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1.发明授权Blocked photographically useful compounds for use with peroxide-containing processes 失效用于含过氧化物的工艺的封闭的有用的化合物
公开(公告)号：US5538834A
公开(公告)日：1996-07-23
申请号：US342983
申请日：1994-11-21
IPC分类号： G03C1/43 , C07C303/36 , C07C303/38 , C07C311/05 , G03C7/30 , G03C7/305 , G03C7/407
CPC分类号： C07C303/36 , C07C303/38 , G03C7/302 , G03C7/30511 , Y10S430/144 , Y10S430/156 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A method is disclosed for developing an image in a photographic element comprising a support, a silver halide emulsion containing an imagewise distribution of developable silver halide grains, and a blocked photographically useful compound comprising a photographically useful group and a blocking group capable of releasing the photographically useful group upon processing the photographic element in the presence of a peroxide, wherein the blocking group comprises an electrophilic group which is solely capable of undergoing a nucleophilic displacement reaction, the electrophilic group being bonded directly or through a releasable timing group to the photographically useful group, with the proviso that when the photographically useful group is a development inhibitor, the blocking group is bonded to the photographically useful group through at least one releasable timing group. The method comprises the step of contacting the photographic element with a processing solution comprising a peroxide.
摘要翻译： 公开了一种用于在照相元件中显影图像的方法，该照相元件包括载体，含有可显影卤化银颗粒的成像分布的卤化银乳剂，以及包含摄影有用的基团和能够照相地释放的封闭基团的封闭照相用化合物 在过氧化物存在下处理照相元件的有用基团，其中所述封闭基团包括仅能够进行亲核置换反应的亲电子基团，所述亲电子基团直接键合或通过可释放定时基团键合至照相用的基团 条件是当照相有用的基团是显影抑制剂时，封闭基团通过至少一个可释放定时基团与照相用组合键合。 该方法包括使照相元件与包含过氧化物的处理溶液接触的步骤。
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公开(公告)号：US5240821A
公开(公告)日：1993-08-31
申请号：US810232
申请日：1991-12-19
CPC分类号： G03C7/30541 , G03C7/30511 , G03C7/388 , Y10S430/16
摘要： A dispersion comprising solid particles of a developer precursor having the structureCD--(T).sub.m --Sin whichCD is a silver halide color developer,T is a timing group,m is an integer from 0 to 6, andS is a blocking group,and a vehicle in which the solid particles are insoluble, is disclosed. The dispersion can be incorporated in a photographic element.
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公开(公告)号：US5256525A
公开(公告)日：1993-10-26
申请号：US810944
申请日：1991-12-19
CPC分类号： G03C1/42 , G03C7/30511 , G03C7/407 , Y10S430/144 , Y10S430/16
摘要： A photographic element is disclosed including a support bearing at least one photographic silver halide emulsion layer and at least one non-photosensitive layer between the emulsion layer and the support, wherein the non-photosensitive layer comprises at least one blocked developing agent.
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4.发明授权
公开(公告)号：US5470688A
公开(公告)日：1995-11-28
申请号：US250146
申请日：1994-05-27
CPC分类号： G03C8/10 , G03C8/4013 , Y10S430/159
摘要： In accordance with this invention a heat-developable photographic color diffusion transfer element is provided, where this element comprises a dimensionally stable support and one or more layers comprising radiation sensitive silver halide, an organic silver salt oxidizing agent, a reducing agent, a methine-dye releasing compound, and a binder, wherein said methine-dye is heat diffusible in said element, and wherein said methine-dye releasing compound is of the structureCp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.
摘要翻译： 根据本发明，提供了一种可热显影的照相彩色扩散转移元件，其中该元件包括尺寸稳定的支撑体和一个或多个包含辐射敏感卤化银，有机银盐氧化剂，还原剂，次甲基 - 染料释放化合物和粘合剂，其中所述次甲基染料在所述元件中是可热扩散的，并且其中所述次甲基染料释放化合物具有结构Cp-LM（I），其中Cp是在与 二价连接基团L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来 。
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5.发明授权Heat image separation with phenolic thermal solvents and dye releasing couplers 失效用酚类热溶剂和染料释放成色剂进行热图像分离
公开(公告)号：US5512410A
公开(公告)日：1996-04-30
申请号：US323967
申请日：1994-10-17
CPC分类号： G03C8/4033 , G03C8/10 , G03C8/4066
摘要： An aqueous-developable photographic color diffusion transfer element comprising one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, a dye-receiving layer intermediate said support and dye-releasing coupler containing layers, a stripping layer intermediate said dye-receiving layer and any layers containing silver halide or dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, wherein said dye-releasing coupler is of the structureCp--L--DyewhereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L--Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and such that said Dye radical is subsequently released from the --L--Dye group;where said stripping layer contains a stripping agent; andwherein said thermal solvent has the structure I: ##STR1## wherein (a) Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, and Z.sub.5 are substituents, the Hammet sigma parameters of Z.sub.2, Z.sub.3, and Z.sub.4 sum to give a total, .SIGMA., of at least -0.28 and less than 1.53;(b) the calculated logP for I is greater than 3 and less than 10, is disclosed.
