公开(公告)号：US11695170B2

公开(公告)日：2023-07-04

申请号：US17789970

申请日：2019-12-31

申请人： JINGMEN GEM CO., LTD ,  GEM CO., LTD

发明人： Kaihua Xu ,  Zhenkang Jiang ,  Qinxiang Li ,  Kun Zhang ,  Wenjie Wang ,  Jun Wang ,  Shihong Wen

IPC分类号： C01D15/04 ,  C01F5/28 ,  H01M10/54 ,  C01F11/22 ,  C01G45/00 ,  C01G51/00 ,  C01G53/00 ,  C22B3/00 ,  C22B47/00

CPC分类号： H01M10/54 ,  C01D15/04 ,  C01F5/28 ,  C01F11/22 ,  C01G45/003 ,  C01G51/003 ,  C01G53/003 ,  C22B23/0453 ,  C22B47/00

摘要： Provided are a battery-level Ni—Co—Mn mixed solution and a preparation method for a battery-level Mn solution, the steps thereof comprising: acid dissolution (S1), alkalization to remove impurities (S2), synchronous precipitation of calcium, magnesium, and lithium (S3), deep ageing to remove impurities (S4), synergistic extraction (S5), and refining extraction (S6). The steps of deep ageing to remove impurities (S4) and synergistic extraction (S5) comprise: performing deep ageing on a filtrate obtained from the step of synchronous precipitation of calcium, magnesium, and lithium (S3), and after performing filtration to remove impurities, obtaining an aged filtrate; using P204 to extract the aged filtrate and obtain a loaded organic phase, and subjecting the loaded organic phase to staged back-extraction to obtain the battery-level Ni—Co—Mn mixed solution and a Mn-containing solution. By means of the cooperation between the multiple process steps of synchronous precipitation of calcium, magnesium, and lithium (S3), deep ageing to remove impurities (S4), and synergistic extraction (S5), the impurity content of the obtained battery-level Ni—Co—Mn mixed solution is significantly lowered, and the battery-level Ni—Co—Mn mixed solution can be directly used to prepare a lithium battery ternary precursor material. At the same time, the battery-level Mn solution can also be obtained, which is favorable for large-scale applications of the process and increasing economic benefits.