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    Organometallic monoacylarylphosphines
    1.
    发明授权
    Organometallic monoacylarylphosphines 失效
    有机金属一酰基芳基膦

    公开(公告)号：US06579663B2

    公开(公告)日：2003-06-17

    申请号：US10037111

    申请日：2001-10-22

    申请人： Jean-Pierre Wolf ,  Beat Michael Aebli ,  Gebhard Hug

    发明人： Jean-Pierre Wolf ,  Beat Michael Aebli ,  Gebhard Hug

    IPC分类号： G03F7027

    CPC分类号： C09D11/101 ,  A61K6/0052 ,  A61K6/08 ,  B33Y70/00 ,  C07F9/28 ,  C07F9/5036 ,  C07F9/5337 ,  C07F9/6521 ,  C08F2/50 ,  C09D4/00 ,  G03F7/0045 ,  G03F7/029 ,  G03F7/0384 ,  G03F7/0388 ,  G03F7/0755 ,  Y10S430/124 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L33/20 ,  C08L33/26 ,  C08L27/00 ,  C08L31/04 ,  C08L25/06 ,  C08L27/04 ,  C08L39/06 ,  A61K6/09 ,  C08L75/04 ,  A61K6/087 ,  C08L67/00 ,  C08L71/02 ,  A61K6/097 ,  C08L1/08

    摘要： Compounds of the formula I R1 and R2 independently of one another are C1-C20alkyl, OR11, CF3 or halogen; R3, R4 and R5 independently of one another are hydrogen, C1-C20alkyl, OR11 or halogen; R6, R7, R8, R9 and R10 independently of one another are hydrogen, C1-C20alkyl; C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R6, R7, R8, R9 and R10 are OR11, SR11, N(R12)(R13), phenyl or halogen; R11 is C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; R12 and R13 independently of one another are hydrogen, C114 C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R12 and R13 together are C3-C5alkylene which can be interrupted by O, S or NR14; R14 is hydrogen, phenyl, C1-C12alkyl or C2-C12alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; and M is hydrogen, Li, Na or K; are valuable intermediates for the preparation of unsymmetrical bisacylphosphine oxides and monoacylphosphine oxides.

    摘要翻译： 式IR1和R2的化合物彼此独立地为C1-C20烷基，OR11，CF3或卤素; R 3，R 4和R 5彼此独立地是氢，C 1 -C 20烷基，OR 11或卤素; R 6，R 7，R 8，R 9和R 10彼此独立地是氢，C 1 -C 20烷基; 被不连续的O原子中断一次或多于一次且未被取代或被OH和/或SH取代的C 2 -C 20烷基; 或R 6，R 7，R 8，R 9和R 10为OR 11，SR 11，N（R 12）（R 13），苯基或卤素; R 11是被O或S间隔一次或多于一次并且未被取代或被OH和/或SH取代的C 1 -C 20烷基，C 3 -C 8环烷基，苯基，苄基或C 2 -C 20烷基。 R 12和R 13彼此独立地是氢，C 11-14 C20烷基，C 3 -C 8环烷基，苯基，苄基或C 2 -C 20烷基，其被非连续的O原子间隔一次或多于一次，并且是未取代的或被OH和/或SH取代; 或R 12和R 13一起是可被O，S或NR14中断的C 3 -C 5亚烷基; R 14是氢，苯基，C 1 -C 12烷基或C 2 -C 12烷基，其被O或S间隔一次或多于一次，并且是未取代的或被OH和/或SH取代; M为氢，Li，Na或K; 是制备不对称双酰基氧化膦和单酰基氧化膦的有价值的中间体。

    Organometallic monoacylarylphosphines
    2.
    发明授权
    Organometallic monoacylarylphosphines 失效
    有机金属一酰基芳基膦