摘要翻译： 一种含水显影照相色彩扩散转移元件，包括一个且仅一维稳定的载体和一个或多个包含辐射敏感卤化银的层，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂，染料 接收层介于所述支持和释放染料的成色剂层之间，所述染料接收层和包含卤化银或染料释放成色剂的任何层的剥离层和亲水性粘合剂，其中所述染料在所述粘合剂中热扩散，并且热 溶剂，其中所述染料释放成色剂具有结构Cp-L-Dye，其中Cp是在与二价连接基团L的偶联位置取代的成色剂基团; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且使得所述染料自由基随后从-L-染料基团中释放; 其中所述剥离层包含剥离剂; 并且其中所述热溶剂具有以下结构I：其中（a）Z 1，Z 2，Z 3，Z 4和Z 5为取代基，Z 2，Z 3和Z 4的Hammetσ参数相加， SIGMA至少为-0.28且小于1.53; （b）公开了I的计算logP大于3并小于10。
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公开(公告)号：US5455140A
公开(公告)日：1995-10-03
申请号：US250145
申请日：1994-05-27
CPC分类号： G03C8/10 , G03C8/4013
摘要： An aqueous-developable photographic color diffusion transfer element is disclosed where this element comprises one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a methine-dye releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said methine-dye releasing coupler is of the structure (I)Cp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.Also disclosed in this invention is a diffusion transfer process for forming a color photographic image comprising the steps of:exposing said element to actinic radiation; processing said element by immersing said element in an external aqueous bath containing color developer of the primary amine type;washing said element;drying said element to remove the imbibed water; andheating said element to effect dye diffusion transfer to an image receiving layer.
摘要翻译： 公开了一种含水显影照相色彩扩散转移元件，其中该元件包括一个且仅一维稳定的载体，以及包含辐射敏感卤化银的一层或多层，用于促进染料通过亲水性粘合剂的热扩散的热溶剂， 染料释放成色剂和亲水性粘合剂，其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述次甲基染料释放成色剂具有结构式（I）Cp-LM（I），其中Cp是取代基 与二价连接基团的偶联位置L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来 。 本发明还公开了用于形成彩色照相图像的扩散转移方法，包括以下步骤：将所述元件暴露于光化辐射; 通过将所述元件浸入含有伯胺型彩色显影剂的外部水浴中来处理所述元件; 洗涤元素; 干燥所述元件以除去吸收的水; 并加热所述元件以进行染料扩散转移到图像接收层。
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公开(公告)号：US5356750A
公开(公告)日：1994-10-18
申请号：US993580
申请日：1992-12-21
CPC分类号： G03C8/4033 , G03C8/10 , G03C8/4066
摘要： An aqueous-developable photographic color diffusion transfer element comprising a single dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said dye-releasing coupler is of the structureCp--L-DyewhereCp is a cyan dye forming radical, magenta dye forming radical, yellow dye forming radical, black dye forming radical, or colorless product forming radical, said Cp being substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L-Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent is disclosed.
摘要翻译： 含水显影照相色彩扩散转移元件包括单尺寸稳定的载体和一层或多层包含辐射敏感的卤化银，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂和亲水性粘合剂， 其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述染料释放成色剂具有结构Cp-L-Dye，其中Cp是形成自由基的青色染料，形成自由基的品红色染料，形成自由基的黄色染料，黑色染料 形成自由基或无色产物形成基团，所述Cp在偶联位置被二价连接基团L取代; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时偶联。
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8.发明授权Nanoporous and microporous solvogels and nanolatexes by microemulsion polymerization 失效纳米孔和微孔溶胶凝胶和纳升酯通过微乳液聚合公开(公告)号：US07759401B2
公开(公告)日：2010-07-20
申请号：US11689866
申请日：2007-03-22
申请人： Feng Yan , John Texter
发明人： Feng Yan , John Texter
摘要： The present invention relates to microemulsions of immiscible fluids stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C. The invention also relates to composite materials comprising a copolymer of ethylenically reactive species, wherein one of the species is a reactive ionic liquid surfactant having a melting point less than 80° C., and wherein the material also comprises non-reactive Class I fluid. The invention further relates to methods for synthesizing the composite materials comprising preparing a microemulsion of immiscible Class I fluid and Class II fluid stabilized by reactive ionic liquid surfactant wherein the ionic liquid surfactant has a melting point less than 80° C., and polymerizing the microemulsion to form a composite material.
