON FEEDSTOCKS 审中-公开液化石油气化学循环燃烧方法与装置公开(公告)号：US20160061442A1
公开(公告)日：2016-03-03
申请号：US14783480
申请日：2014-03-11
CPC分类号： F23C10/01 , B01J8/0055 , B01J8/007 , B01J8/28 , B01J8/32 , B01J8/388 , B01J2208/00513 , B01J2208/00902 , F23C6/04 , F23C10/005 , F23C10/10 , F23C10/22 , F23C2206/101 , F23C2900/10003 , F23C2900/99008 , Y02E20/346
摘要： The invention relates to a method for chemical looping (CLC) oxidation-reduction combustion of liquid hydrocarbon feedstocks carried out in a fluidized bed, wherein liquid hydrocarbon feedstock (2) is partly vaporized on contact with a hot solid (1) in form of particles so as to form a partly vaporized liquid feedstock and to form coke on said solid (1), prior to contacting partly vaporized liquid feedstock (19) with a redox active mass in form of particles (12) so as to achieve combustion of partly vaporized liquid feed (19). Hot solid particles (1) used to carry the coke can notably form a second fluidized-bed particle circulation loop, the first one being the circulation loop of the oxygen-carrying redox active mass (12) circulating between the oxidation and combustion reactors, thus allowing coke-carrying particles (1) to be recycled to the process.
摘要翻译： 本发明涉及在流化床中进行的液体烃原料的化学循环（CLC）氧化 - 还原燃烧的方法，其中液体烃原料（2）在与颗粒形式的热固体（1）接触时部分蒸发 以在部分蒸发的液体原料（19）与颗粒（12）形式的氧化还原活性物质接触之前，在所述固体（1）上形成部分蒸发的液体原料并形成焦炭，以实现部分蒸发的 液体进料（19）。 用于承载焦炭的热固体颗粒（1）可以显着地形成第二流化床颗粒循环回路，第一个是在氧化和燃烧反应器之间循环的携氧氧化还原活性物质（12）的循环回路，因此 允许将焦炭携带的颗粒（1）再循环到该方法中。
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3.发明授权公开(公告)号：US11885488B2
公开(公告)日：2024-01-30
申请号：US17261509
申请日：2019-07-18
发明人： Stephane Bertholin , Ann Cloupet , Florent Guillou , Airy Tilland , Benjamin Amblard , Sina Tebianian , Mahdi Yazdanpanah
摘要： The invention relates to a CLC plant for the combustion of solid hydrocarbon feedstocks generating particles of unburnt residues, comprising a solid/solid separator above the combustion reactor in order to efficiently separate the particles of the oxygen-carrying solid from the particles of unburnt residues contained in the gas/solid mixture (14) exiting from the combustion reactor. The chamber (1) of the solid/solid separator, the combustion reactor and the inlet (2) for the gas/solid mixture (14) of the chamber have a parallelepiped shape. The inlet (2) is equipped at its top with means (3) for distribution of said gas/solid mixture in the chamber which extend over the entire length of the inlet, improving the solid/solid separation.
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公开(公告)号：US10317072B2
公开(公告)日：2019-06-11
申请号：US14783480
申请日：2014-03-11
IPC分类号： F23D3/40 , F23C10/01 , B01J8/28 , B01J8/32 , B01J8/38 , B01J8/00 , F23C10/00 , F23C6/04 , F23C10/10 , F23C10/22
摘要： The invention is a method for chemical looping (CLC) oxidation-reduction combustion of liquid hydrocarbon feedstocks carried out in a fluidized bed. A liquid hydrocarbon feedstock (2) is partly vaporized on contact with a hot particle solid (1) to form a partly vaporized liquid feedstock and to form coke on the solid prior to contacting partial vaporized liquid feedstock (19) with a redox active mass of particles (12) to achieve combustion of the partially vaporized liquid feed (19). The hot solid particles can notably be from a second fluidized-bed particle circulation loop.
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公开(公告)号：US11913640B2
公开(公告)日：2024-02-27
申请号：US17278399
申请日：2019-09-13
发明人： Airy Tilland , Benjamin Amblard , Sina Tebianian , Ann Cloupet , Florent Guillou , Stephane Bertholin , Mahdi Yazdanpanah
CPC分类号： F23C10/10 , F23C9/003 , F23J15/022 , F23C2206/10 , F23C2900/10001 , F23C2900/99008 , F23J2217/60
摘要： The present invention relates to a device and a method for chemical looping combustion, for which the end of the intake duct (4) opening out within the chamber of the separator (1) is inclined with respect to a horizontal plane (H).
