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1.发明授权
公开(公告)号：US4599193A
公开(公告)日：1986-07-08
申请号：US622582
申请日：1984-06-20
CPC分类号： H01B1/04 , C01B31/02 , C04B35/524 , D01F11/14 , D01F9/21
摘要： A highly electroconductive carbonaceous material is obtained by pyrolysis in an inert atmospherea conjugated polymer represented by the general formula--R--CH.dbd.CH).sub.n wherein R is an aromatic hydrocarbon group which forms a consecutive carbon to carbon conjugated system with the vinylene group, and n is an integer of at least 2, at a temperature above 400.degree. C., or an aromatic polyimide at a temperature of 2000.degree. C. or above. Further, a highly electroconductive composition is obtained by treating the carbonaceous material mentioned above with a dopant.
摘要翻译： 通过在惰性气氛中热解由通式-R-CH = CH）n表示的共轭聚合物，其中R是与亚乙烯基形成连续碳 - 碳共轭体系的芳族烃基，得到高导电性碳质材料， 在400℃以上，n为2以上的整数，或在2000℃以上的温度下为芳香族聚酰亚胺。 此外，通过用掺杂剂处理上述碳质材料来获得高导电性组合物。
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公开(公告)号：US4791177A
公开(公告)日：1988-12-13
申请号：US911216
申请日：1986-09-24
CPC分类号： C08J5/18 , C04B35/524 , C08G61/02 , H01B1/04 , C08J2349/00
摘要： A high strength and modulus conjugated polymer film which comprises as its principal constitutive unit a conjugated polymer structure represented by the general formula:--R--CH.dbd.CH.sub.nwherein R is an aromatic hydrocarbon group having 6 to 20 carbon atoms which forms a consecutive carbon to carbon conjugated system with vinylene group, and n is an integer of 5 to 50,000, and has a tensile strength of 15 kg/mm.sup.2 or more and an elastic modulus of 350 kg/mm.sup.2 or more, and a highly electroconductive pyrolyzed product thereof.
摘要翻译： 一种高强度和模量的共轭聚合物膜，其包含作为其主要构成单元的由以下通式表示的共轭聚合物结构：-R-CH = CH n，其中R是具有6至20个碳原子的芳族烃基，其形成连续的碳 碳共轭体系和亚乙烯基，n为5〜50,000的整数，拉伸强度为15kg / mm 2以上，弹性模量为350kg / mm 2以上，高导电性热解产物。
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公开(公告)号：US4626588A
公开(公告)日：1986-12-02
申请号：US747221
申请日：1985-06-21
CPC分类号： C08J5/18 , C04B35/524 , C08G61/02 , H01B1/04 , C08J2349/00
摘要： A high strength and modulus conjugated polymer film which comprises as itsrincipal constitutive unit a conjugated polymer structure represented by the general formula:--R--CH.dbd.CH).sub.nwherein R is an aromatic hydrocarbon group having 6 to 20 carbon atoms which forms a consecutive carbon to carbon conjugated system with vinylene group, and n is an integer of 5 to 50,000, and has a tensile strength of 15 kg/mm.sup.2 or more and an elastic modulus of 350 kg/mm.sup.2 or more, and a highly electroconductive pyrolyzed product thereof.
摘要翻译： 一种高强度和模量共轭聚合物膜，其包含作为其主要构成单元的由以下通式表示的共轭聚合物结构：-R-CH = CH）n，其中R是具有6至20个碳原子的芳族烃基，其形成连续的 具有亚乙烯基的碳 - 碳共轭体系，n为5〜50,000的整数，拉伸强度为15kg / mm 2以上，弹性模量为350kg / mm 2以上，高导电性热分解产物为 。
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4.发明授权
公开(公告)号：US4528118A
公开(公告)日：1985-07-09
申请号：US602534
申请日：1984-04-20
摘要： A highly electroconductive conjugated polymer composition which comprises a polymer having as the principal constitutive unit thereof a conjugated polymer structure --R.sub.1 --CH.dbd.CH).sub.m, wherein m is an integer satisfying the equation 2.ltoreq.m.ltoreq.n, obtained by subjecting to elimination of sulfonium salt from the polyelectrolyte of sulfonium salt having the general formula ##STR1## wherein R.sub.1 represents a group which forms a consecutive carbon to carbon conjugated system together with the adjacent vinylene group formed by the dehydrogenation of the group >CH--CH.sub.2 --; R.sub.2 and R.sub.3 each represent a hydrocarbon radical having 1 to 20 carbon atoms; X represents a counter ion; and n represents an integer larger than 2, and a dopant.