摘要翻译： 本发明涉及由反应性离子液体表面活性剂稳定的不混溶流体的微乳液，其中离子液体表面活性剂的熔点低于80℃。本发明还涉及包含烯属反应性物质的共聚物的复合材料，其中物种之一 是具有低于80℃的熔点的反应性离子液体表面活性剂，并且其中所述材料还包含非反应性I类流体。 本发明还涉及用于合成复合材料的方法，包括制备不混溶的I类流体的微乳液和通过反应性离子液体表面活性剂稳定的II类流体，其中离子液体表面活性剂具有低于80℃的熔点，并使微乳液聚合 以形成复合材料。
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9.发明授权Hydrogen bond donating/accepting thermal solvents for image separation systems 失效供氢/接受用于图像分离系统的热溶剂的氢键
公开(公告)号：US5843618A
公开(公告)日：1998-12-01
申请号：US73821
申请日：1993-06-08
IPC分类号： G03C8/40
CPC分类号： G03C8/402 , Y10S430/156
摘要： An aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element is disclosed, wherein said element comprises radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer according to formula (I) ##STR1## wherein AH is a hydrogen bond donating group with an aqueous pK.sub.a value for proton loss of greater than 6; L.sup.1 and L.sup.2 are each independently divalent linking groups consisting of groups of 1 to 12 atoms or are independently absent; m is 1, 2, or 3; Q comprises a group of 2 to 15 carbon atoms selected from the group consisting of aromatic rings, alkyl chains, alkyl rings, or ring-chain combinations, optionally substituted with substituents, Z, consisting of alkyl groups or halogens; B is a hydrogen bond accepting group with an aqueous pK.sub.a value for proton gain of less than 6; n is 1 or 2; the groups AH and B cannot hydrogen bond to form a ring of either 5 or 6 atoms; R is an alkyl, aryl and alkylaryl group of from 1 to 18 carbon atoms; the calculated log of the octanol/water partition coefficient (clogP) is greater than 3 and less than 10.
摘要翻译： 公开了含水可显影的显色照相可热转印非水性染料扩散转印照相材料，其中所述元件包括辐射敏感卤化银，一种提供染料的化合物，其在所述颜料反应反应时形成或释放可热转移的图像染料 与伯胺展开剂，亲水性粘合剂和热溶剂的氧化产物的化合物，用于促进根据式（I）的非水扩散转移。其中AH是具有水性的氢键供体基团 质子损失的pKa值大于6; L1和L2各自独立地为由1至12个原子的基团组成的二价连接基团或独立地不存在; m为1,2或3; Q包括选自芳基环，烷基链，烷基环或环 - 链组合的2至15个碳原子的基团，任选被取代基Z取代，Z由烷基或卤素组成; B是具有小于6的质子增益的pKa值的氢键接受基团; n为1或2; 基团AH和B不能氢键形成5或6个原子的环; R是1至18个碳原子的烷基，芳基和烷基芳基; 辛醇/水分配系数（clogP）的计算对数大于3且小于10。
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公开(公告)号：US5605785A
公开(公告)日：1997-02-25
申请号：US412252
申请日：1995-03-28
申请人： John Texter , David A. Czekai
发明人： John Texter , David A. Czekai
CPC分类号： G03C7/388 , G03C1/005 , Y10S430/156
摘要： A process for forming a nanocrystalline dispersion of a photographically useful compound in a continuous phase comprising the steps of:providing a nanoamorphous dispersion of said photographically useful compound in said continuous phase, andannealing said nanoamorphous dispersion to transform the physical state of said chemical compound therein to a crystalline physical state and to thereby obtain a nanocrystalline dispersion is disclosed.
摘要翻译： 一种在连续相中形成摄影有用化合物的纳米晶体分散体的方法，包括以下步骤：在所述连续相中提供所述照相用化合物的纳米无定形分散体，并退火所述纳米无定形分散体以将其中所述化合物的物理状态转化 公开了结晶物理状态，从而获得纳米晶体分散体。
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