Monoazo dyes having an aryloxyalkyl group on the nitrogen atom in the
para position of a 1,4-phenylene coupling component radical
    1.
    发明授权
    Monoazo dyes having an aryloxyalkyl group on the nitrogen atom in the para position of a 1,4-phenylene coupling component radical 失效
    在1,4-亚苯基偶联组分分子的位置上的氮原子上具有芳氧基甲基的MONOAZO染料

    公开(公告)号:US4111930A

    公开(公告)日:1978-09-05

    申请号:US669165

    申请日:1976-03-22

    申请人: Jacques Meybeck

    发明人: Jacques Meybeck

    CPC分类号: C09B29/0025 C09B29/08

    摘要: Sparingly water-soluble azo compounds of the formula ##STR1## wherein D is phenyl, substituted phenyl, thiazolyl, substituted thiazolyl, benzothiazolyl, substituted benzothiazolyl, 1,3,5-thiadiazolyl, phenyl-1,3,4-thiadiazolyl, nitrobenzoisothiazolyl or substituted thienyl,Wherein each substituent of substituted phenyl, substituted thiazolyl and substituted benzothiazolyl is independently chloro, bromo, nitro, cyano or methylsulfonyl and each substituent of substituted thienyl is independently nitro or acetyl,R.sub.1 is hydrogen, alkyl, alkoxy or --NH--Y--R.sub.5, wherein Y is --CO--, --COO-- or --SO.sub.2 --, and R.sub.5 is alkyl, haloalkyl, phenyl or substituted phenyl,R.sub.2 is hydrogen or alkoxy,R.sub.3 is phenoxyalkyl, substituted phenoxyalkyl, benzyloxyalkyl or substituted benzyloxyalkyl, andR.sub.4 is hydrogen, cyclohexyl, alkyl or alkyl substituted by chloro, bromo or --O--CO--NH--R.sub.6, wherein R.sub.6 is alkyl or phenyl are eminently suitable for application as disperse dyes. From aqueous dispersion such dyes build up powerfully on regenerated fibres and synthetic fibres of high molecular weight and hydrophobic character. Dyeings are obtained which are fast to thermofixation, sublimation, pleating, gas fumes, dry cleaning and wet treatments.

    2-Optionally substituted alkyl-and phenylsulfonylphenyl-azo-phenyl dyes
and a process for their synthesis
    2.
    发明授权
    2-Optionally substituted alkyl-and phenylsulfonylphenyl-azo-phenyl dyes and a process for their synthesis 失效
    2-任选取代的烷基 - 和苯基磺酰基苯基 - 偶氮苯基染料及其合成方法

    公开(公告)号:US4046757A

    公开(公告)日:1977-09-06

    申请号:US860403

    申请日:1969-09-23

    IPC分类号: C09B43/40 C09B43/02

    CPC分类号: C09B43/405

    摘要: Compounds of the formula ##STR1## wherein R.sub.1 is optionally substituted hydrocarbyl (alkyl or phenyl),R.sub.2 is hydrogen, alkyl or acylamino,R.sub.3 is hydrogen, alkyl, substituted alkyl, alkoxy or substituted alkoxy,Each of R.sub.4 and R.sub.5 is independently hydrogen, alkyl or substituted alkyl,T is halo, nitro, cyano, alkyl, alkoxy, alkylsulfonyl, sulfamoyl or alkylsulfamoyl, andn is 0 to 3. These compounds are suitable for the dyeing and printing of textile materials. The dyeings obtained are extremely fast to thermofixation, sublimation, pleating, gas fumes, cross dyeing, rubbing, dry cleaning, chlorine, and wet treatments, such as water, washing and perspiration. The compounds of this invention and other phenylazo-phenyl compounds with an optionally substituted hydrocarbylsulfonyl group (R.sub.1-- SO.sub.2 --) on the diazo component radical in a position ortho to the azo group can be synthesized from the corresponding compounds having a halo atom or nitro group in this position by reaction with a compound of the formula H--SO.sub.2 --R.sub.1 or a salt thereof.

    摘要翻译: 其中R 1为任选取代的烃基(烷基或苯基),R 2为氢,烷基或酰氨基,R 3为氢,烷基,取代的烷基,烷氧基或取代的烷氧基,其中R 4和R 5各自独立地为氢, 烷基或取代烷基,T为卤素,硝基,氰基,烷基,烷氧基,烷基磺酰基,氨磺酰基或烷基氨磺酰基,N为0至3.这些化合物适用于纺织材料的染色和印花。 获得的染色对于热固化,升华,打褶,气体烟雾,交叉染色,摩擦,干洗,氯和湿处理如水,洗涤和排汗都非常快。 本发明化合物和其它苯偶氮基 - 苯基化合物与偶氮基团邻位上重氮组分基团上任意取代的烃基磺酰基(R 1 -SO 2 - )可以由具有卤原子或硝基的相应化合物合成 在该位置上与式H-SO 2 -R 1的化合物或其盐反应。