摘要翻译： 一种高导电性共轭聚合物组合物，其包含具有共轭聚合物结构-R1-CH = CH）m的主成分单元的聚合物，其中m为满足式2的整数，其通过 从具有通式为“IMAGE”的锍盐的聚电解质中除去锍盐，其中R 1表示与通过基团脱氢反应形成的相邻亚乙烯基一起形成连续的碳 - 碳共轭体系的基团> CH-CH 2 - ; R2和R3各自表示具有1至20个碳原子的烃基; X表示抗衡离子; n表示大于2的整数，和掺杂剂。
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5.发明授权
公开(公告)号：US5053166A
公开(公告)日：1991-10-01
申请号：US013628
申请日：1987-02-11
CPC分类号： C08G61/123 , C08G61/128 , H01B1/127 , H01B1/128 , H01M4/60
摘要： A poly(hetero-arylene vinylene) containing, as its major constituent unit, a repeating unit represented by the general formula ##STR1## (wherein X is a sulfur or oxygen atom), which is obtained by subjecting a sulfonium salt represented by the general formula ##STR2## (wherein X has the same definition as given above, R.sub.1 and R.sub.2 are independently a hydrocarbon group of 1 to 10 carbon atoms, and A.sup.- is a counter ion) to condensation polymerization using an alkali to obtain a precursor polymer, and subjecting the precursor polymer to stretching and orientation and then to a treatment for sulfonium salt elimination or subjecting the precursor polymer in one step to stretching and orientation and to a treatment for sulfonium salt elimination, as well as a highly conductive composition thereof.
摘要翻译： 作为其主要构成单元的含有由通式（IMAGE）表示的重复单元（其中，X为硫或氧原子）的聚（异亚芳基亚乙烯基），其为通式 （其中X具有与上述相同的定义，R 1和R 2独立地为1至10个碳原子的烃基，A-为抗衡离子）以使用碱进行缩聚以获得前体聚合物， 并对前体聚合物进行拉伸和取向，然后进行锍盐消除处理或一步法对前体聚合物进行拉伸和取向，以及对锍盐消除的处理以及其高导电性组合物。
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6.发明授权Process for producing stretched molded articles of conjugated polymers and highly conductive compositions of said polymers 失效用于制备共轭聚合物的拉伸模塑制品和所述聚合物的高导电性组合物的方法
公开(公告)号：US4868284A
公开(公告)日：1989-09-19
申请号：US95825
申请日：1987-09-10
CPC分类号： H01B1/128 , C08G61/123 , C08G61/128 , H01B1/127 , H01M4/60
摘要： A process for producing a stretched molded article of a conjugated polymer,hich comprises subjecting a polymer precursor having a repeating unit represented by the general formula (I) ##STR1## (wherein R.sub.1 is a group which forms a C--C conjugated system together with a vinylene group which is formed upon the dehydrogenation of the >CH--Ch.sub.2 -- group; and R.sub.2 is a group which is to be eliminated from the alpha-position carbon of the >CH--CH.sub.2 -- group simultaneously with the elimination of one of the hydrogen atoms bonding to the beta-position carbon of the >CH--Ch.sub.2 -- group) to stretching in the swelling state and then subjecting the stretched precursor polymer to elimination of the R.sub.2 group, and a conductive composition of the stretched molded article of the conjugated polymer, comprising the comjugated polymer and a dopant as essential components.
摘要翻译： 一种共轭聚合物的拉伸成型体的制造方法，其特征在于，对具有由通式（I）表示的重复单元的聚合物前体（I）（其中R1是形成CC共轭体系的基团） 具有在> CH-CH 2 - 基团的脱氢时形成的亚乙烯基; R2是从> CH-CH 2 - 基团的α-位置碳排除的基团，同时消除 与> CH-CH 2 - 基团的β位碳结合的氢原子）在溶胀状态下拉伸，然后使拉伸的前体聚合物消除R2基团，并将拉伸的成型体的导电组合物 共轭聚合物，其包含共轭聚合物和作为必需组分的掺杂剂。
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公开(公告)号：US4438262A
公开(公告)日：1984-03-20
申请号：US429282
申请日：1982-09-30
IPC分类号： C08B11/155 , C08B31/12 , C08B37/00 , C08B31/08 , C08B37/02
CPC分类号： C08B31/12 , C08B11/155 , C08B37/0033
摘要： Highly dielectric organic compounds can be obtained by cyanoethylating a dihydroxyalkylate of a water-soluble polysaccharide or a derivative thereof with acrylonitrile.
