公开(公告)号：US4116887A

公开(公告)日：1978-09-26

申请号：US539729

申请日：1975-01-09

申请人： Jean-Marie Lehn ,  Francois Schue ,  Sylvia Boileau ,  Bernd Kaempf ,  Alain Andre Cau ,  Jean Robert Moinard ,  Serge Fernand Raynal

发明人： Jean-Marie Lehn ,  Francois Schue ,  Sylvia Boileau ,  Bernd Kaempf ,  Alain Andre Cau ,  Jean Robert Moinard ,  Serge Fernand Raynal

IPC分类号： C08F4/00 ,  C08G61/10 ,  C08G63/82 ,  C08G63/87 ,  C08G65/26 ,  C08G75/00 ,  C08G75/06 ,  C08G77/08 ,  C08G85/00 ,  C08G65/12 ,  C08G63/10

CPC分类号： C08G65/2603 ,  C08F4/00 ,  C08G61/10 ,  C08G63/823 ,  C08G63/87 ,  C08G65/263 ,  C08G65/2648 ,  C08G65/2651 ,  C08G75/00 ,  C08G75/06 ,  C08G77/08 ,  C08G85/00

摘要： A novel process for polymerization or copolymerization of monomers is described, according to which the reaction is carried out in the presence of an anionic initiator and a macroheterocyclic complexing agent of formula ##STR1## in which: EACH R.sub.1 is a hydrogen atom, a hydrocarbon group or an alkoxycarbonyl group, or the two R.sub.1 together can form a group of the general formula: ##STR2## THAT IS TO SAY FORMING A THIRD BRIDGE BETWEEN THE TWO NITROGEN ATOMS IN THE MOLECULE, A is a hydrocarbon group,D is an oxygen or sulfur atom or a hydrocarbon group, with the proviso that at least two of the groups D are oxygen or sulfur atoms and that, if each R.sub.1 is hydrogen, a hydrocarbon group or an alkoxycarbonyl group, one of these two groups D is oxygen or sulfur and the other is oxygen,n and p are integers ranging from 1 to 3, andm is 2 or 3.

摘要翻译： 描述了单体聚合或共聚的新方法，根据该方法，反应在阴离子引发剂和式（I）的大环杂合络合剂的存在下进行，其中：