公开(公告)号：US5554698A

公开(公告)日：1996-09-10

申请号：US463375

申请日：1995-06-05

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Yen Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Yen Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08F8/44 ,  C08J5/18 ,  C01F8/42

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08 ,  Y10T428/31913

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

公开(公告)号：US5569722A

公开(公告)日：1996-10-29

申请号：US463373

申请日：1995-06-05

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08F8/44 ,  C08J5/18 ,  C08F8/42

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08 ,  Y10T428/31913

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

摘要翻译： 公开了具有改进的光学性质的离聚物组合物。 这些组合物包含可以表示为具有2至8个碳原子的α-烯烃的聚合产物的离聚物，α，β-烯属不饱和羧酸的酯，丙烯酸和甲基丙烯酸的金属盐，以及任选的α，β- 赋予一些期望的聚合物性质或性质如酸度和/或溶剂电阻率的烯属不饱和共聚单体。 还公开了将这些离聚物组合物制成反应性挤出机并用酸处理组合物以赋予组合物酸性或仅对组合物表面赋予酸性的方法。

公开(公告)号：US5631328A

公开(公告)日：1997-05-20

申请号：US379411

申请日：1995-01-27

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08F8/44 ,  C08J5/18 ,  C08F8/00

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08 ,  Y10T428/31913

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

摘要翻译： 公开了具有改进的光学性质的离聚物组合物。 这些组合物包含可以表示为具有2至8个碳原子的α-烯烃的聚合产物的离聚物，α，β-烯属不饱和羧酸的酯，丙烯酸和甲基丙烯酸的金属盐，以及任选的α，β- 赋予一些期望的聚合物性质或性质如酸度和/或溶剂电阻率的烯属不饱和共聚单体。 还公开了将这些离聚物组合物制成反应性挤出机并用酸处理组合物以赋予组合物酸性或仅对组合物表面赋予酸性的方法。

公开(公告)号：US5599877A

公开(公告)日：1997-02-04

申请号：US464504

申请日：1995-06-05

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08F8/44 ,  C08J5/18 ,  C08F8/42

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08 ,  Y10T428/31913

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

公开(公告)号：US5576396A

公开(公告)日：1996-11-19

申请号：US330290

申请日：1994-10-27

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08J5/18 ,  C08F8/42

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

公开(公告)号：US5597869A

公开(公告)日：1997-01-28

申请号：US463338

申请日：1995-06-05

申请人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

发明人： James H. Wang ,  David Rosendale ,  Victor P. Kurkov ,  Leslie P. Theard ,  Ta Y. Ching ,  Lewis R. Compton ,  Tor H. G. Palmgren ,  Mitchell P. Eichelberger

IPC分类号： C08F8/12 ,  C08F8/44 ,  C08J5/18 ,  C08F8/42

CPC分类号： C08J5/18 ,  B29C47/00 ,  C08F8/44 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08J2323/08 ,  Y10T428/31913

摘要： Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.

公开(公告)号：US5498785A

公开(公告)日：1996-03-12

申请号：US181027

申请日：1994-01-14

申请人： James H. Wang ,  Victor P. Kurkov ,  Leslie P. Theard ,  David Rosendale

发明人： James H. Wang ,  Victor P. Kurkov ,  Leslie P. Theard ,  David Rosendale

IPC分类号： C08F8/32

CPC分类号： C08F8/32 ,  C08F2800/20

摘要： A continuous process for the aminolysis of polymers produced from ethylenically unsaturated structural units comprising contacting, in a reaction vessel,(a) a molten polymer containing structural units produced from alpha-olefins having from 2 to 8 carbons atoms, and esters of of .alpha.,.beta.-ethylenically-unsaturated carboxylic acids in a reaction vessel; and(b) a liquid phase comprising an amine-containing compound, e.g., an alkylamine having an alkyl group containing 1-30 carbon atoms, ammonia, or derivatives thereof, in the presence of(c) a catalytically effective amount of a catalyst, which is preferably a metal-containing solution, for a period of time effective to produce a polymer containing acrylamide structural units, wherein the period of time is less than about 1 hour.This process is performed continuously in a reaction vessel, preferably in at least one reactive extruder, under conditions effective to provide an ethylene co-polymer containing acrylamide structural units.

