公开(公告)号：US06222073B1

公开(公告)日：2001-04-24

申请号：US09600267

申请日：2000-07-03

申请人： Jürgen Herwig ,  Matthias Beller ,  Claudia Breindl ,  Harald Trauthwein ,  Elisabeth Eichberger ,  Anton Eichberger

发明人： Jürgen Herwig ,  Matthias Beller ,  Claudia Breindl ,  Harald Trauthwein ,  Elisabeth Eichberger ,  Anton Eichberger

IPC分类号： C07C20900

CPC分类号： C07C213/00 ,  C07C209/60 ,  C07C211/48 ,  C07C217/84

摘要： Process for the preparation of an N-arylethylaniline of the formula (I) Ar—N(R1)2-n(CHR2CHR3Ar′)n  (I) by reacting an aromatic olefin of the formula (II) Ar′CR3=CHR2  (II) with an aniline of the formula (III) Ar—N(R1)2-n(H)n  (III) in an inert solvent in the presence of at least one basic catalyst selected from the group consisting of alkali metal alcoholates and alkaline earth metal alcoholates or alkali metal amides and alkaline earth metal amides, where, in the formulae (I) to (III), Ar and Ar′, independently of one another, are an aryl radical selected from the group consisting of the fused and nonfused C6-C22-aromatics and of the fused or nonfused C5-C22heteroaromatics which have at least one nitrogen, oxygen or sulfur atom in the ring; R1, R2 and R3, independently of one another, are a hydrogen atom, a C1-C8-alkyl radical or an aryl radical Ar; and n is the number 1 or 2.

摘要翻译： 通过使式（II）的芳族烯烃与式（III）的苯胺在惰性溶剂中在至少一种选自以下的碱式催化剂的存在下反应制备式（I）的N-芳基乙基苯胺的方法： 由碱金属醇化物和碱土金属醇化物或碱金属氨化物和碱土金属酰胺组成的组中，其中在式（I）至（III）中，Ar和Ar'彼此独立地为选自 由稠合和未填充的C 6 -C 22芳族化合物和在环中具有至少一个氮，氧或硫原子的稠合或未稠合的C 5 -C 22杂原子取代基组成的组; R 1，R 2和R 3彼此独立地是 氢原子，C1-C8-烷基或芳基Ar; andn是数字1或2。