摘要:
The transverse cross section of a body is modified by the steps of: a) determining the extent to which the body has material in excess of a desired shape at a plurality of points, b) exposing the body to a local heat source having a temperature sufficiently high to remove material from the surface of the body, and c) moving the surface of the body in relation to the source at a speed which decreases in regions where the body has material in excess of the desired shape so as to remove more material from such regions than from other regions. In a preferred embodiment, the body is an optical fiber preform, the local heat source is the fireball of a plasma torch, and the body is moved relative to the torch by rotating the preform at a controllable angular velocity while the torch is translated along the length of the preform.
摘要:
To attain high strength optical glass fibers, the glass preforms, from which the fibers are drawn, must generally be free of surface imperfections such as bubbles, and air lines. It has been discovered that these imperfections can be removed quickly and cleanly by contacting the preform surface with a substantial portion of the electrically conducting plasma region (the plasma fireball) extending from a plasma torch. Significantly, the surface material is substantially removed by vaporization, due to the extremely high plasma temperature (>9000.degree. C. at the plasma center) of the isothermal plasma torch. Though the temperatures in the tail of the plasma fireball are substantially less than at the plasma center, the temperatures are generally still several thousand degrees centigrade. These tail temperatures typically are sufficiently high to cause vaporization of most refractory dielectrics making the inventive method applicable to the fabrication of a wide variety of articles comprising refractory dielectric bodies.Advantageously, selective etching, according to one aspect of the inventive method, is used to remove fiber preform eccentricity and to fabricate optical fiber preforms with non-circular cross-sections for such applications as fiber sensors. Selective etching can result by controlling the plasma fireball location, the rotation of the silica preform, and/or the travel of the fireball across the preform. Significantly, the fireball location is controlled, among other ways, by injecting into the torch an additional gas that has a high ionization threshold or by inserting a probe along the axis of the torch. In either case, a substantial portion of the plasma fireball is advantageously "pushed" outside the torch for ease of contact with the silica preform surface, or any other refractory dielectric being processed.
摘要:
Heating a wet colloidal gel body in an autoclave above its 1-atmosphere boiling point, under rigorously defined conditions, avoids shrinkage during subsequent drying. As a consequence, drying rates may be increased, and handling care becomes less critical.
摘要:
Aluminum metaphosphate optical fibers are disclosed. In a specific embodiment, aluminum metaphosphate, doped with from 10 to 30 mole percent of diboron trioxide, is found to yield an optical fiber which combines the desirable properties of both high numerical aperture and low material dispersion. The fiber is nonhygroscopic and has a high melting temperature. The index of refraction of the glass may be lowered by doping with silicon dioxide. Consequently, a graded fiber may be made by increasing the concentration of silicon oxide from the core to the cladding.
摘要:
Optical fiber preforms are produced by means of a duplex hot zone, a section of which is defined by an r.f. generated plasma fire ball. The process operates within a tube with gaseous precursor material reacting within the hot zone to result in deposited material of the desired preform glass composition. A "smoothing" region within the hot zone is defined by tube surface at a temperature sufficiently elevated to consolidate any particulate material resulting from reaction. In some aspects, the disclosed procedures may be regarded as Modified Chemical Vapor Deposition. Commercial significance resides in significantly increased throughput of preforms and, consequently, in fiber.
摘要:
Aluminum metaphosphate optical fibers are disclosed. In a specific embodiment, aluminum metaphosphate, doped with from 10 to 30 mole percent of diboron trioxide, is found to yield an optical fiber which combines the desirable properties of both high numerical aperture and low material dispersion. The fiber is nonhygroscopic and has a high melting temperature. The index of refraction of the glass may be lowered by doping with silicon dioxide. Consequently, a graded fiber may be made by increasing the concentration of silicon oxide from the core to the cladding.
摘要:
A ceramic composition and processing procedure is described which is useful in electric and electronic devices such as thermistors. The ceramic composition, which may be described as a semiconducting barium titanate, exhibits a large positive temperature coefficient of resistance. Advantages are ease and convenience of fabrication with lower sintering temperature than conventional processing and use of an air atmosphere instead of nitrogen or oxygen atmospheres. This facilitates batch processing and permits convenient sintering in a continuous kiln.
摘要:
In accordance with the invention, a plurality of elongated refractory bodies are laminated together by placing the bodies in close adjacency, exposing the adjacent bodies to a plasma torch heat source, and moving the bodies longitudinal past the torch at a nonzero average rate which includes a reciprocating (e.g., oscillatory) component to longitudinally spread the zone of heating. Where the bodies are a rod to be laminated within a hollow tube, it is advantageous to reduce the air pressure between the rod and tube, thereby eliminating potential contaminants and, at the same time, biasing the tube to collapse against the rod. This method is particularly useful in laminating overcladding tubes to core rods to form optical fiber preforms.
摘要:
Sol-gel processing of a silica glass body is facilitated by rapid drying. The body, having been heated to a temperature of about 200.degree. C. in a hermetically sealed vessel, is vented while reducing temperature. Termination of drying coincides with reduction to atmospheric pressure.
摘要:
Bent sol-gel produced tubing is straightened by drawing, with tensile force and operating temperature to result in minimal plastic flow, so that size reduction is small. The method is usefully applied to reject recovery in the preparation of overclad tubes, which as encompassing closely-fitting core rods, form the composite preform from which optical fiber is drawn.