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公开(公告)号:US20140004351A1
公开(公告)日:2014-01-02
申请号:US14016975
申请日:2013-09-03
申请人: Ilse VAN CASTEREN , Gerardus Cornelis OVERBEEK , Ronald TENNEBROEK , Tijs NABUURS , Richard George COOGAN
发明人: Ilse VAN CASTEREN , Gerardus Cornelis OVERBEEK , Ronald TENNEBROEK , Tijs NABUURS , Richard George COOGAN
IPC分类号: C09D133/14
CPC分类号: C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要: An aqueous solution coating composition comprising an autoxidisable polyvinyl polymer having ≧20% of fatty acid residue by weight of polymer; Tg from −60 to +15° C.; acid value of 15 to 75 mg KOH/g, Mw from 2500 to 100000 g/mol; polydispersity ≦30, said composition having ≦25% co-solvent by weight of solids, ≧30% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译: 一种水溶液涂料组合物,其包含具有≥20重量%的脂肪酸残基的聚合物的可自动氧化的聚乙烯基聚合物; Tg从-60到+ 15℃。 酸值为15至75mg KOH / g,Mw为2500至100000g / mol; 多分散性为30,所述组合物具有25重量%的固体重量的共溶剂,≥30重量%组合物的固体; 所述组合物当以具有透光值形式的涂层的形式时,所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上浇铸的膜之间的20°角的光泽差。
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公开(公告)号:US20130225724A1
公开(公告)日:2013-08-29
申请号:US13864062
申请日:2013-04-16
申请人: Gerardus Cornelis OVERBEEK , Ilse van CASTEREN , Ronald TENNEBROEK , Jelle Bernardus Otto van der WERF
发明人: Gerardus Cornelis OVERBEEK , Ilse van CASTEREN , Ronald TENNEBROEK , Jelle Bernardus Otto van der WERF
IPC分类号: C09D133/14
CPC分类号: C09D133/14 , C08F8/14 , C08F8/44 , C08F220/28 , C08F220/32 , C08F2810/30 , C08F2810/50 , C09D133/068 , Y10T428/31855 , C08F120/06 , C08F2220/325 , C08F220/14 , C08F2220/1825 , C08F212/08
摘要: There is described (pref. non-adhesive) coating compositions (which may be either water or solvent borne) that comprise an autoxidisable vinyl polymer, the autoxidisable polymer having a vinyl polymer backbone 25% to 75% by wt of the autoxidisable polymer; fatty acid residue 25% to 75% by wt of the autoxidisable polymer; Tg from −60° C. to +20° C., Mw from 3500 to 50000 g/mol; and polydispersity from 2 to 10; the autoxidisable polymer obtained by a process of: (A) polymerising ethylenically unsaturated vinyl monomers comprising: at least one epoxy functional vinyl monomer 15% to 100% by wt total monomers in (A); 0 to 85% of at least one other ethylenically unsaturated vinyl monomer, (preferably other than styrenic monomers) by wt total monomers in (A); (B) reacting the epoxy functional polymer from (A) with fatty acids having an average iodine value from 30 to 250 g I2/100 g fatty acid; where composition has: a) a opt. co-solvent content 40% by wt of the composition; b) a solids content either 30% (aqueous) 60% (solvent based) by wt of the composition, the composition as a coating film having a telegraphing value of less than 10 gloss units (difference between an initial smooth gloss minus an initial rough gloss of the film).
摘要翻译: 描述了包含可自动氧化的乙烯基聚合物的(优先非粘性)涂料组合物(其可以是水或溶剂载体),所述可自动氧化聚合物具有25重量%至75重量%的可自动氧化聚合物的乙烯基聚合物主链; 脂肪酸残基25%至75%重量的可自动氧化聚合物; Tg为-60℃至+ 20℃,Mw为3500至50000g / mol; 多分散性为2〜10; 通过以下方法获得的可自动氧化聚合物:(A)烯键式不饱和乙烯基单体的聚合,包括:(A)中至少一种15重量%至100重量%的单体的至少一种环氧官能乙烯基单体; 0至85%的(A)中的总单体的至少一种其它烯属不饱和乙烯基单体(优选不同于苯乙烯类单体); (B)使来自(A)的环氧官能聚合物与平均碘值为30-250g I2 / 100g脂肪酸的脂肪酸反应; 其中组合有:a)选择。 共溶剂含量为组合物的40重量% b)固体含量为组合物重量的30%(水性)60%(溶剂基),作为涂膜的组合物具有小于10个光泽单位的透印值(初始平滑光泽度减去初始粗糙度之间的差异 膜的光泽)。
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公开(公告)号:US20140011041A1
公开(公告)日:2014-01-09
申请号:US14017990
申请日:2013-09-04
IPC分类号: C09D137/00
CPC分类号: C09D137/00 , C08F8/14 , C08F8/44 , C08F120/06 , C08F212/08 , C08F220/28 , C08F220/32 , C08F2220/325 , C08F2810/30 , C08F2810/50 , C08J5/18 , C09D139/06 , Y10T428/31938
摘要: An aqueous emulsion coating composition comprising an autoxidisable vinyl oligomer having ≧20 wt % of unsaturated fatty acid residue; Tg from −50 to +15° C.; Mw from 2,500 to 40,000 g/mol; polydispersity from 2 to 12, said composition having ≦15% co-solvent by weight of solids, ≦13% NMP by weight of solids ≧38% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译: 一种水性乳液涂料组合物,其包含具有> = 20重量%的不饱和脂肪酸残基的可自动氧化的乙烯基低聚物; Tg为-50〜+ 15℃。 Mw为2,500至40,000g / mol; 多分散性为2至12,所述组合物具有按固体重量计占15%的共溶剂,固体重量的13%NMP =固体重量的组合物重量的38% 所述组合物当以具有透光值形式的涂层的形式时,所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上铸造的膜之间的20°角的光泽差。
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公开(公告)号:US20130296486A1
公开(公告)日:2013-11-07
申请号:US13936025
申请日:2013-07-05
申请人: Ronald TENNEBROEK , Gerardus Cornelis OVERBEEK , Franciscus Adrianus Cornelis BERGMAN , Mourad AABICH , Richard George COOGAN , Roel Johannes Marinus SWAANS
发明人: Ronald TENNEBROEK , Gerardus Cornelis OVERBEEK , Franciscus Adrianus Cornelis BERGMAN , Mourad AABICH , Richard George COOGAN , Roel Johannes Marinus SWAANS
IPC分类号: C09D177/12
CPC分类号: C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要: An aqueous coating composition comprising an autoxidisable polyester resin having ≧30 wt % of fatty acid residues; a Tg in the range of from −60° C. to +35° C.; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; said composition having a co-solvent content less that 15 wt % by weight of total composition; a solids content >30 wt %; and when a film, a telegraphing value of less than 20 gloss units.
摘要翻译: 一种水性涂料组合物,其包含具有> = 30重量%脂肪酸残基的可自动氧化的聚酯树脂; Tg在-60℃至+ 35℃的范围内。 酸值大于15mg KOH / g且小于75mg KOH / g; 在2500至100,000g / mol范围内的Mw; 所述组合物的共溶剂含量小于总组合物的15重量%; 固体含量> 30wt%; 而当一部电影,电报值小于20光泽单位。
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