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1.发明授权
公开(公告)号：US5814707A
公开(公告)日：1998-09-29
申请号：US868544
申请日：1997-06-04
IPC分类号： C08F8/00 , C08F8/06 , C08F212/08
CPC分类号： C08F8/06 , C08F2800/10 , C08F2810/50
摘要： This invention provides a method by which an alkylstyrene containing polymer may be exclusively functionalized at the primary benzylic carbon site of the styrenic monomer. The process of this invention comprises the treatment of an alkylstyrene containing polymer dissolved in a non-polar liquid medium with an organic hydroperoxide oxidizing reagent in the presence of a catalytically sufficient amount of a chromium compound, to oxidize a portion of the aromatic alkyl groups of the polymer to an oxygen containing functional group.
摘要翻译： 本发明提供了一种含烷基苯乙烯的聚合物可以在苯乙烯类单体的伯苄基碳原子官能化官能化的方法。 本发明的方法包括在催化足够量的铬化合物存在下，用有机氢过氧化物氧化试剂处理溶解在非极性液体介质中的含烷基苯乙烯的聚合物，以将一部分芳族烷基氧化成 该聚合物与含氧官能团。
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公开(公告)号：US5814708A
公开(公告)日：1998-09-29
申请号：US868548
申请日：1997-06-04
IPC分类号： C08F8/00 , C08F8/06 , C08F212/08
CPC分类号： C08F8/06 , C08F2800/10 , C08F2810/50
摘要： This invention provides a method by which an alkylstyrene containing polymer may be exclusively functionalized at the primary benzylic carbon site of the styrenic monomer. The process of this invention comprises the treatment of an alkylstyrene containing polymer dissolved in a non-polar liquid medium with an organic hydroperoxide oxidizing reagent in the presence of a catalytically sufficient amount of a chromium compound, to oxidize a portion of the aromatic alkyl groups of the polymer to an oxygen containing functional group.
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公开(公告)号：US5670581A
公开(公告)日：1997-09-23
申请号：US476753
申请日：1995-06-07
CPC分类号： C08F8/42 , C08F8/00 , C08F2800/10 , C08F2810/30 , C08F2810/50
摘要： There is provided a method of introducing functionality into a copolymer of an isoolefin and an alkylstyrene at the alkylbenzyl carbon atom comprising the steps of: forming a solution of said copolymer in a hydrocarbon solvent; adding to said polymer solution an alkali metal Cs, K, Na alkoxide and an alkyl lithium compound to form a superbase with the polymer solution; and adding an electrophile to said base polymer solution also provided are the metalated copolymers and the functionalized derivative therefrom.
摘要翻译： 提供了在烷基苄基碳原子上将官能度引入异烯烃和烷基苯乙烯的共聚物的方法，包括以下步骤：在烃溶剂中形成所述共聚物的溶液; 向所述聚合物溶液中加入碱金属Cs，K，醇钠和烷基锂化合物以与所述聚合物溶液形成超基; 还向所述基础聚合物溶液中加入亲电试剂也是金属化共聚物和由其衍生的官能化衍生物。
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公开(公告)号：US06545101B2
公开(公告)日：2003-04-08
申请号：US09777398
申请日：2001-02-06
IPC分类号： C08F1000
CPC分类号： C08G83/003 , C08F8/26 , C08F8/46 , C08F2810/30 , C08F2810/40 , C08G81/00 , C08G81/02 , C08G81/024 , C08G83/001 , C08F110/10
摘要： Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succinimide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
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公开(公告)号：US5807931A
公开(公告)日：1998-09-15
申请号：US868547
申请日：1997-06-04
IPC分类号： C08F8/00 , C08F8/06 , C08F212/08
CPC分类号： C08F8/06 , C08F2800/10 , C08F2810/50
摘要： This invention provides a method by which an alkylstyrene containing polymer may be exclusively functionalized at the primary benzylic carbon site of the styrenic monomer. The process of this invention comprises the treatment of an alkylstyrene containing polymer dissolved in a non-polar liquid medium with an organic hydroperoxide oxidizing reagent in the presence of a catalytically sufficient amount of a chromium compound, to oxidize a portion of the aromatic alkyl groups of the polymer to an oxygen containing functional group.
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公开(公告)号：US5849828A
公开(公告)日：1998-12-15
申请号：US869818
申请日：1997-06-05
IPC分类号： C08L23/26 , C08F8/00 , C08F8/42 , C08F210/10
CPC分类号： C08F8/42 , C08F8/00 , C08F2800/10 , C08F2810/30 , C08F2810/50
摘要： There is provided a method of introducing functionality into a copolymer of an isoolefin and an alkylstyrene at the alkylbenzyl carbon atom comprising the steps of: forming a solution of said copolymer in a hydrocarbon solvent; adding to said polymer solution an alkali metal Cs, K, Na alkoxide and an alkyl lithium compound to form a superbase with the polymer solution; and adding an electrophile to said base polymer solution also provided are the metalated copolymers and the functionalized derivative therefrom.