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公开(公告)号：US10473326B2
公开(公告)日：2019-11-12
申请号：US15535010
申请日：2015-12-01
发明人： Mahdi Yazdanpanah , William Pelletant , Tiago Sozinho , Stephane Bertholin , Hélène Stainton , Ann Cloupet , Florent Guillou
IPC分类号： F23C10/01 , F23C10/02 , F23C10/20 , F23C10/22 , B01J8/26 , C01B3/44 , F23C10/04 , F23C99/00 , B01J8/18
摘要： In a method and a plant for chemical looping oxidation-reduction combustion (CLC) of a gaseous hydrocarbon feed, for example natural gas essentially containing methane, catalytic reforming of the feed is performed within the reduction zone where combustion of the feed is conducted on contact with an oxidation-reduction active mass in form of particles. The reforming catalyst comes in form of untransported fluidized particles within the reduction zone. The catalyst thus confined in the reduction zone does not circulate in the CLC loop.
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公开(公告)号：US10215400B2
公开(公告)日：2019-02-26
申请号：US14897866
申请日：2014-06-12
发明人： Florent Guillou , Tiago Sozinho , Heloise Dreux , Helene Stainton
IPC分类号： F23D3/40 , F23C10/01 , F23C10/00 , F23C10/22 , F23C10/26 , F23C10/04 , F23C10/20 , F23C10/28 , F23D1/00
摘要： The invention relates to a method and to a device for chemical looping combustion CLC of a solid hydrocarbon feed wherein it is proposed to inject the solid hydrocarbon feed so as to limit any occurrence of sticking of the feed to the walls of the injection device. The solid feed is fed into a conveying zone operating under fluidized bed conditions and opening into a combustion reactor. A fluidization gas is injected into this conveying zone while controlling the flow of gas in such a way that the superficial velocity of the gas in the conveying zone is higher than the terminal velocity of the solid hydrocarbon feed particles and the terminal velocity of solid particles present in the combustion reactor, and while controlling the fluidization gas temperature in such a way that the temperature in the conveying zone is less than or equal to 500° C.
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8.发明授权公开(公告)号：US10184657B2
公开(公告)日：2019-01-22
申请号：US15319603
申请日：2015-06-18
摘要： The invention relates to a process and to a unit for chemical looping oxidation-reduction combustion of a hydrocarbon feed, wherein heat exchanges are controlled through a level variation of a dense fluidized bed of active mass particles in an external heat exchanger (E1, E2), positioned on a transport line carrying particles circulating between a reduction zone (210) and an oxidation zone (200) for the particles in the chemical loop. The bed level variation is allowed through controlled application of a pressure drop on a fluidization gas outlet in the heat exchanger, said pressure drop being compensated by the level variation of an active mass particle bed in a reservoir zone provided on the particle circuit in the chemical loop.
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9.发明申请CHEMICAL-LOOPING COMBUSTION METHOD WITH DILUTE PHASE REMOVAL OF ASHES AND FINES IN THE OXIDATIONZONE AND PLANT USING SAME 有权化学循环燃烧方法，使用相同的氧化剂和植物进行相位去除和去除灰分公开(公告)号：US20140335461A1
公开(公告)日：2014-11-13
申请号：US14361755
申请日：2012-10-25
申请人： TOTAL SA , IFP Energies nouvelles
CPC分类号： F23C10/01 , F23C10/005 , F23C10/08 , F23C10/24 , F23C10/26 , F23C2900/10003 , F23C2900/99008 , Y02E20/346
摘要： The invention relates to a method for chemical-looping combustion of a hydrocarbon-containing feedstock, comprising: contacting oxygen-carrying material particles coming from a reduction zone R0 with an oxidizing gas stream in a reactive oxidation zone R1, separating the fly ashes, the fines and the oxygen-carrying material particles within a mixture coming from zone R1 in a dilute phase separation zone S2, the driving force required for dilute phase elutriation in S2 being provided by the oxidizing gas stream from reactive oxidation zone R1. Optionally, partitioning is carried out in a dedusting zone S4, then possibly in a dense phase elutriation separation zone S5. The invention also relates to a chemical-looping combustion plant allowing said method to be implemented.
摘要翻译： 本发明涉及一种用于含烃原料的化学循环燃烧的方法，包括：将来自还原区R0的携氧材料颗粒与反应性氧化区R1中的氧化气流接触，分离飞灰， 细粉和在稀相分离区S2中来自区域R1的混合物中的载氧材料颗粒，S2中稀相淘析所需的驱动力由来自反应性氧化区R1的氧化气流提供。 任选地，在除尘区S4中进行分配，然后可能在密相淘析分离区S5中进行分配。 本发明还涉及允许实现所述方法的化学循环燃烧设备。
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公开(公告)号：US11534742B2
公开(公告)日：2022-12-27
申请号：US17255801
申请日：2019-06-21
IPC分类号： B01J31/02 , B01J20/283 , B01J20/284 , B01J37/02 , B01J37/20 , B01J37/28 , C10G49/02
摘要： The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one group VIII element, at least one group VIB element and at least one organic compound of formula (I) in which R1 is a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, R2 and R3 are chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, X is chosen from an oxygen atom or a sulfur atom except when R2 and R3 represent a hydrogen atom, in which case X is an oxygen atom, Y is chosen from a hydrogen atom, a hydrocarbon-based radical comprising from 1 to 12 carbon atoms or a unit —C(O)R4, R4 being chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms.
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