摘要翻译： 通过将水溶性多糖或其衍生物的二羟基烷基酯与丙烯腈氰基化，可以得到高介电有机化合物。
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8.发明授权Process for improving semipermeable membranes by treating with protic acids or inorganic salts 失效通过用质子酸或无机盐处理来改善半透膜的方法
公开(公告)号：US4268662A
公开(公告)日：1981-05-19
申请号：US17326
申请日：1979-03-05
申请人： Takezo Sano , Takatoshi Shimomura , Ichiki Murase
发明人： Takezo Sano , Takatoshi Shimomura , Ichiki Murase
IPC分类号： B01D20060101 , B01D71/42 , C08F6/00 , C08F20/44 , C08J20060101 , C08J7/14
CPC分类号： B01D71/42 , B01D67/009
摘要： A process for improving the performances of semipermeable membranes which comprise an acrylonitrile polymer containing 40 to 100% by mole of acrylonitrile and have a bubble point of more than 0.1 kg/cm.sup.2, by dipping said membranes in an aqueous solution containing inorganic salts and/or protic acids.
摘要翻译： 通过将所述膜浸渍在含有无机盐和/或其中的无机盐的水溶液中，提高包含含有40-100％（摩尔）丙烯腈并且具有大于0.1kg / cm 2的泡点的丙烯腈聚合物的半透膜性能的方法 质子酸。
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公开(公告)号：US4163725A
公开(公告)日：1979-08-07
申请号：US761904
申请日：1977-01-24
IPC分类号： C08J7/00 , B01D71/68 , B29C59/14 , C08G75/20 , C08L81/06 , D06M14/18 , C08J3/24 , C08J3/28 , C08J7/10
CPC分类号： B01D71/68 , B01D67/0013 , B01D67/009 , B29C59/14 , C08L81/06 , D06M14/18 , B29K2081/00 , B29K2105/24 , B29L2031/755
摘要： A method for the preparation of semipermeable membrane which comprises exposing porous shaped articles of polysulfone to a plasma.The resulting semipermeable membrane is very useful for separating substances by reverse osmosis or ultrafiltration.
摘要翻译： 一种制备半透膜的方法，其包括将聚砜的多孔成形制品暴露于等离子体中。
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公开(公告)号：US5376730A
公开(公告)日：1994-12-27
申请号：US853741
申请日：1992-06-05
CPC分类号： C08G81/027 , C08G81/00
摘要： There are provided a thermoplastic graft copolymer comprising, as main chain, a polymer having a glass transition temperature of 10.degree. C. or below and, as side chain, an aromatic oligomer having a flow temperature of 100.degree. C. or above; and its preparation process, especially a process wherein an aromatic oligomer containing 50% or more of the structural units represented by the following formula (I): ##STR1## wherein X is O or S; and Ar is ##STR2## wherein R.sup.1 and R.sup.2 are alkyl group of 1-3 carbon atoms or phenyl group, and p and q are an integer of 0-2.The graft copolymer of this invention can be used as a thermal resistant plastic elastomer for heat-resisting hoses, seals, automobile materials, etc.
摘要翻译： PCT No.PCT / JP90 / 01592 Sec。 371日期：1992年6月5日 102（e）日期1992年6月5日PCT 1990年12月6日PCT PCT。 出版物WO91 / 09074 日期：1991年6月27日。提供了一种热塑性接枝共聚物，其包含作为主链的玻璃化转变温度为10℃或更低的聚合物，并且作为侧链具有流动温度为100℃的芳族低聚物 C.或以上; 特别是其中含有50％以上由下式（I）表示的结构单元的芳族低聚物的方法：其中X为O或S;其中X为O或S; 并且Ar是
，其中R1和R2是1-3个碳原子的烷基或苯基，p和q是0-2的整数。 本发明的接枝共聚物可用作耐热软管，密封件，汽车材料等的耐热塑料弹性体。
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