摘要:
A heterogeneous ruthenium catalyst comprising silicon dioxide as support material, in which the percentage ratio of the Q2 and Q3 structures Q2/Q3 in the silicon dioxide determined by means of solid-state 29Si-NMR is less than 25, a process for preparing a bisglycidyl ether of the formula I where R is CH3 or H, by ring hydrogenation of the corresponding aromatic bisglycidyl ether of the formula II in which the abovementioned heterogeneous ruthenium catalyst is used, and a bisglycidyl ether of the formula I which can be prepared using the abovementioned process.
摘要:
Heterogeneous ruthenium catalyst comprising silicon dioxide as support material, wherein the catalyst surface comprises alkaline earth metal ions (M2+), process for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic group, in particular a process for preparing bisglycidyl ethers of the formula I where R is CH3 or H, by ring hydrogenation of the corresponding aromatic bisglycidyl ether of the formula II in which the abovementioned heterogeneous ruthenium catalyst is used, and bisglycidyl ethers of the formula I which can be prepared by the abovementioned process.
摘要:
A continuous process for preparing sugar alcohols by catalytic hydrogenation of an aqueous solution of a saccharide, which forms the corresponding sugar alcohol on hydrogenation, in the presence of a ruthenium catalyst which is obtainable by: i) single or multiple treatment of an amorphous silicon-dioxide-based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i), which comprises, before the hydrogenation, bringing the aqueous saccharide solution to be hydrogenated into contact with the support material.
摘要:
Composition comprising a hydrogenated bisglycidyl ether and a crosslinker, wherein the hydrogenated bisglycidyl ether has the formula I where R is CH3 or H, and is obtained by hydrogenation of the aromatic rings of a corresponding bisglycidyl ether of the formula II where the degree of hydrogenation is >98%, and the crosslinker has no aromatic structural elements.Process for preparing a crosslinked epoxy resin, in which the abovementioned composition is used.Crosslinked epoxy resins which can be prepared by the abovementioned process, and their uses.
摘要:
The present invention relates to a process for continuously preparing a mononitrated organic compound, especially a process for preparing mononitrobenzene. The invention relates more particularly to an improved continuous adiabatic process for preparing nitrobenzene.
摘要:
Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel and (b) a phosphine having at least two trivalent phosphorus atoms and/or (c) a phosphine having one trivalent phosphorus atom and the alkyne is added only after the phosphonic acid derivative has been brought into contact with the catalyst complex system for at least one minute.
摘要:
Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel, (b) a phosphine having at least two trivalent phosphorus atoms and in addition (c) a phosphine having one trivalent phosphorus atom.
摘要:
The present invention relates to a process for continuously preparing a mononitrated organic compound, especially a process for preparing mononitrobenzene. The invention relates more particularly to an improved continuous adiabatic process for preparing nitrobenzene.
摘要:
Novel ruthenium catalysts can be obtained by: i) treating a support material based on amorphous silicon dioxide one or more times with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequently drying the treated support material at below 200° C., ii) reducing the solid obtained in i) by means of hydrogen at from 100 to 350° C., where step ii) is carried out directly after step i). These catalysts can be used for the catalytic hydrogenation of monosaccharides and disaccharides to produce sugar alcohols, with the exception of sorbitol.
摘要:
The use of hexahydrophthalimide compounds of the formula (I) is described as plasticizers for molding compositions, in particular polyvinyl chloride, in which R is alkyl, cycloalkyl, or cycloalkylalkyl, where the two last named moieties can be unsubstituted or alkyl-substituted, and the moiety R has at least 6 carbon atoms.