摘要:
Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succinimide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
摘要:
Film is provided wherein, at least one layer comprises polymer, a molecular majority of which is derived from propylene, having water vapor transmission rate of less than or equal to about (-7.4428 g.times..mu.m/m.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallinity)+627.32 g.times..mu.m/m.sup.2 .times.day, or (-0.0189 g.times.mil/100 in.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallity)+1.593 g.times.mil/100 in.sup.2 .times.day.
摘要翻译:提供膜,其中至少一层包含聚合物,其分子主要来源于丙烯,其水蒸气透过率小于或等于约(-7.4428g×m / m 2×x%x%聚合物结晶度)(%聚合物结晶度 )+627.32gxm / m 2×日,或(-0.0189gxmil / 100 in 2xdayx%聚合物结晶度)(%聚合物结晶度)+1.593gxmil / 100 in2xday。
摘要:
The co-polymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.
摘要:
The present invention relates generally to rubber compositions having improved green strength and thermal stability. These compositions comprise blends of a first rubber component, an isoolefin/para-alkylstyrene copolymer component, and an amine component reacted in situ prior to curing. The present invention further relates to methods for preparing these compositions.
摘要:
This invention relates generally to foamable crystalline propylene polymers obtained from metallocene catalysis and to their methods of production. The foamed crystalline propylene polymers have molecular weight distributions and densities that fall within broad ranges. The crystalline propylene polymers may be prepared in a multiple stage polymerization process using a combination of metallocene components in at least two stages.
摘要:
Improved thermoplastic polymer soft elastic fiber blend compositions including a crystalline isotactic polypropylene component and a crystallizable alpha-olefin and propylene copolymer component, the copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided prepared from 0% to 95%, preferably 2% to 40% of the crystalline isotactic polypropylene and from 5% to 100%, preferably 60% to 98% of a crystallizable ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and, improved resistance to elastic deformation.
摘要:
Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succininide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
摘要:
The co-polymerization reaction of one or more olefin monomers, such as propylene, with α,ω-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of α,ω-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.