    公开(公告)号：US06399805B2

    公开(公告)日：2002-06-04

    申请号：US09776657

    申请日：2001-02-05

    申请人： Jean-Pierre Wolf ,  Beat Michael Aebli ,  Gebhard Hug

    发明人： Jean-Pierre Wolf ,  Beat Michael Aebli ,  Gebhard Hug

    IPC分类号： C07F953

    CPC分类号： C09D11/101 ,  A61K6/0052 ,  A61K6/08 ,  B33Y70/00 ,  C07F9/28 ,  C07F9/5036 ,  C07F9/5337 ,  C07F9/6521 ,  C08F2/50 ,  C09D4/00 ,  G03F7/0045 ,  G03F7/029 ,  G03F7/0384 ,  G03F7/0388 ,  G03F7/0755 ,  Y10S430/124 ,  A61K6/083 ,  C08L33/08 ,  C08L33/10 ,  C08L33/20 ,  C08L33/26 ,  C08L27/00 ,  C08L31/04 ,  C08L25/06 ,  C08L27/04 ,  C08L39/06 ,  A61K6/09 ,  C08L75/04 ,  A61K6/087 ,  C08L67/00 ,  C08L71/02 ,  A61K6/097 ,  C08L1/08

    摘要： Compounds of the formula I R1 and R2 independently of one another are C1-C20alkyl, OR11, CF3 or halogen; R3, R4 and R5 independently of one another are hydrogen, C1-C20alkyl, OR1 or halogen; R6, R7, R8, R9 and R10 independently of one another are hydrogen, C1-C20alkyl; C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R6, R7, R8, R9 and R10 are OR11, SR11, N(R12)(R13), phenyl or halogen; R11 is C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; R12 and R13 independently of one another are hydrogen, C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R12 and R13 together are C3-C5alkylene which can be interrupted by O, S or NR14; R14 is hydrogen, phenyl, C1-C12alkyl or C2-C12alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; and M is hydrogen, Li, Na or K; are valuable intermediates for the preparation of unsymmetrical bisacylphosphine oxides and monoacylphosphine oxides.

    摘要翻译： 式IR1和R2的化合物彼此独立地为C1-C20烷基，OR11，CF3或卤素; R 3，R 4和R 5彼此独立地是氢，C 1 -C 20烷基，OR 1或卤素; R 6，R 7，R 8，R 9和R 10彼此独立地是氢，C 1 -C 20烷基; 被不连续的O原子中断一次或多于一次且未被取代或被OH和/或SH取代的C 2 -C 20烷基; 或R 6，R 7，R 8，R 9和R 10为OR 11，SR 11，N（R 12）（R 13），苯基或卤素; R 11是被O或S间隔一次或多于一次并且未被取代或被OH和/或SH取代的C 1 -C 20烷基，C 3 -C 8环烷基，苯基，苄基或C 2 -C 20烷基。 R 12和R 13彼此独立地是氢，C 1 -C 20烷基，C 3 -C 8环烷基，苯基，苄基或C 2 -C 20烷基，其被非连续的O原子中断一次或多于一次，并且是未取代的或被OH和/或SH取代; 或R 12和R 13一起是可被O，S或NR14中断的C 3 -C 5亚烷基; R 14是氢，苯基，C 1 -C 12烷基或C 2 -C 12烷基，其被O或S间隔一次或多于一次，并且是未取代的或被OH和/或SH取代; M为氢，Li，Na或K; 是制备不对称双酰基氧化膦和单酰基氧化膦的有价值的中间体。

    Photoinitiator formulations
    3.
    发明授权
    Photoinitiator formulations 有权
    光引发剂配方

    公开(公告)号：US06803392B1

    公开(公告)日：2004-10-12

    申请号：US10088222

    申请日：2002-03-18

    申请人： Manfred Köhler ,  Beat Michael Aebli ,  Martin Holer ,  Ernst Eckstein ,  Jean-Pierre Wolf

    发明人： Manfred Köhler ,  Beat Michael Aebli ,  Martin Holer ,  Ernst Eckstein ,  Jean-Pierre Wolf

    IPC分类号： C08F246

    CPC分类号： G03F7/029 ,  C08F2/50

    摘要： Aqueous storage-stable, non-sedimenting photoinitiator suspensions comprising (a) a mono- or bis-acylphosphine oxide of formula (I), wherein R1 is C1-C20alkyl; C2-C20alkyl interrupted by one or more O atoms; C1-C12alkoxy; phenyl-C1-C4alkyl; or phenyl that is unsubstituted or substituted by C1C20alkyl, C1-C12alkoxy, halogen, cyclopentyl, cyclohexyl, C2-C12alkenyl, C2-C18alkyl interrupted by one or more O atoms, and/or by phenyl-C1-C4alkyl; or R1 is biphenylyl; R2 is an aromatic radical or has one of the meanings give for R1; R3 and R4 are each independently of the other C1-C12alkyl, C1-C12alkoxy or halogen; and R5 is hydrogen, C1-C12alkyl, C1-C12alkoxy or halogen; (b) a dispersant; and (c) water are suitable especially in the photopolymerisation of aqueous formulations comprising ethylenically unsaturated monomers.