摘要翻译： 用于由烯属不饱和结构单元生产的聚合物的氨解的连续方法包括在反应容器中使（a）含有由具有2至8个碳原子的α-烯烃制成的结构单元的熔融聚合物和α， β-烯属不饱和羧酸在反应容器中; 和（b）在（c）催化有效量的催化剂的存在下，包含含胺化合物，例如具有含有1-30个碳原子的烷基的烷基胺，氨或其衍生物的液相， 其优选为含金属溶液，持续一段时间有效地制备含有丙烯酰胺结构单元的聚合物，其中所述时间段小于约1小时。 在有效提供含有丙烯酰胺结构单元的乙烯共聚物的条件下，在反应容器中优选在至少一个反应性挤出机中连续进行该方法。

公开(公告)号：US5543233A

公开(公告)日：1996-08-06

申请号：US461232

申请日：1995-06-05

申请人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

发明人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

IPC分类号： C08F8/44 ,  C08F210/02 ,  C08L23/02 ,  B32B27/06 ,  B32B27/32

CPC分类号： C08F8/44 ,  C08F210/02 ,  C08L23/02 ,  Y10T428/31913 ,  Y10T428/31928

摘要： A composition is disclosed which comprises a copolymer of ethylene and alkyl acrylate having improved melt-point temperature and/or improved adhesiveness to polymeric substrates. A process for making these compositions is also disclosed. In addition, an ionomer made from the copolymer and a method for making the ionomer are disclosed.

摘要翻译： 公开了一种组合物，其包含具有改进的熔点温度和/或改善的与聚合物基材的粘合性的乙烯和丙烯酸烷基酯的共聚物。 还公开了制备这些组合物的方法。 此外，公开了由共聚物制成的离聚物和制备离聚物的方法。

公开(公告)号：US5532066A

公开(公告)日：1996-07-02

申请号：US462335

申请日：1995-06-05

申请人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

发明人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

IPC分类号： C08J5/18 ,  C08F2/00 ,  C08F2/34 ,  C08F8/44 ,  C08F210/02 ,  C08F220/14 ,  C08F220/18 ,  C08L23/02 ,  C08L23/06 ,  C08L23/08 ,  B32B27/08 ,  B32B27/30 ,  C08F10/02 ,  C08F20/18

CPC分类号： C08F8/44 ,  C08F210/02 ,  C08L23/02 ,  C08L23/0869 ,  C08L23/06 ,  C08L23/0853 ,  C08L23/10 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31935

摘要： A composition is disclosed which comprises a copolymer of ethylene and alkyl acrylate having improved melt-point temperature and/or improved adhesiveness to polymeric substrates. A process for making these compositions is also disclosed. In addition, an ionomer made from the copolymer and a method for making the ionomer are disclosed.

摘要翻译： 公开了一种组合物，其包含具有改进的熔点温度和/或改善的与聚合物基材的粘合性的乙烯和丙烯酸烷基酯的共聚物。 还公开了制备这些组合物的方法。 此外，公开了由共聚物制成的离聚物和制备离聚物的方法。

公开(公告)号：US5804675A

公开(公告)日：1998-09-08

申请号：US699307

申请日：1996-08-19

申请人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

发明人： Jerry G. Latiolais ,  J. Paul Gathright ,  Nicholas R. Galante ,  M. Stephen Galland ,  J. Diores Gallet ,  Lewis R. Compton ,  George L. Baker ,  James H. Wang

IPC分类号： C08J5/18 ,  C08F2/00 ,  C08F2/34 ,  C08F8/44 ,  C08F210/02 ,  C08F220/14 ,  C08F220/18 ,  C08L23/02 ,  C08L23/06 ,  C08L23/08 ,  C08F10/02 ,  C08F20/18

CPC分类号： C08F8/44 ,  C08F210/02 ,  C08L23/02 ,  C08L23/0869 ,  C08L23/06 ,  C08L23/0853 ,  C08L23/10 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31935

摘要： A composition is disclosed which comprises a copolymer of ethylene and alkyl acrylate having improved melt-point temperature and/or improved adhesiveness to polymeric substrates. A process for making these compositions is also disclosed. In addition, an ionomer made from the copolymer and a method for making the ionomer are disclosed.

摘要翻译： 公开了一种组合物，其包含具有改进的熔点温度和/或改善的与聚合物基材的粘合性的乙烯和丙烯酸烷基酯的共聚物。 还公开了制备这些组合物的方法。 此外，公开了由共聚物制成的离聚物和制备离聚物的方法。