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公开(公告)号：US5840810A
公开(公告)日：1998-11-24
申请号：US659457
申请日：1996-06-06
IPC分类号： C08L23/26 , C08F8/00 , C08F8/42 , C08F210/10
CPC分类号： C08F8/42 , C08F8/00 , C08F2800/10 , C08F2810/30 , C08F2810/50
摘要： There is provided a method of introducing functionality into a copolymer of an isoolefin and an alkylstyrene at the alkylbenzyl carbon atom comprising the steps of: forming a solution of said copolymer in a hydrocarbon solvent; adding to said polymer solution an alkali metal Na, K, Rb, Cs alkoxide and an alkyl lithium compound to form a superbase with the polymer solution; and adding an electrophile to the metalated polymer solution; also provided are the metalated copolymers and the functionalized derivatives therefrom.
摘要翻译： 提供了在烷基苄基碳原子上将官能度引入异烯烃和烷基苯乙烯的共聚物的方法，包括以下步骤：在烃溶剂中形成所述共聚物的溶液; 向所述聚合物溶液中加入碱金属Na，K，Rb，Cs醇盐和烷基锂化合物以与所述聚合物溶液形成超级碱基; 并向金属化聚合物溶液中加入亲电试剂; 还提供了金属化共聚物及其官能化衍生物。
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8.发明授权
公开(公告)号：US5679748A
公开(公告)日：1997-10-21
申请号：US628416
申请日：1996-04-05
IPC分类号： C08F8/00 , C08F8/06 , C08F212/08
CPC分类号： C08F8/06 , C08F2800/10 , C08F2810/50
摘要： This invention provides a method by which an alkylstyrene containing polymer may be exclusively functionalized at the primary benzylic carbon site of the styrenic monomer. The process of this invention comprises the treatment of an alkylstyrene containing polymer dissolved in a non-polar liquid medium with an organic hydroperoxide oxidizing reagent in the presence of a catalytically sufficient amount of a chromium compound, to oxidize a portion of the aromatic alkyl groups of the polymer to an oxygen containing functional group.
摘要翻译： 本发明提供了一种含烷基苯乙烯的聚合物可以在苯乙烯类单体的伯苄基碳原子官能化官能化的方法。 本发明的方法包括在催化足够量的铬化合物存在下，用有机氢过氧化物氧化试剂处理溶解在非极性液体介质中的含烷基苯乙烯的聚合物，以氧化一部分芳族烷基 该聚合物与含氧官能团。
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公开(公告)号：US06228978B1
公开(公告)日：2001-05-08
申请号：US09100271
申请日：1998-06-19
IPC分类号： C08G7300
CPC分类号： C08G83/003 , C08F8/26 , C08F8/46 , C08F2810/30 , C08F2810/40 , C08G81/00 , C08F110/10
摘要： Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succininide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
摘要翻译： 公开了用末端反应性不饱和官能化的聚异丁烯（PIB）。 碳氢化合物封端的PIB在烃溶剂中使用式RO-M的醇盐进行脱卤化氢，其中R是至少5个碳原子的烷基，M是碱金属。 得到的PIB具有末端不饱和度，其反应性“外”形式为100％，可通过与马来酸酐的烯酯反应转化为琥珀酸酐基团（PIB-SA），PIB-SA与胺官能树枝状大分子反应以获得 具有树枝状聚合物核心和通过琥珀酰亚胺键连接的PIB分支的星形支化聚合物。星形支化聚合物与聚丙烯的共混物具有改善的能量吸收性能和可用于膜中的水分/氧气渗透性。
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10.发明授权
公开(公告)号：US6011120A
公开(公告)日：2000-01-04
申请号：US771001
申请日：1996-12-23
CPC分类号： C08F8/42
摘要： There is provided a method of introducing ethylenically unsaturated functionality, into an alkylstyrene homopolymer or copolymer with an isoolefin, at the alkylbenzyl carbon atom comprising the steps of: forming a solution of the polymer in a hydrocarbon solvent; adding to the polymer solution an alkali metal (Na, K, Rb, Cs) alkoxide and an alkyl lithium compound to form a solution of a metalated intermediate; and adding a halodialkylalkenyl silane to the metalated polymer solution. Also provided are the ethylenically unsaturated functionalized polymer derivatives made by the method, and the crosslinked derivatives thereof.
摘要翻译： 提供了一种在烷基苄基碳原子上将烯属不饱和官能团引入烷基苯乙烯均聚物或与异烯烃的共聚物的方法，包括以下步骤：在烃溶剂中形成聚合物溶液; 向聚合物溶液中加入碱金属（Na，K，Rb，Cs）醇盐和烷基锂化合物以形成金属化中间体的溶液; 并向金属化聚合物溶液中加入卤代二烷基烯基硅烷。 还提供了通过该方法制备的烯键式不饱和官能化聚合物衍生物及其交联衍生物。
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