    摘要翻译： 含水储存稳定的非沉降光引发剂悬浮液，其包含（a）式（I）的单或双酰基氧化膦，其中R 1为C 1 -C 20烷基; 被一个或多个O原子间断的C 2 -C 20烷基; C1-C12烷氧基; 苯基-C 1 -C 4烷基; 或未被取代或被C 1 -C 20烷基，C 1 -C 12烷氧基，卤素，环戊基，环己基，C 2 -C 12烯基，被一个或多个O原子间隔的C 2 -C 18烷基和/或被苯基-C 1 -C 4烷基取代的苯基; 或R 1为联苯基; R2是芳族基团或具有R1的含义之一; R 3和R 4各自独立地为C 1 -C 12烷基，C 1 -C 12烷氧基或卤素; 和R 5是氢，C 1 -C 12烷基，C 1 -C 12烷氧基或卤素; （b）分散剂; 和（c）水尤其适用于包含烯属不饱和单体的水性制剂的光聚合。

    Nonylated diphenylamines
    4.
    发明授权
    Nonylated diphenylamines 有权
    非化学二苯胺

    公开(公告)号：US06315925B1

    公开(公告)日：2001-11-13

    申请号：US09503264

    申请日：2000-02-14

    申请人： Beat Michael Aebli ,  Samuel Evans ,  Sandor Gati

    发明人： Beat Michael Aebli ,  Samuel Evans ,  Sandor Gati

    IPC分类号： C09K1516

    CPC分类号： C07C211/55

    摘要： The invention relates to a mixture of nonylated diphenylamines, especially dinonylated diphenylamines, and to a technically advantageous methodological process for the preparation of that mixture by using acid catalysts in small quantities. The mixture is used as an additive for stabilizing organic products that are subjected to oxidative, thermal and/or light-induced degradation.

    摘要翻译： 本发明涉及壬基化二苯胺，特别是二壬基化二苯胺的混合物，以及通过使用少量酸催化剂制备该混合物的技术上有利的方法方法。 该混合物用作用于稳定经受氧化，热和/或光诱导降解的有机产物的添加剂。

    CONDENSATION PRODUCTS OF MELAMINE AND PHENYLPHOSPHONIC ACID AND THEIR USE AS FLAME RETARDANTS
    7.
    发明申请
    CONDENSATION PRODUCTS OF MELAMINE AND PHENYLPHOSPHONIC ACID AND THEIR USE AS FLAME RETARDANTS 审中-公开
    甲胺和苯基磷酸的冷凝产物及其作为阻燃剂的使用

    公开(公告)号：US20130338264A1

    公开(公告)日：2013-12-19

    申请号：US14002146

    申请日：2012-03-09

    申请人： Thomas Weiss ,  Beat Michael Aebli ,  Rainer Xalter

    发明人： Thomas Weiss ,  Beat Michael Aebli ,  Rainer Xalter

    IPC分类号： C08K5/5317

    CPC分类号： C08K5/5317 ,  C07D251/70 ,  C08K5/34922 ,  C09K21/12

    摘要： Condensation products of melamine and phenylphosphonic acid, a process for their preparation, their compositions with polymeric materials and their use as flame retardants in polymer substrates are provided. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates, such as polyesters, polyamides and polycarbonates.

    摘要翻译： 提供三聚氰胺和苯基膦酸的缩合产物，其制备方法，它们与聚合物材料的组成以及它们在聚合物基材中作为阻燃剂的用途。 该组合物特别可用于制造基于多官能环氧化物或缩聚物如聚酯，聚酰胺和聚碳酸酯的阻燃剂化合物。